Citation: FANG Jie, LI Na, CHENG Lang, LU Jiang-yin. Effect of Ni-Cu on the one-step mild pressure hydrogenation of 1, 4-butynediol[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(6): 725-736. shu

Effect of Ni-Cu on the one-step mild pressure hydrogenation of 1, 4-butynediol

Key Laboratory of Oil & Gas Fine Chemicals, Ministry of Education, Xinjiang University, Urumqi 830046, China

Corresponding author: LU Jiang-yin,
Received Date: 11 December 2018
Revised Date: 5 March 2019

Fund Project: The project was supported by National Natural Science Foundation of China (21366030)National Natural Science Foundation of China 21366030

Figures(17)

The deposition-precipitation method was employed for the purpose of bringing in metallic promoters into Ni/Al₂O₃ catalysts. The effects of various metallic promoters on the catalytic performance in 1, 4-butynediol (BYD) hydrogenation were investigated. Besides, the contents of the suitable promoter were further studied, which were combined with BET, XRD, H₂-TPR, EDX-MAPPING, TEM, XPS, and NH₃-TPD techniques, aimed at exploring physico-chemical characteristics in catalysts. As the findings suggested, the addition of different promoters substantially impacted the interaction between Ni²⁺ and support, acting as the key factor impacting the catalytic performance. The introduction of Cu and Fe had the potential to prominently lower the strong interaction between Ni²⁺ and support for the improvement of the BYD conversion of 95%. Furthermore, different contents of Cu were further studied and discovered that it was the phenomenon of hydrogen spillover arisen on Cu surfaces, efficiently lowering the interaction between Ni²⁺ and support. Nevertheless, the aggregation in Ni particles cannot be evitable, but for the existence of Ni-Cu alloying in Cu-added catalysts. As the Cu content reached up to 5%, the catalyst manifested the excellent catalytic performance in hydrogenation owing to the abundant amount of Ni⁰ active sites in the form of the high dispersion and the fitting acidity.
- Ni/Al₂O₃ catalysts,
- Ni-Cu,
- modification,
- BYD,
- BED
1. [1]
  LI Chang-you, YANG Le-fu, CAI Fan, HUANG Bo, HU Yu-xiang, CAI Jun-xiu. Study on Pd-Pb/CaCO₃ catalyst for selective hydrogenation of acetylenic link in hydrocarbon[J]. J Xiamen Univ (Nat Sci), 2005(4):515-519. doi: 10.3321/j.issn:0438-0479.2005.04.018
2. [2]
  NATIVIDAD R, CRUZ OLIVARES J, FISHWICK R P, WOOD J, WINTERBOTTOM J M. Scaling-out selective hydrogenation reactions:From single capillary reactor to monolith[J]. Fuel, 2007,86(9):1304-1312. doi: 10.1016/j.fuel.2006.12.005
3. [3]
  TELKAR M M, RODE C V, RANE V H, JAGANATHAN R, CHAUDHARI R V. Selective hydrogenation of 2-butyne-1, 4-diol to 2-butene-1, 4-diol:Roles of ammonia, catalyst pretreatment and kinetic studies[J]. Appl Catal A:Gen, 2001,216(1):13-22.
4. [4]
  LIU Xiang, LIAO Qi-jiang, ZHANG Min-qing. Research progress of 1, 4-butynediol hydrogenation process[J]. Chem Ind Eng Prog, 2017,36(8):2787-2797.
5. [5]
  CHEN X, ZHANG M M, YANG K X, WILLIAMS C T, LIANG C H. Raney Ni-Si catalysts for selective hydrogenation of highly concentrated 2-butyne-1, 4-diol to 2-butene-1, 4-diol[J]. Catal Lett, 2014,144(7):1118-1126. doi: 10.1007/s10562-014-1259-8
