Citation: LIU Yan-quan, CHENG Le-ming, JI Jie-qiang, FANG Meng-xiang, WANG Qin-hui. Influence of additives on sodium release and ash sintering temperature of a high-alkali coal[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(11): 1298-1304. shu

Influence of additives on sodium release and ash sintering temperature of a high-alkali coal

State Key Laboratory of Clean Energy Utilization, Institute for Thermal Power Engineering, Zhejiang University, Hangzhou 310027, China

Corresponding author: CHENG Le-ming, lemingc@zju.edu.cn
Received Date: 12 June 2018
Revised Date: 31 July 2018

Fund Project: The project was supported by the Key Project of the National Research Program of China (2015BAA04B02-09)the Key Project of the National Research Program of China 2015BAA04B02-09

Figures(8)

The influence of three additves (Kaolin, SiO₂ and Al₂O₃) on sodium release and ash sintering temperature of high-alkali Zhundong coal with addition ratio range of 1%-5% was studied. The results indicate that the order of sodium capture efficiency for the additives is:Kaolin > SiO₂ > Al₂O₃. The sodium capture efficiency increases with the addition ratio. However, the effect of temperature is much complex. At 600-1000℃, the sodium caputre efficiency of Kaolin increases firstly and then decreases, and the maximum value is achieved at 900℃. Meanwhile, the sodium capture efficiencies of other two additives decrease with increasing temperature. In addition, the ash sintering temperature of Zhundong coal is 803℃. After adding Kaolin, it decreases firstly and then increases with the addition ratio. At the addition ratio of 3%, the sintering tempeature is lowest due to the low-melting eutectic reaction between gehlenite and anorthite. SiO₂ with 5% can increase the sinntering temperature to 879℃ sharply because of generation of diopside and its skeleton effect. The influence of Al₂O₃ on the sintering temperature is minimal.
- Zhundong coal,
- additive,
- sodium capture efficiency,
- sintering temperature,
- mineral evolution
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