Citation: CHENG Zhi-fa, WANG Feng-jiao, YANG Wen-xi, ZHANG Han-yi, DENG Li-dan, ZHOU Gui-lin, ZHANG Xian-ming. Study of bimetallic NiFe catalysts for methyl laurate hydrogenation[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(7): 860-866. shu

Study of bimetallic NiFe catalysts for methyl laurate hydrogenation

1.
Department of Chemical Engineering, Chongqing Technology and Business University, Chongqing 400067, China
2.
Engineering Research Center for Waste Oil Recovery Technology and Equipment, Ministry of Education, Chongqing 400067, China

Corresponding author: ZHOU Gui-lin, dicpglzhou@ctbu.edu.cn
Received Date: 17 June 2020
Revised Date: 9 July 2020

Fund Project: The project was supported by the Innovation and Entrepreneurship Training Program for Chongqing College Students (S201911799031), the Science and Technology Research Project of Chongqing Education Commission(KJQN201900817), Science and Technology Major Projects of Chongqing Municipal Education Commission (KJZD-M201900802, KJZD-K201800801)Science and Technology Major Projects of Chongqing Municipal Education Commission KJZD-M201900802the Innovation and Entrepreneurship Training Program for Chongqing College Students S201911799031the Science and Technology Research Project of Chongqing Education Commission KJQN201900817Science and Technology Major Projects of Chongqing Municipal Education Commission KJZD-K201800801

Figures(5)