6. [6]
  TANIELYAN S, SCHIMIDT S, MARIN N, ALVEZ G, AUGUSTINE R. Selective hydrogenation of 2-butyne-1, 4-diol to 1, 4-butanediol over particulate raney^(R) nickel catalysts[J]. Top Catal, 2010,53(15/18):1145-1149.
7. [7]
  LI C, ZHANG M, DI X, YIN D, LI W, LIANG C. One-step synthesis of Pt@ZIF-8 catalyst for the selective hydrogenation of 1, 4-butynediol to 1, 4-butenediol[J]. Chin J Catal, 2016,37(9):1555-1561. doi: 10.1016/S1872-2067(16)62497-X
8. [8]
  ZHANG M M, YANG Y B, LI C, LIU Q, WILLIAMS C T, LIANG C H. PVP-Pd@ZIF-8 as highly efficient and stable catalysts for selective hydrogenation of 1, 4-butynediol[J]. Catal Sci Technol, 2014,4(2):329-332. doi: 10.1039/C3CY00873H
9. [9]
  SAVVA P G, GOUNDANI K, VAKROS J, BOURIKAS K, FOUNTZOULA C, VATTIS D, LYCOURGHIOTIS A, KORDULIS C. Benzene hydrogenation over Ni/Al₂O₃ catalysts prepared by conventional and sol-gel techniques[J]. Appl Catal B:Environ, 2008,79(3):199-207. doi: 10.1016/j.apcatb.2007.10.023
10. [10]
  XIONG J, CHEN J, ZHANG J. Liquid-phase hydrogenation of o-chloronitrobenzene over supported nickel catalysts[J]. Catal Commun, 2007,8(3):345-350. doi: 10.1016/j.catcom.2006.06.028
11. [11]
  MICHALSKA K, KOWALIK P, KONKOL M, PROCHNIAK W, STOLECKI K, SLOWIK G, BOROWIECKI T. The effect of copper on benzene hydrogenation to cyclohexane over Ni/Al₂O₃ catalyst[J]. Appl Catal A:Gen, 2016,523(5):54-60.
12. [12]
  PEYROVI M, TOOSI M. Study of benzene hydrogenation catalyzed by nickel supported on alumina in a fixed bed reactor[J]. React Kinet Catal Lett, 2008,94(1):115-119. doi: 10.1007/s11144-008-5277-7
13. [13]
  LOULOUDI A, MICHALOPOULOS J, GANGAS N H, PAPAYANNAKOS N. Hydrogenation of benzene on Ni/Al-pillared saponite catalysts[J]. Appl Catal A:Gen, 2003,242(1):41-49. doi: 10.1016/S0926-860X(02)00503-3
14. [14]
  ZIELINSKI M. The catalytic and physico-chemical properties of Ni/MgF₂-MgO catalysts[J]. Appl Catal A:Gen, 2012,449:15-22. doi: 10.1016/j.apcata.2012.09.033
15. [15]
  BOUDJAHEM A G, BOUDERBALA W, BETTAHAR M. Benzene hydrogenation over Ni-Cu/SiO₂ catalysts prepared by aqueous hydrazine reduction[J]. Fuel Process Technol, 2011,92(3):500-506. doi: 10.1016/j.fuproc.2010.11.003
16. [16]
  DONG X F, CAI X L, SONG Y B, LIN W M. Effect of transition metals (Cu, Co and Fe) on the autothermal reforming of methane over Ni/Ce_0.2Zr_0.1Al_0.7O_δ catalyst[J]. J Nat Gas Chem, 2007,16(1):31-36. doi: 10.1016/S1003-9953(07)60022-X
17. [17]
  LI Hai-tao. Study of deactivation and promotion of catalyst employed in hydrogenation of butynediol to 1, 4-butanediol[D].Taiyuan: Shanxi University, 2011.
18. [18]
  KANG L N, GUO J Y, ZHANG H X, LI H T, XU Y L, ZHAO Y X. Activity and stability of Ni/SiO₂-Al₂O₃ catalyst in the aqueous phase hydrogenation system[J]. J Mol Catal, 2014,2:119-125.
19. [19]
  REN Yong, YUAN Tao, LIU De-rong, XIONG Wei, WU Xiao-hai, YI Fei, MENG Xiao-jing. Study on selective hydrogenation of 1, 4-butynediol by Pd-Cu/Fe₃O₄@C catalyst[J]. Chem Res Appl, 2017,29(11):1686-1692. doi: 10.3969/j.issn.1004-1656.2017.11.012
20. [20]
  LI Xia, HU Yu-fang, LIU De-rong, FENG Jian, XIONG Wei, SONG Fa-yi. Hydrogenolysis of glycerol to 1, 2-propanediol over Ru-Cu/Fe₃O₄-TiO₂ catalyst[J]. Chem Res Appl, 2016,28(5):629-635. doi: 10.3969/j.issn.1004-1656.2016.05.011
