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Citation: Li Huaming, Ye Xingkai, Wu Yue. Catalytic Oxidation of Cyclohexene to Cyclohexanone by Palladium Compounds[J]. Chinese Journal of Applied Chemistry, ;1995, 12(5): 15-19. shu

Catalytic Oxidation of Cyclohexene to Cyclohexanone by Palladium Compounds

Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022

Received Date: 24 October 1994
Revised Date: 17 March 1995

Cyclohexene has been oxidized to cyclohexanone catalytically by catalyst systems of Pd(OAc)₂/HQ with macrocyclic compounds: metallophthalocyanine(MPc,M=Fe,Cr,Co) and chlorometalloporphyrin(MTPPCI,M=Fe,Cr,Mn) in an acidic aqueous solution of acetonitrile. The best results were obtained by using Pd(OAc)₂/HQ/FePc system. The yield of cyclohexanone was 84% with selectivity of 98% on 30min reaction. Some factors influenc-ing the activity of the catalyst have been examined.
- cyclohexene,
- cyclohexanone,
- catalytic oxidation,
- palladium acetate,
- phthalocya-nine iron,
- hydroquinone
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