The physicochemical properties of the prepared bimetallic NiFe/γ-Al₂O₃ catalysts can be affected by reduction temperature, which can change the hydrogenation activity and product selectivity for methyl laurate catalytic hydrogenation. The metal Ni active sites mainly promote the decarbonylation/decarboxylation (DCO/DCO₂) reaction, and the addition of Fe can promote the hydrodeoxygenation (HDO) reaction of methyl laurate to produce C₁₂ alkanes. The results of H₂-TPR, XRD, H₂-TPD and BET indicate that high reduction temperature is beneficial to the formation of metal or alloy active centers. The hydrogenation activity of bimetallic catalysts depends on the content of metal Ni, Fe and NiFe alloy. The ability of NiFe bimetallic catalyst to adsorb and activate H₂ is obviously affected by reduction temperature. In the studied temperature range, Ni active centers have excellent hydrogenation and cracking performances, and the introduction of Fe species can effectively inhibit the cracking performance. The sequence of catalytic hydrogenation activity for these bimetallic catalysts is:NF420 > NF360 > NF450 > NF300. When the reduction temperature is 420℃, the prepared NF420 catalyst owns the best catalytic hydrogenation performances. The conversion of methyl laurate and the selectivity of alkanes are 93.3% and 90.0% at the reaction temperature of 380℃, respectively.
- NiFe bimetallic catalyst,
- hydrodeoxygeantion,
- methyl laurate,
- biodiesel
1. [1]
  TAROMI A A, KALIAGUINE S. Hydrodeoxygenation of triglycerides over reduced mesostructured Ni/γ-alumina catalysts prepared via one-pot sol-gel route for green diesel production[J]. Appl Catal A:Gen, 2018,558:140-149. doi: 10.1016/j.apcata.2018.03.030
2. [2]
  TANG Rui-feng, ZHANG Ming-yuan. Standardization makes the road of circular economy wider[EB/OL]. http://www.cqn.com.cn/zgzlb/content/2018-07/24/content_6072335. 2018-07-24.
3. [3]
  FANG H, ZHENG J, LUO X, DU J, ALBERTO R, STEFANO L, YUAN Y. Product tunable behavior of carbon nanotubes-supported Ni/Fe catalysts for guaiacol hydrodeoxygenation[J]. Appl Catal A:Gen, 2017,529:20-31. doi: 10.1016/j.apcata.2016.10.011
4. [4]
  YU X, CHEN J, REN T. Promotional effect of Fe on performance of Ni/SiO₂ for deoxygenation of methyl laurate as a model compound to hydrocarbons[J]. RSC Adv, 2014,4(87):46427-46436. doi: 10.1039/C4RA07932A
5. [5]
  ZHANG X M, CHEN S, WANG F J, DENG L D, REN J M, JIAO Z J, ZHOU G L. Effect of surface composition and structure of the mesoporous Ni/KIT-6 catalyst on catalytic hydrodeoxygenation performance[J]. Catalysts, 2019,9(11)889. doi: 10.3390/catal9110889
6. [6]
  PHAN D-P, VO T K, LE V N, KIM J, LEE E Y. Spray pyrolysis synthesis of bimetallic NiMo/Al₂O₃-TiO₂ catalyst for hydrodeoxygenation of guaiacol:Effects of bimetallic composition and reduction temperature[J]. J Ind Eng Chem, 2020,3(83):351-358.
7. [7]
  LIU H R, XU S Y, ZHOU G L, HUANG G C, HUANG S Y, XIONG K. CO₂ hydrogenation to methane over Co/KIT-6 catalyst:Effect of reduction temperature[J]. Chem Eng J, 2018,351:65-73. doi: 10.1016/j.cej.2018.06.087
8. [8]
  ZHAO A, YING W, ZHANG H, MA H, FANG D. Ni-Al₂O₃, catalysts prepared by solution combustion method for syngas methanation[J]. Catal Commun, 2012,17(1):34-38.
9. [9]
  QIN Z, REN J, MIAO M, LI Z, LIN J, XIE K. The catalytic methanation of coke oven gas over Ni-Ce/Al₂O₃ catalysts prepared by microwave heating:Effect of amorphous NiO formation[J]. Appl Catal B:Environ, 2015,164:18-30. doi: 10.1016/j.apcatb.2014.08.047
10. [10]
  KANG S H, RYU J H, KIM J H, SEO S J, YOO Y D, PRASAD P S, LIM H J, BYUN C D. Co-methanation of CO and CO on the Ni_x-Fe_1-x/Al₂O₃ catalysts; effect of Fe contents[J]. Korean J Chem Eng, 2011,28(12):2282-2286. doi: 10.1007/s11814-011-0125-2
11. [11]
  ZHU Yue-hui, WU Feng, WU Chuan. Catalysts research for hydrogen production from steam reforming of ethanol over Ni-Fe/γ-Al₂O₃[J]. J Funct Mater, 2009,40(11):1867-1869. doi: 10.3321/j.issn:1001-9731.2009.11.030
12. [12]
  CHEN Shuang. Study on the preparation of porous Ni catalyst and the performance of Oil Hydrodeoxygenation[D]. Chongqing: Chongqing Technology and Business University, 2018.
13. [13]
  MORALES M A, AYASTUYA J L, IRIARTE V U, ORTIZ M G. Nickel aluminate spinel-derived catalysts for the aqueous phase reforming of glycerol:Effect of reduction temperature[J]. Appl Catal B:Environ, 2019,244:931-945. doi: 10.1016/j.apcatb.2018.12.020
14. [14]
