Citation: Hui Yuan HU, Man Zhou ZHU, Zhi Ping ZHANG, Guo Tao WEN, Qing Xiang GUO. Photoinduced Electron Transfer in Host-Guest Complexes of Naphthalene Derivatives with p-NBCD and m-NBCD[J]. Chinese Chemical Letters, ;2006, 17(3): 333-336. shu

Photoinduced Electron Transfer in Host-Guest Complexes of Naphthalene Derivatives with p-NBCD and m-NBCD

Department of Chemistry, University of Science and Technology of China, Hefei 230026

Received Date: 22 August 2005

Fund Project: We thank the National Natural Science Foundation of China (No.20472079) for the financial support.

A number of naphthalene derivatives containing adamantanamine binding moiety and an (CH₂)_n (n=2, 3, 4, 5, 6) spacer were prepared as electron donor. A supramolecular assembly was fabricated by the inclusion complexation of the donor substrates with the host molecules, mono-6-O-p-nitrobenzoyl-β-cyclodextrin (p-NBCD) and mono-6-O-m-nitrobenzoyl-β-cyclodextrin (m-NBCD), in water. The fluorescence quenching in these systems was studied and detailed Stern-Volmer constants were measured. It revealed that an efficient photoinduced electron transfers (PET) between the naphthalene donors and the cyclodextrin acceptors occurred.
- Cyclodextrin,
- fluorescence quenching,
- photoinduced electron transfer,
- supramolecule
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