21. [21]
  BANG Y J, SEO J G, SONG I K. Hydrogen production by steam reforming of liquefied natural gas (LNG) over Ni-Al₂O₃ catalysts prepared by a sequential precipitation method:Effect of precipitation agent[J]. Int J Hydrogen Energy, 2009,34(19):8053-8060. doi: 10.1016/j.ijhydene.2009.08.020
22. [22]
  CAI B, ZHOU X C, MIAO Y C, LUO J Y, PAN H, HUANG Y B. Enhanced catalytic transfer hydrogenation of ethyl levulinate to γ-valerolactone over a robust Cu-Ni bimetallic catalyst[J]. ACS Sustainable Chem Eng, 2017,5(2):1322-1331. doi: 10.1021/acssuschemeng.6b01677
23. [23]
  WANG A, YIN H, LU H, XUE J, REN M, JIANG T. Effect of organic modifiers on the structure of nickel nanoparticles and catalytic activity in the hydrogenation of p-nitrophenol to p-aminophenol[J]. Langmuir, 2009,25(21):12736-12741. doi: 10.1021/la901815b
24. [24]
  BAYAT N, REZAEI M, MESHKANI F. Methane decomposition over Ni-Fe/Al₂O₃ catalysts for production of CO_x-free hydrogen and carbon nanofiber[J]. Int J Hydrogen Energy, 2016,41(3):1574-1584. doi: 10.1016/j.ijhydene.2015.10.053
25. [25]
  ZENG Y, WANG Z, LIN W, SONG W, CHRISTENSEN J M, JENSEN A. Hydrodeoxygenation of phenol over Pd catalysts by in-situ generated hydrogen from aqueous reforming of formic acid[J]. Catal Commun, 2016,82(5):46-49.
26. [26]
  CHEN J, QIAO Y, LI Y. Promoting effects of doping ZnO into coprecipitated NiAl₂O₃catalyst on methane decomposition to hydrogen and carbon nanofibers[J]. Appl Catal A:Gen, 2008,337(2):148-154. doi: 10.1016/j.apcata.2007.12.007
27. [27]
  YADAV G D, KHARKARA M R. Liquid-phase hydrogenation of saturated and unsaturated nitriles:Activities and selectivities of bimetallic nickel-copper and Nickel-Iron catalysts supported on silica[J]. Appl Catal A:Gen, 1995,126(1):115-123. doi: 10.1016/0926-860X(95)00039-9
28. [28]
  DONG F, ZHU Y, ZHENG H, ZHU Y, LI X, LI Y. Cr-free Cu-catalysts for the selective hydrogenation of biomass-derived furfural to 2-methylfuran:The synergistic effect of metal and acid sites[J]. J Mol Catal A:Chem, 2015,398:140-148. doi: 10.1016/j.molcata.2014.12.001
29. [29]
  WANG Z, LIU Q, YU J, WU T, WANG G. Surface structure and catalytic behavior of silica-supported copper catalysts prepared by impregnation and Sol-Gel methods[J]. Appl Catal A:Gen, 2003,239(1/2):87-94.
30. [30]
  ASHOK J, SUBRAHMANYAM M, AKULA V. Hydrotalcite structure derived Ni-Cu-Al catalysts for the production of H₂ by CH₄ decomposition[J]. Int J Hydrogen Energy, 2008,33(11):2704-2713. doi: 10.1016/j.ijhydene.2008.03.028
31. [31]
  JUSZCZYK W, COLMENARES J C, ŚREBOWATA A, KARPINSKI Z. The effect of copper and gold on the catalytic behavior of nickel/alumina catalysts in hydrogen-assisted dechlorination of 1, 2-dichloroethane[J]. Catal Today, 2011,169(1):186-191. doi: 10.1016/j.cattod.2010.08.019
32. [32]
  SHALI N B, SUGUNAN S. Influence of transition metals on the surface acidic properties of titania prepared by sol-gel route[J]. Mater Res Bull, 2007,42(9):1777-1783. doi: 10.1016/j.materresbull.2006.11.016
33. [33]
