Citation: Peng GAO, Qun LI, Shi Yu WANG, Pang ZHANG. A NOVEL SCISSION OF ALKYL-CARBONYL C-C BOND BY ALKYL p-HYDROXYPHENYL KETONES[J]. Chinese Chemical Letters, ;1992, 3(7): 489-492. shu

A NOVEL SCISSION OF ALKYL-CARBONYL C-C BOND BY ALKYL p-HYDROXYPHENYL KETONES

Department of Chemistry, Peking University, Beijing 100871

Received Date: 3 March 1992

Fund Project: We are grateful to the National Natural Science Foundation and National Commission of Education for financial grant.

Methyl, ethyl, n-propyl, and benzyl p-hydroxyphenyl ketones and 6-hydroxy-1-tetralone are shown under the condition of ethylene ketal formation to undergo alkyl-carbonyl C-C bondscission, but not with p-hydroxybenzophenone, p-hydroxyisobutyrophenone, and 5-hydroxy-1-indanone. It is suggested that the scissiou is preceded by an aldol condensation.
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