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Citation: Shi Tongshun, Liu Wei, Xu Chunfang, Wang Xingqiao, Liu Guofa. Synthesis and Electrochemical Behavior of Tetra-(1-naphthyl)tetrabenzoporphyrin Cobalt(Ⅱ) Complex[J]. Chinese Journal of Applied Chemistry, ;1998, 15(2): 23-26. shu

Synthesis and Electrochemical Behavior of Tetra-(1-naphthyl)tetrabenzoporphyrin Cobalt(Ⅱ) Complex

Department of Chemistry, Jilin University, Changchun 130023

Received Date: 22 May 1997
Revised Date: 28 September 1997

The title complex TNTBPCo(Ⅱ) was synthesized and characterized by elemental analysis, UV-vis, spectrum, IR photoacoustic spectrum, H NMR and molar conductance measurements. Its electrochemical behavior has been investigated by cyclic voltammetry in DMSO. The half wave potential of [TNTBPCo(Ⅲ)]⁺ /TNTBPCo(Ⅱ) was -0.255 V and that of TNTBPCo(Ⅱ)/[TNTBPCo(Ⅰ)]^-1 was -1.175 V. The half wave potential of redox of porphyrin ring [TNTBPCo(Ⅰ)]^-1 /[TNTBPCo(Ⅰ)]^-2 was -1.850 V.
- tetranaphthyl tetrabenzoporphyrin,
- colbalt complex,
- synthesis,
- characterization,
- electrochemical behavior
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