  MORE S, TANIELYAN S L, AUGUSTINE R, SCHMIDT S. Continuous liquid phase hydrogenation of 1, 4-butynediol to high purity 1, 4-Butanediol over particulate catalyst in fixed bed reactor[J]. Org Process Res Dev, 2016,21:327-335.
34. [34]
  KHOUZ M, GKANAS E I, DU S, WOOD J. Catalytic performance of Ni-Cu/Al₂O₃ for effective syngas production by methanol steam reforming[J]. Fuel, 2018,232:672-683. doi: 10.1016/j.fuel.2018.06.025
35. [35]
  RIAZ N, KAIT C B, MAN Z, DUTTA B, KHAN M. Photodegradation of orange Ⅱ under visible light using Cu-Ni/TiO₂:Influence of Cu:Ni mass composition, preparation, and calcination temperature[J]. Ind Eng Chem Res, 2013,52(12):4491-4503. doi: 10.1021/ie303255v
36. [36]
  YANG Z, LIU Y, LIU D, MENG X, LIU C. Hydroisomerization of n-octane over bimetallic Ni-Cu/SAPO-11 catalysts[J]. Catal Sci Technol, 2018,8(3):817-828. doi: 10.1039/C7CY02106B
37. [37]
  WU Q D L, DUCHSTEIN L, CHIARELLO G L, CHRISTENSEN J M, DAMSGAARD C, ELKJAR C, WAGNER J, TEMEL B, GRUNWALDT J D, JENSEN A. In situ observation of Cu-Ni alloy nanoparticle formation by X-Ray diffraction, X-Ray absorption spectroscopy, and transmission electron microscopy:Influence of Cu/Ni ratio[J]. ChemCatChem, 2013,6(1):301-310.
38. [38]
  HAO Z, ZHU Q, JIANG Z, HOU B, LI H. Characterization of aerogel Ni/Al₂O₃ catalysts and investigation on their stability for CH₄-CO₂ reforming in a fluidized bed[J]. Fuel Process Technol, 2009,90(1):113-121. doi: 10.1016/j.fuproc.2008.08.004
39. [39]
  YANG Z, LIU Y, LIU D, MENG X, LIU C. Hydroisomerization of n-octane over bimetallic Ni-Cu/SAPO-11 catalysts[J]. Appl Catal A:Gen, 2017,543:274-282. doi: 10.1016/j.apcata.2017.06.028
40. [40]
  MIRYALA B, REKHA V, PRASAD P S S, PRASAD R B N, NAKKA L. Selective hydrogenolysis of glycerol to 1, 2 propanediol over Cu-ZnO catalysts[J]. Catal Lett, 2008,126(1/2):119-124.
41. [41]
  SOUZA G D, BALZARETTI N M, MARCILIO N R, PEREZ-LOPEZ O W. Decomposition of ethanol over Ni-Al catalysts:Effect of copper addition[J]. Procedia Eng, 2012,42:335-345. doi: 10.1016/j.proeng.2012.07.425
42. [42]
  KAMEOKA S, TANABE T, PANG T A. Spinel CuFe₂O₄:A precursor for copper catalyst with high thermal stability and activity[J]. Catal Lett, 2005,100(1/2):89-93.
43. [43]
  PRAKASH M G, MAHALAKSHMY R, KRISHNAMURTHY K R, VISWANATHAN B. Studies on Ni-M (M=Cu, Ag, Au) bimetallic catalysts for selective hydrogenation of cinnamaldehyde[J]. Catal Today, 2015,263:105-111.
44. [44]
  WANG Da, ZHANG Yin, LI Hai-tao, ZHAO Li-li, ZHANG Hong-xi, ZHAO Yong-xiang. Selective hydrogenation of maleic anhydride to succinic anhydride in liquid phase over Ni-Cu/Al₂O₃ catalyst[J]. Chin J Catal, 2012,33(7):1229-1235.
45. [45]
  IRIONDO A, CAMBRA J F, GUEMEZ M B, BARRIO V L, REQUIES J, SANCHEZ M C, NAVARRO R M. Effect of ZrO₂ addition on Ni/Al₂O₃ catalyst to produce H₂ from glycerol[J]. Int J Hydrogen Energy, 2012,37(8):7084-7093. doi: 10.1016/j.ijhydene.2011.11.075
46. [46]
  SHI Y, CHEN W, DONGg L, LI H, FU Y. Enhancing copper infiltration into alumina using spark plasma sintering to achieve high performance Al₂O₃/Cu composites[J]. Ceram Int, 2018,44(1):57-64. doi: 10.1016/j.ceramint.2017.09.062
47. [47]