  CHEN S, ZHOU G L, XIE H M, JIAO Z J, ZHANG X M. Hydrodeoxygenation of methyl laurate over the sulfur-free Ni/γ-Al₂O₃ catalysts[J]. Appl Catal A:Gen, 2019,569:35-44. doi: 10.1016/j.apcata.2018.10.014
15. [15]
  SHI D C, WOJCIESZAK R, PAUL S, ERIC M. Ni promotion by Fe:What benefifits for catalytic hydrogenation[J]. Catalysts, 2019,9:451-478. doi: 10.3390/catal9050451
16. [16]
  CHENG Zhi-fa, ZHOU Gui-lin, JIAO Zhao-jie, ZHANG Xian-ming. Study of bimetallic NiFe/γ-Al₂O₃ catalysts for of methyl laurate hydrodeoxygenation[J]. Acta Energ Sol Sin, 2020, in press.
17. [17]
  ZANUTTINI M.S, GROSS M, MARCHETTI G, QUERINI C. Furfural hydrodeoxygenation on iron and platinum catalysts[J]. Appl Catal A:Gen, 2019,587117217. doi: 10.1016/j.apcata.2019.117217
18. [18]
  ARUMUGAM R, PERUMAL T, KANAN S. Catalytic hydrodeoxygenation of jojoba oil to the green-fuel application on Ni-MoS/Mesoporous zirconia-silica catalysts[J]. Renewable Energy, 2019,1138:161-173.
19. [19]
  CHEN N, GONG S, QIAN E W. Effect of reduction temperature of NiMoO_3-x/SAPO-11 on its catalytic activity in hydrodeoxygenation of methyl laurate[J]. Appl Catal B:Environ, 2015,174-175:253-263. doi: 10.1016/j.apcatb.2015.03.011
20. [20]
  MIAO C X, ZHOU G L, CHEN S, XIE H M, ZHANG X M. Synergistic effects between Cu and Ni species in NiCu/γ-Al₂O₃ catalysts for hydrodeoxygenation of methyl laurate[J]. Renewable Energy, 2020,153:1439-1454. doi: 10.1016/j.renene.2020.02.099
1. [1]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
2. [2]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004
3. [3]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046
4. [4]
  Ping Song , Nan Zhang , Jie Wang , Rui Yan , Zhiqiang Wang , Yingxue Jin . Experimental Teaching Design on Synthesis and Antitumor Activity Study of Cu-Pyropheophorbide-a Methyl Ester. University Chemistry, 2024, 39(6): 278-286. doi: 10.3866/PKU.DXHX202310087
5. [5]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
6. [6]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
7. [7]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
8. [8]
  Jingzhao Cheng , Shiyu Gao , Bei Cheng , Kai Yang , Wang Wang , Shaowen Cao . 4-氨基-1H-咪唑-5-甲腈修饰供体-受体型氮化碳光催化剂的构建及其高效光催化产氢研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406026-. doi: 10.3866/PKU.WHXB202406026
9. [9]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . Soft template-induced deep pore structure of Cu/Al₂O₃ for promoting plasma-catalyzed CO₂ hydrogenation to DME. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-. doi: 10.1016/j.actphy.2025.100054
10. [10]
  Fangxuan Liu , Ziyan Liu , Guowei Zhou , Tingting Gao , Wenyu Liu , Bin Sun . Hollow structured photocatalysts. Acta Physico-Chimica Sinica, 2025, 41(7): 100071-. doi: 10.1016/j.actphy.2025.100071
11. [11]
  Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO₂ reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409
12. [12]
  Hong CAI , Jiewen WU , Jingyun LI , Lixian CHEN , Siqi XIAO , Dan LI . Synthesis of a zinc-cobalt bimetallic adenine metal-organic framework for the recognition of sulfur-containing amino acids. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 114-122. doi: 10.11862/CJIC.20240382
13. [13]
  Zhaoxin LI , Ruibo WEI , Min ZHANG , Zefeng WANG , Jing ZHENG , Jianbo LIU . Advancements in the construction of inorganic protocells and their cell mimic and bio-catalytical applications. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2286-2302. doi: 10.11862/CJIC.20240235
14. [14]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
15. [15]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
16. [16]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
17. [17]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
18. [18]
  Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . Designing thermodynamically stable noble metal single-atom photocatalysts for highly efficient non-oxidative conversion of ethanol into high-purity hydrogen and value-added acetaldehyde. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-. doi: 10.1016/j.actphy.2025.100067
19. [19]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
20. [20]
  Xuejie Wang , Guoqing Cui , Congkai Wang , Yang Yang , Guiyuan Jiang , Chunming Xu . 碳基催化剂催化有机液体氢载体脱氢研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-. doi: 10.1016/j.actphy.2024.100044

Get Citation

PDF

XML

Metrics

PDF Downloads(9)
Abstract views(836)
HTML views(177)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142