Citation: ZHANG Ke-zhuo, YU Ya-qian, TANG Rui, ZHENG Yu-qi, GAO Jia-jun, JIANG Xing-mao. Adsorption performance of polyvinylpyrrolidone for phenols in oil[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(11): 1305-1312. shu

Adsorption performance of polyvinylpyrrolidone for phenols in oil

Hubei Provincial Research Centre of Engineering & Technology for New Energy Materials, Hubei Key Lab of Novel Reactor & Green Chemical Technology, Key Laboratory for Green Chemical Process of Ministry of Education, School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology, Wuhan 430205, China

Corresponding author: GAO Jia-jun, gaojiajun@wit.edu.cn
Received Date: 1 July 2019
Revised Date: 11 September 2019

Fund Project: the Scientific Research Foundation of Wuhan Institute of Technology 17QD62The project was supported by Hubei Provincial Department of Education Science and Technology Research Project (Q20181504) and the Scientific Research Foundation of Wuhan Institute of Technology (17QD62)Hubei Provincial Department of Education Science and Technology Research Project Q20181504

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Effective separation of phenols in coal tar is essential for enhancing its application value. In this work, polyvinylpyrrolidone (PVP) was used as a sorbent in the separation of phenols in model oils; the adsorption performance of PVP towards o-cresol, m-cresol, p-cresol, 1-naphthol, and 2-naphthol was then comparatively investigated. The results indicate that PVP possesses high adsorption capacity towards the phenols; the maximum adsorbance of PVP towards m-cresol, p-cresol, 1-naphthol, and 2-naphthol is higher than 1000 mg/g. For the adsorption of phenols on PVP, H-bonds are formed between the Lewis basic sites (C=O and N) of PVP and the phenolic -OH group and the H-bonding intensity is influenced by the steric hindrance of phenols. Furthermore, PVP shows high adsorption selectivity; 2-naphthol can be adsorbed effectively on PVP even in the presence of benzofuran or quinoline. Moreover, PVP can be regenerated for recycling where phenols are recovered as well. As a result, PVP is a promising sorbent for the separation of phenols from the coal tar oil.
- polyvinylpyrrolidone,
- coal tar,
- phenols,
- adsorption
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