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Citation: Zhao Chunbao, Liu Zhen, Xiong Zhen, Han Min. Preparation and Electrochemical Properties of Graphene/Polyaniline Composites from Spent Lithium-Ion Batteries[J]. Chemistry, ;2019, 82(5): 431-435. shu

Preparation and Electrochemical Properties of Graphene/Polyaniline Composites from Spent Lithium-Ion Batteries

Department of Chemistry & Chemical Engineering, Xi'an University of Arts and Science, Xi'an 710065

Corresponding author: Zhao Chunbao, 276377944@qq.com
Received Date: 27 November 2018
Accepted Date: 21 January 2019

Figures(7)

Using graphene oxide (GO), which was prepared from cathodic graphite powder of spent lithium-ion batteries by an improved oxidation-reduction method, and aniline monomer as starting materials, the graphene/polyaniline composites were prepared via in situ polymerization by hydroxyl free radicals (·OH) from GO activated H₂O₂. The structure of the composite was characterized by FT-IR, XRD and SEM. The electrochemical behavior of the composites electrode was evaluated by cyclicvoltammetry (CV), electrochemical impedance spectroscopy (EIS) and galvanostatic charge-discharge tests (GCD). The results showed that the capacitance of rGO/PANI-10 was 481F/g at a current density of 100 mA/g, and it retained 77% capacitance after 1000 cycles at a current density of 500mA/g.
- Graphene,
- Graphene/polyaniline composites,
- Spent lithium-ion battery
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