Citation: BAI Shu-li, ZHANG Xiao-yu, XUE Yao-jia, LI Huan-ying, JIA Jian-bo. Silicon carbon-supported copper oxide catalysts for the selective catalytic reduction of NO_x with NH₃ at low temperature[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(6): 723-727. shu

Silicon carbon-supported copper oxide catalysts for the selective catalytic reduction of NO_x with NH₃ at low temperature

School of Biotechnology and Health Sciences, Wuyi University, Jiangmen 529020, China

Corresponding author: BAI Shu-li, wyuchembsl@126.com
Received Date: 10 March 2020
Revised Date: 11 May 2020

Fund Project: National Natural Science Foundation of China 21006065The project was supported by National Natural Science Foundation of China (21006065)

Figures(7)

Silicon carbide supported copper oxide (CuO/SiC) catalysts were prepared by wet impregnation method and characterized by scanning electron microscope (SEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS); their catalytic performance in the selective catalytic reduction of NO_x with NH₃ at low temperature was investigated with a mimic flue gas. The results indicate that the catalytic performance of CuO/SiC in the selective catalytic reduction NO with NH₃ is related to the loading of copper oxide and reaction temperature. The CuO/SiC catalyst with a CuO loading of 5% exhibits high activity at low temperature, where SO₂ shows slightly inhibition upon the NO reduction activity; the NO reduction reaction over CuO/SiC may take place between the adsorbed ammonia and the gaseous or weakly adsorbed NO. Such CuO/SiC catalysts may provide a new choice for the practical removal of NO_x in industry.
- selective catalytic reduction,
- silicon carbide,
- copper oxide,
- ammonia
1. [1]
  PARVULESCU V, GRANGE P, DELMON B. Catalytic removal of NO[J]. Catal Today, 1998,46(4):233-316. doi: 10.1016/S0920-5861(98)00399-X
2. [2]
  BOSCH H, JANSSEN F. Catalytic reduction of nitrogen oxides:A review on the fundamentals and technology[J]. Catal Today, 1988,19(31):369-531.
3. [3]
  BRANDENBERGER S, KRÖCHER O, TISSLER A, ALTHOFF R. The state of the art in selective catalytic reduction of NO_x by ammonia using metal-exchanged zeolite catalysts[J]. Catal Rev, 2008,50(4):492-531. doi: 10.1080/01614940802480122
4. [4]
  WANG L, ZHAO J, BAI S, ZHAO H, ZHU Z. Significant catalytic effects induced by the electronic interactions between carboxyl and hydroxyl group modified carbon nanotube supports and vanadium species for NO reduction with NH₃ at low temperature[J]. Chem Eng J, 2014,254:399-409. doi: 10.1016/j.cej.2014.05.096
5. [5]
  CASANOVA M, SCHERMANZ K, LLORCAl J, TROVARELLI A. Improved high temperature stability of NH₃-SCR catalysts based on rare earth vanadates supported on TiO₂WO₃SiO₂[J]. Catal Today, 2012,184(1):227-236. doi: 10.1016/j.cattod.2011.10.035
6. [6]
  CHEN L, LI J, GE M. The poisoning effect of alkali metals doping over nano V₂O₅-WO₃/TiO₂ catalysts on selective catalytic reduction of NO_x by NH₃[J]. Chem Eng J, 2011,170(2/3):531-537.
7. [7]
  SUÁREZ S, MARTÍA J A, YATES M, AVILA P, BLANCO J. N₂O formation in the selective catalytic reduction of NO_x with NH₃ at low temperature on CuO-supported monolithic catalysts[J]. J Catal, 2005,229(1):227-236.
8. [8]
  KOMATSU T, NAGAI T, YASHIMA T. Cu-loaded dealuminated Y zeolites active in selective catalytic reduction of nitric oxide with ammonia[J]. Res Chem Intermed, 2006,32(3/4):291-304.
9. [9]
  LIU Q, LIU Z, XIE G, HUANG Z. Effect of SO₂ on a cordierite honeycomb supported CuO catalyst for NO reduction by NH₃[J]. Catal Lett, 2005,101(1/2):27-30.
10. [10]
  SHAFFER P. A review of the structure of silicon carbide[J]. Acta Crystallogr Sect B:Struct Sci Cryts Eng Mater, 1969,25(3):477-488. doi: 10.1107/S0567740869002457
