Citation: ZHONG Liu, LI Xin, FANG Qing-yan, YU Sheng-hui, XU Hao, ZHANG Cheng, CHEN Gang. Catalytic performance of the Mn-Ce catalysts in lean methane combustion prepared by a redox co-precipitation method[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(3): 378-384. shu

Catalytic performance of the Mn-Ce catalysts in lean methane combustion prepared by a redox co-precipitation method

State Key Laboratory of Coal Combustion, Huazhong University of Science and Technology, Wuhan 430074, China

Corresponding author: FANG Qing-yan, qyfang@mail.hust.edu.cn
Received Date: 16 October 2018
Revised Date: 17 December 2018

Fund Project: The project was supported by the National Natural Science Foundation of China 51676076the Research and Development Fund of SKLCC FSKLCC1805The project was supported by the National Natural Science Foundation of China (51676076) and the Research and Development Fund of SKLCC (FSKLCC1805)

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A series of Mn-Ce catalysts with different Mn/Ce ratios were prepared by a redox co-precipitation method and characterized by N₂ sorption, XRD, XRF and XPS; their catalytic performance in lean methane combustion was investigated. The results indicate that the Mn/Ce ratio has a great influence on the activity of Mn-Ce catalyst in lean methane combustion. With an increase of the Mn/Ce ratio from 3:7 to 9:1, the activity of the Mn-Ce catalyst increases gradually and the reaction temperature needed for a methane conversion of 50% (t₅₀) decreases from 501 ℃ to 446 ℃; however, a further increase in the Mn/Ce ratio may lead to a decrease in the catalytic activity. The performance of Mn-Ce catalyst is related to many factors such as the surface area and the concentration of higher valence manganese (Mn⁴⁺) species, lower valence cerium (Ce³⁺) species and lattice oxygen; in particular, KMn₈O₁₆ is of benefit to enhancing the activity of Mn-Ce catalyst.
- lean methane,
- Mn-Ce catalyst,
- catalytic combustion,
- redox-precipitation method
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