Citation: Zhang Feng. Catalytic Property and Mechanism of[Mn(salen)]₂ Accelerated Degradation of Phenol Wastewater by Fenton Reaction[J]. Chemistry, ;2017, 80(9): 873-879. shu

Catalytic Property and Mechanism of[Mn(salen)]₂ Accelerated Degradation of Phenol Wastewater by Fenton Reaction

Zhang Feng

Advanced Molecular Engineering Materials Laboratory, Department of Chemistry and Chemical Engineering, Baoji University of Arts and Science, Baoji 721013

Received Date: 20 February 2017
Accepted Date: 20 June 2017

Figures(11)

The catalytic property for degradation of phenol wastewater using Fenton reaction of Schiff base manganese complexes{[MnⅢ(salen)(H₂O)]₂(ClO₄)₂, [Mn(salen)]₂}was studied. The reaction characteristics and mechanism were analyzed by UV analysis, liquid chromatography, double reciprocal mapping and other analytical methods. The experimental results showed that the degradation efficiency of phenol of Fenton reaction is improved with the addition of Mn(salen)₂ complex. It maintained a certain degradation ability under different pH systems or excess H₂O₂. Due to the high valence manganese intermediate, which is converted from the manganese ion in the complex, the oxidation of organic matter and the degradation efficiency have been accelerated. The activation energy of the degradation reaction was reduced by 35.9% after adding the complex into the Fenton system. The catalytic activity of[Mn(salen)]₂ remained 60% after 7 times repeat uses.
- [Mn(salen)]₂ complex,
- Fenton reaction,
- Phenolic wastewater,
- Degradation
1. [1]
  L Throop, M William. J. Hazard. Mater., 1975, 1(4):319~329.
2. [2]
  A M Klibanov, E D Morris, L M Felshin. Appl. Biochem., 1980, 4(2):414~421.
3. [3]
  S Nakamoto, N Machida. Water Res., 1992, 26(1):49~54.
4. [4]
5. [5]
  C Renzo, D Francesco. J. Environ. Chem. Eng., 2013, 1(10):1292~1300.
6. [6]
7. [7]
  M Tokumura, R Morito, R Hatayama et al. Appl. Catal. B:Environ., 2011, 106(3~4):565~576.
8. [8]
  V Homem, A Alves, L Santos. Chem. Eng. J., 2013, 220:35~44.
9. [9]
  Y Segura, F Martínez, J A Melero et al. Appl. Catal. B:Environ., 2012, 113~114:100~106.
10. [10]
  E Brillas, I Sirés, M A Oturan. Chem. Rev., 2009, 109(12):6570~6631.
11. [11]
  D Xiang, C Duan, X Tan. J. Chem. Soc. Dalton. Transac., 1998, (7):1201~1204.
12. [12]
  Z Liao, X Zheng, B Luo et al. Polyhedron. 2001, 20:2813~2821.
13. [13]
  R L Rardin, W B Tolman, S Lippard. New J. Chem., 1991, 15:417~430.
14. [14]
  N Reddig, D Pursche, A Rompel. Dalton Transac., 2004, 14:1474~1480.
15. [15]
  D D Cox, S J Benkovic, L M Bloom. J. Am. Chem. Soc., 1988, 110:8085~8092.
16. [16]
  H L Wang, W Z Liang, Q A Zhang et al. Chem. Eng. J., 2010, 164(1):115~120.
17. [17]
  T Zhou, Y Z Li, F S Wong et al. Ultrason. Sonochem., 2008, 15(5):782~790.
18. [18]
  M R A Silva, A G Trovo, R F P Nogueira. J. Photochem. Photobiol. A, 2007, 191(2~3):187~192.
19. [19]
  C P Bai, W S Xiao, D X Feng et al. Chem. Eng. J., 2013, 215:227~234.
20. [20]
21. [21]
22. [22]
  S Aurora, Y Pedro, R Sergio et al. Ind. Eng. Chem. Res., 2010, 49(2):5583~5587.
23. [23]
24. [24]
25. [25]
26. [26]
  T Rigg, W Taylor, J Weiss. J. Chem. Phys., 1954, 22(4):575~577.
27. [27]
  F Jacobsen, J Holcman, K Sehested. Int. J. Chem. Kinet., 1998, 30(3):207~214.
28. [28]
  B H J Bielski, D E Cabelli, R L Arudi et al. J. Phys. Chem. Ref. Data, 1985, 14:1041~1098.
1. [1]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
2. [2]
  Hongbo Zhang , Yihong Tang , Suxia Zhang , Yuanting Li . Electrochemical Monitoring of Photocatalytic Degradation of Phenol Pollutants: A Recommended Comprehensive Analytical Chemistry Experiment. University Chemistry, 2024, 39(6): 326-333. doi: 10.3866/PKU.DXHX202310013
3. [3]
  Fei ZHOU , Xiaolin JIA . Co₃O₄/TiO₂ composite photocatalyst: Preparation and synergistic degradation performance of toluene. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2232-2240. doi: 10.11862/CJIC.20240236
4. [4]