11. [11]
  EOM J H, KIM Y W, RAJU S. Processing and properties of macroporous silicon carbide ceramics:A review[J]. J Asian Ceram Soc, 2013,1(3):220-242. doi: 10.1016/j.jascer.2013.07.003
12. [12]
  BERTHER A, THOMANN A, AIRES F C S, BRUN M, DERANLOT C, BERTOLINI J, ROZENBAUM J, BRAULT P, ANDREAZZA P. Comparison of Pd/(bulk SiC) catalysts prepared by atomic beam deposition and plasma sputtering deposition:Characterization and catalytic properties[J]. J Catal, 2000,190(1):49-59.
13. [13]
  ZHI G, GUO X, WANG Y, JIN G, GUO X. Effect of La₂O₃ modification on the catalytic performance of Ni/SiC for methanation of carbon dioxide[J]. Catal Commun, 2011,16(1):56-59.
14. [14]
  DUONG-VIET C, BA H, LIU Y, TRUONG-PHUOC L, NHUT J M, PHAM-HUU C. Nitrogen-doped carbon nanotubes on silicon carbide as a metal-free catalyst[J]. Chin J Catal, 2014,35(6):906-913. doi: 10.1016/S1872-2067(14)60116-9
15. [15]
  XIE S, GUO X N, TONG X L, WANG Y Y, GUO X Y. In situ grafted carbon on sawtooth-like SiC supported Ni for high-performance supercapacitor electrodes[J]. Chem Commun, 2014,50(2):228-230. doi: 10.1039/C3CC47019A
16. [16]
  BAI S, LI H, WANG L, GUAN Y, JIANG S. The properties and mechanism of CuO modified carbon nanotube for NO_x removal[J]. Catal Lett, 2014,144(2):216-221. doi: 10.1007/s10562-013-1157-5
17. [17]
  KELLER N, PHAM-HUU C, ESTOURNōS C, LENOUX M J. Low temperature use of SiC-supported NiS₂-based catalysts for selective H₂S oxidation:Role of SiC surface heterogeneity and nature of the active phase[J]. Appl Catal A:Gen, 2002,234(1/2):191-205.
18. [18]
  LIU Q, LIU Z, SU J. Al₂O₃-coated cordierite honeycomb supported CuO catalyst for selective catalytic reduction of NO by NH₃:Surface properties and reaction mechanism[J]. Catal Today, 2010,158(3/4):370-376.
19. [19]
  RAMIS G, YI L, BUSCA G, TURCO M, KOTUR E, WILLEY R J. Adsorption, activation, and oxidation of ammonia over SCR catalysts[J]. J Catal, 1995,157(2):523-535.
20. [20]
  TOPSØE N, TOPSØE H. Vanadia/titania catalysts for selective catalytic reduction (SCR) of nitric-oxide by ammonia I. combined temperature-programmed in-situ FTIR and on-line mass-spectroscopy studies[J]. J Catal, 1995,151(1):226-240.
21. [21]
  AMORES J G, ESCRIBANO V S, RAMIS G, BUSCA G. An FT-IR study of ammonia adsorption and oxidation over anatase-supported metal oxides[J]. Appl Catal B:Environ, 1997,13(1):45-58. doi: 10.1016/S0926-3373(96)00092-6
22. [22]
  ZHU Z, LIU Z, NIU H, LIU S, HU T, LIU T, XIE Y. Mechanism of SO₂ promotion for NO reduction with NH₃ over activated carbon-supported vanadium oxide catalyst[J]. J Catal, 2001,197(1):6-16.
23. [23]
  HUANG B, HUANG R, JIN D, YE D. Low temperature SCR of NO with NH₃ over carbon nanotubes supported vanadium oxides[J]. Catal Today, 2007,126(3/4):279-283.
24. [24]
  BAI S, ZNAO J, WANG L, ZHU Z. SO₂-promoted reduction of NO with NH₃ over vanadium molecularly anchored on the surface of carbon nanotubes[J]. Catal Today, 2010,158(3/4):393-400.
25. [25]
  ZHANG L, ZHANG D, ZHANG J, CAI S, FANG C, HUANG L, LI H, GAO R, SHI L. Nanoscale design of meso-TiO₂@MnO_x-CeO_x/CNTs with a core. shell structure as DeNO_x catalysts:Promotion of activity, stability and SO₂-tolerance[J]. Nanoscale, 2013,5(20):9821-9829. doi: 10.1039/c3nr03150k
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Silicon carbon-supported copper oxide catalysts for the selective catalytic reduction of NOx with NH3 at low temperature

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通讯作者: 陈斌, bchen63@163.com

Silicon carbon-supported copper oxide catalysts for the selective catalytic reduction of NO_x with NH₃ at low temperature