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Citation: Qu Yahuan, Yu Wei, Li Yuliang, Yu Guangqian. Synthesis of Propionamide Complexes with Lanthanide Chloride and Catalytic Activity of Its NdCl₃ Complex in Butadiene Polymerization[J]. Chinese Journal of Applied Chemistry, ;1998, 15(5): 21-23. shu

Synthesis of Propionamide Complexes with Lanthanide Chloride and Catalytic Activity of Its NdCl₃ Complex in Butadiene Polymerization

Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022

Received Date: 18 December 1997
Revised Date: 20 July 1998

The lanthanide complexes LnCl₃° 3PA(Ln=Pr,Nd,Eu,Dy; PA=propionamide) were synthesized. The IR results showed that PA is coordinated with Nd via its oxygen atom. The binary catalyst systems consisted of NdCl₃ ° 3PA with i-Bu₃Al, i-Bu₂AlH, or Et₃Al were all found to be very active for butadiene polymerization when the cis-1,4-content of polybutadiene is 98% or more.
- butadiene,
- coordination polymerization,
- propionamide,
- lanthanide complex
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Synthesis of Propionamide Complexes with Lanthanide Chloride and Catalytic Activity of Its NdCl3 Complex in Butadiene Polymerization

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com

Synthesis of Propionamide Complexes with Lanthanide Chloride and Catalytic Activity of Its NdCl₃ Complex in Butadiene Polymerization