  Cunling Ye , Xitong Zhao , Hongfang Wang , Zhike Wang . A Formula for the Calculation of Complex Concentrations Arising from Side Reactions and Its Applications. University Chemistry, 2024, 39(4): 382-386. doi: 10.3866/PKU.DXHX202310043
5. [5]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
6. [6]
  Ke QIAO , Yanlin LI , Shengli HUANG , Guoyu YANG . Advancements in asymmetric catalysis employing chiral iridium (ruthenium) complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2091-2104. doi: 10.11862/CJIC.20240265
7. [7]
  Jiaxun Wu , Mingde Li , Li Dang . The R eaction of Metal Selenium Complexes with Olefins as a Tutorial Case Study for Analyzing Molecular Orbital Interaction Modes. University Chemistry, 2025, 40(3): 108-115. doi: 10.12461/PKU.DXHX202405098
8. [8]
  Xuyu WANG , Xinran XIE , Dengke CAO . Photoreaction characteristics and luminescence modulation in phosphine-anthracene-based Au(Ⅰ) and Ir(Ⅲ) complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1513-1522. doi: 10.11862/CJIC.20250113
9. [9]
  Hexing SONG , Zan SUN . Synthesis, crystal structure, Hirshfeld surface analysis, and fluorescent sensing for Fe³⁺ of an Mn(Ⅱ) complex based on 1-naphthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 885-892. doi: 10.11862/CJIC.20240402
10. [10]
  Xinxin YU , Yongxing LIU , Xiaohong YI , Miao CHANG , Fei WANG , Peng WANG , Chongchen WANG . Photocatalytic peroxydisulfate activation for degrading organic pollutants over the zero-valent iron recovered from subway tunnels. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 864-876. doi: 10.11862/CJIC.20240438
11. [11]
  Aiyi Xin , Jiawei Li , Xinyang Ran , Chuanjiang Fu , Zhiguo Wang . Collaborative Science and Education Based Experimental Design in Organic Chemistry: A Case Study of the Nucleophilic Substitution Reaction of 2-Hydroxymethyl-4,6-Di-Tert-Butylphenol. University Chemistry, 2025, 40(5): 366-375. doi: 10.12461/PKU.DXHX202407031
12. [12]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
13. [13]
  Yuanqing Wang , Yusong Pan , Hongwu Zhu , Yanlei Xiang , Rong Han , Run Huang , Chao Du , Chengling Pan . Enhanced Catalytic Activity of Bi₂WO₆ for Organic Pollutants Degradation under the Synergism between Advanced Oxidative Processes and Visible Light Irradiation. Acta Physico-Chimica Sinica, 2024, 40(4): 2304050-0. doi: 10.3866/PKU.WHXB202304050
14. [14]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . Improved Photo-Carrier Transfer by an Internal Electric Field in BiOBr/N-rich C₃N₅ 3D/2D S-Scheme Heterojunction for Efficiently Photocatalytic Micropollutant Removal. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-0. doi: 10.3866/PKU.WHXB202407014
15. [15]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
16. [16]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
17. [17]
  Liangliang Song , Haoyan Liang , Shunqing Li , Bao Qiu , Zhaoping Liu . Challenges and strategies on high-manganese Li-rich layered oxide cathodes for ultrahigh-energy-density batteries. Acta Physico-Chimica Sinica, 2025, 41(8): 100085-0. doi: 10.1016/j.actphy.2025.100085
18. [18]
  Menglan Wei , Xiaoxia Ou , Yimeng Wang , Mengyuan Zhang , Fei Teng , Kaixuan Wang . S-scheme heterojunction g-C₃N₄/Bi₂WO₆ highly efficient degradation of levofloxacin: performance, mechanism and degradation pathway. Acta Physico-Chimica Sinica, 2025, 41(9): 100105-0. doi: 10.1016/j.actphy.2025.100105
19. [19]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
20. [20]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188

Get Citation

PDF

XML

Metrics

PDF Downloads(13)
Abstract views(3322)
HTML views(574)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Catalytic Property and Mechanism of[Mn(salen)]2 Accelerated Degradation of Phenol Wastewater by Fenton Reaction

Metrics

通讯作者: 陈斌, bchen63@163.com

Catalytic Property and Mechanism of[Mn(salen)]₂ Accelerated Degradation of Phenol Wastewater by Fenton Reaction