Citation: Zhang Yilin, Yan Yong, Ge Ying, Wang Xuejun, Qiao Chengfang. Ni-Catalyzed Suzuki Coupling Reaction[J]. Chemistry, ;2019, 82(5): 404-414. shu

Ni-Catalyzed Suzuki Coupling Reaction

1.
College of Biology Pharmacy and Food Engineering, Shangluo University, Shangluo 726000
2.
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Northwest University, Xi'an 710069
3.
College of Chemical Engineering and Modern Materials, Shangluo University, Shangluo 726000

Corresponding author: Zhang Yilin, yilin_190@126.com
Received Date: 28 October 2018
Accepted Date: 14 December 2018

Figures(7)

Progress in Ni-catalyzed Suzuki coupling reaction including the development path and all kinds of Ni-catalyzed Suzuki coupling reaction (C-Halo bond cleavage, C-O bond cleavage, C-C bond cleavage, C-N bond cleavage and C-S bond cleavage) in the past decade have been reviewed. Through nearly ten years of research, various new catalysts, ligands and additives have been developed, resulting in greatly improved reactivity and milder reaction conditions. The mechanism of Ni-catalyzed Suzuki coupling reaction was analyzed. It was found that Ni catalyzed Suzuki coupling reaction can be divided into Ni(0)/Ni(Ⅱ) cycle and Ni(Ⅰ)/Ni(Ⅲ) cycle. It is considered that the research and development of cheap metal nickel catalyst is an important direction to study the Suzuki coupling reaction. In the future, the study of Ni catalytic Suzuki coupling reaction will focus on mechanism investigation, design of new catalysts and ligands, multi-type C-C bond construction (Csp²-Csp³, Csp³-Csp³) and asymmetric Ni-catalyzed Suzuki coupling reaction of multi-type substrates.
- Ni catalyst,
- Suzuki coupling reaction,
- C-C bond,
- Mechanism
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