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Citation: Li Pengxi, Jiang Zonglin, Chen Benshou, Ren Tao. Syntheses of Pentaerythritol Derived Imidazolium Compounds and Their Spectral Response to Anions[J]. Chemistry, ;2018, 81(8): 734-738. shu

Syntheses of Pentaerythritol Derived Imidazolium Compounds and Their Spectral Response to Anions

Li Pengxi ^1,2 ,
Jiang Zonglin ^1,, ,
Chen Benshou ² ,
Ren Tao ¹

1.
School of Chemistry and Chemical Engineering, China West Normal University, Nanchong 637009
2.
School of Environment and Quality Test, Chongqing Chemical Industry Vocational College, Chongqing 401228

Corresponding author: Jiang Zonglin, orgchem@cwnu.edu.cn
Received Date: 2 December 2017
Accepted Date: 17 April 2018

Figures(4)

The imidazolium group is an attractive building block for anion receptors because in contributes a positive charge and relatively acidic C2-hydrogen. By the use of tetra(1-imidazolylmethyl) methane 1, we designed a series of novel imidazoliums with alkylating reagents, including imidazolium 2, the open chain bis-imidazolium salt 3, imidazolium cyclophane 4. The spectral response of compound 2, 3, 4 to anion was further determined by fluorescence spectra. The results showed that imidazolium 2 and imidazolium cyclophane 4a have a better selectivity for Cl^-, bisimidazolium 3a has definite recognition ability to PhCOO^-, bisimidazolium 3b and imidazolium cyclophane 4b have a better selectivity for I^-.
- Imidazolium,
- Cyclophane,
- Anion recognition,
- Fluorescence spectrum
1. [1]
  C B Zhang, Y Liu, Z F Liu et al. Bioorg. Med. Chem. Lett., 2017, 27(8):1808~1814.
2. [2]
  Z Z Li, L Gopala, V K R Tangadanchu et al. Bioorg. Med. Chem., 2017, 25(24):6511~6522.
3. [3]
  W W Gao, S Rasheed, V K R Tangadanchu et al. Sci. China Chem., 2017, 60(6):769~785.
4. [4]
  L Zhang, K V Kumar, S Rasheed et al. Chem. Biol. Drug Design, 2015, 86(4):648~655.
5. [5]
  L Zhang, X M Peng, G L V Damu et al. Med. Res. Rev., 2014, 34(2):340~437.
6. [6]
  P Rajakumar, R Padmanabhan et al. Tetrahed. Lett., 2010, 51:1059~1063.
7. [7]
  L Yang, S Qin, X Su et al. Org. Biomol. Chem., 2010, 8:339~348.
8. [8]
9. [9]
10. [10]
  Y X Xu, N Y Ye, D J Zhang et al. J. Colloid Interf. Sci., 2017, 497:333~342.
11. [11]
  Z Li, X H Yu, Y Chen et al. J. Org. Chem., 2017, 82(24):13368~13375.
12. [12]
  F Liu, P F Hao, T L Yu et al. J. Mol. Struct., 2016, 1119:431~436.
13. [13]
  J Y C Lim, I Marques, A L. Thompson et al. J. Am. Chem. Soc., 2017, 139:3122~3133.
14. [14]
  P Molina, F Zapata, A Caballero. Chem. Rev., 2017, 117:9907~9972.
15. [15]
  A Brown, P D Beer. Chem. Commun., 2016, 52:8645~8658.
1. [1]
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2. [2]
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