  PRAKRUTHI H R, CHANDRASHEKARA B M, JAI PRAKASH B S, BHAT Y S. Hydrogenation efficiency of highly porous Cu-Al oxides derived from dealuminated LDH in the conversion of furfural to furfuryl alcohol[J]. J Ind Eng Chem, 2018,62:96-105. doi: 10.1016/j.jiec.2017.12.048
48. [48]
  NAGHASH A R, ETSELL T H, XU S. XRD and XPS study of Cu-Ni interactions on reduced copper-nickel-aluminum oxide solid solution catalysts[J]. Chem Mater, 2006,18(10):2480-2488. doi: 10.1021/cm051910o
49. [49]
  XU S, WANG X. Highly active and coking resistant Ni/CeO₂-ZrO₂ catalyst for partial oxidation of methane[J]. Fuel, 2005,84(5):563-567. doi: 10.1016/j.fuel.2004.10.008
1. [1]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
2. [2]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
3. [3]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . Soft template-induced deep pore structure of Cu/Al₂O₃ for promoting plasma-catalyzed CO₂ hydrogenation to DME. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-. doi: 10.1016/j.actphy.2025.100054
4. [4]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
5. [5]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
6. [6]
  Shuhui Li , Rongxiuyuan Huang , Yingming Pan . Electrochemical Synthesis of 2,5-Diphenyl-1,3,4-Oxadiazole: A Recommended Comprehensive Organic Chemistry Experiment. University Chemistry, 2025, 40(5): 357-365. doi: 10.12461/PKU.DXHX202407028
7. [7]
  Jingzhao Cheng , Shiyu Gao , Bei Cheng , Kai Yang , Wang Wang , Shaowen Cao . 4-氨基-1H-咪唑-5-甲腈修饰供体-受体型氮化碳光催化剂的构建及其高效光催化产氢研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406026-. doi: 10.3866/PKU.WHXB202406026
8. [8]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
9. [9]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
10. [10]
  Tianlong Zhang , Rongling Zhang , Hongsheng Tang , Yan Li , Hua Li . Online Monitoring and Mechanistic Analysis of 3,5-diamino-1,2,4-triazole (DAT) Synthesis via Raman Spectroscopy: A Recommendation for a Comprehensive Instrumental Analysis Experiment. University Chemistry, 2024, 39(6): 303-311. doi: 10.3866/PKU.DXHX202312006
11. [11]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005
12. [12]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371
13. [13]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
14. [14]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
15. [15]
  Zhuoming Liang , Ming Chen , Zhiwen Zheng , Kai Chen . Multidimensional Studies on Ketone-Enol Tautomerism of 1,3-Diketones By ¹H NMR. University Chemistry, 2024, 39(7): 361-367. doi: 10.3866/PKU.DXHX202311029
16. [16]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
17. [17]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
18. [18]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004
19. [19]
  Yi Yang , Xin Zhou , Miaoli Gu , Bei Cheng , Zhen Wu , Jianjun Zhang . Femtosecond transient absorption spectroscopy investigation on ultrafast electron transfer in S-scheme ZnO/CdIn₂S₄ photocatalyst for H₂O₂ production and benzylamine oxidation. Acta Physico-Chimica Sinica, 2025, 41(6): 100064-. doi: 10.1016/j.actphy.2025.100064
20. [20]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046

Get Citation

PDF

XML

Metrics

PDF Downloads(11)
Abstract views(1746)
HTML views(128)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142