Citation: ZHAI Jian-rong, ZHANG Yan-min, MO Wen-long, LI Xian, ZHONG Mei, MA Feng-yun. Effect of preparation method on the structure and properties of coal tar model compound cracking catalyst Ni/Al₂O₃[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(9): 1063-1073. shu

Effect of preparation method on the structure and properties of coal tar model compound cracking catalyst Ni/Al₂O₃

ZHAI Jian-rong ¹ ,
ZHANG Yan-min ¹ ,
MO Wen-long ¹ ,
LI Xian ^1,2 ,
ZHONG Mei ^1,, ,
MA Feng-yun ^1,,

1.
Key Laboratory of Coal Clean Conversion & Chemical Engineering Process(Xinjiang Uyghur Autonomous Region), College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China
2.
State Key Laboratory of Coal Combustion, Huazhong University of Science and Technology, Wuhan 430074, China

Corresponding author: ZHONG Mei, zhongmei0504@126.com MA Feng-yun, ma_fy@126.com
Received Date: 5 March 2018
Revised Date: 3 July 2018

Fund Project: National Natural Science Foundation of China 21606187Youth Science and technology innovation personnel training project in Xinjiang Uygur Autonomous Region QN2016BS0152The project was supported by the Key Laboratory of Xinjiang Uygur Autonomous Region (2016D03009), National Natural Science Foundation of China (21606187), National Key Research and Development Program (2016YFF0102602) and Youth Science and technology innovation personnel training project in Xinjiang Uygur Autonomous Region (QN2016BS0152)National Key Research and Development Program 2016YFF0102602the Key Laboratory of Xinjiang Uygur Autonomous Region 2016D03009

Figures(12)

Cat-1, Cat-2, Cat-3 and Cat-4 catalysts were synthesized via different preparation methods that are incipient wetness, impregnation-precipitation and mechanochemical method (carriers from market and homemade for comparison), and then characterized by BET, H₂-TPR, XRD, XPS and NH₃-TPD. The cracking behavior of toluene and pyrene (3%, mass fraction) (coal tar model compounds) were investigated to evaluate the catalytic performance of the stated catalysts. The catalyst characterization showed that the pore size of all the catalysts belonged to mesoporous range, and Cat-4 catalyst exhibited higher ordered mesoporous and larger surface area than others, up to 235 m²/g. Besides, the peak area of NiAl₂O₄ spinel reached up to the highest value of 85.2%. The dispersion of Ni in the reduced Cat-4 was the highest and its particle size was the lowest value, about 10.0 nm. Which means that there are more active sites. The catalytic performance results showed that the cracking rate of pyrene varied little for other catalysts, except for Cat-1, but the lowest carbon deposition of 10.84% was obtained under the action of Cat-4, while the carbon deposition of Cat-1, Cat-2 and Cat-3 increased by 35.0%, 74.7% and 45.7% respectively compared with that of Cat-4. Thus, Cat-4 prepared by mechanochemical method is more suitable for the cracking of toluene and pyrene system because of highest BET surface area, which is favorable for the dispersion of active component, and at the same time, the highest content of NiAl₂O₄ can inhibit the formation of carbon.
- preparation method,
- Ni/Al₂O₃ catalyst,
- model compound,
- cracking performance
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Effect of preparation method on the structure and properties of coal tar model compound cracking catalyst Ni/Al2O3

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通讯作者: 陈斌, bchen63@163.com

Effect of preparation method on the structure and properties of coal tar model compound cracking catalyst Ni/Al₂O₃