Citation: ZHANG Kai, LIN Ming-gui, LU Huai-qian, HOU Bo, WANG Jun-gang, JIA Li-tao, LI De-bao. Effects of ZrO₂ and Al₂O₃ on the performance of Mo-based catalysts in methanation[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(7): 854-862. shu

Effects of ZrO₂ and Al₂O₃ on the performance of Mo-based catalysts in methanation

ZHANG Kai ^1,2 ,
LIN Ming-gui ^1,*,, ,
LU Huai-qian ¹ ,
HOU Bo ¹ ,
WANG Jun-gang ¹ ,
JIA Li-tao ¹ ,
LI De-bao ^1,*,,

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: LIN Ming-gui, linmg@sxicc.ac.cn LI De-bao, dbli@sxicc.ac.cn
Received Date: 30 March 2017
Revised Date: 30 April 2017

Figures(7)

Mo/ZrO₂ and Mo/Al₂O₃ catalysts with a MoO₃ loading of 5% were prepared by incipient wetness impregnation method; the effect of support on the performance of Mo-based catalysts in methanation was then investigated in three different feeds. The results indicate that ZrO₂ as a support can promote the methanation and water-gas shift (WGS) reaction. ZrO₂ is beneficial to the sulfuration and reduction of MoO₃. The Mo sulfidation degree and the content of Mo⁴⁺ on Mo/ZrO₂ are higher than that on Mo/Al₂O₃. Besides, the curved MoS₂ basal plane on Mo/ZrO₂ can provide the active sites for methanation and WGS, which is effective to enhance the performance of Mo-based catalysts in methanation.
- CO/CO₂ hydrogenation,
- methanation,
- oxide supports,
- sulfidation degree
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Effects of ZrO₂ and Al₂O₃ on the performance of Mo-based catalysts in methanation