Citation: Chen Shiqing, Dai Wenhui, Xu Hewei, Liu Zhaoping. Tetramethylene Sulfone-Based Concentrated Electrolytes for High-Voltage Lithium-Ion Batteries[J]. Chemistry, ;2018, 81(11): 1000-1005. shu

Tetramethylene Sulfone-Based Concentrated Electrolytes for High-Voltage Lithium-Ion Batteries

Chen Shiqing ^1,2 ,
Dai Wenhui ^1,2 ,
Xu Hewei ² ,
Liu Zhaoping ^2,,

1.
Faculty of Science, Ningbo University, Ningbo 315211
2.
Advanced Li-ion Battery Engineering Lab, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201

Corresponding author: Liu Zhaoping, liuzp@nimte.ac.cn
Received Date: 28 June 2018
Accepted Date: 30 July 2018

Figures(5)

A concentrated electrolyte containing lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) and tetramethylene sulfone (TMS) was prepared. The electrolyte samples were characterized by Fourier transform infrared spectroscopy. The electrochemical properties of electrolytes were researched by linear sweep voltammetry (LSV) and cyclic voltammetry (CV). The TMS/LiTFSI (mole ratio 2:1) concentrated electrolyte displayed satisfactory electrochemical and chemical stability, extended electrochemical window to 5.02V. In addition, The 2:1 concentrated electrolyte could effectively restrain Al foil corrosion. Notably, the concentrated electrolyte was suitable for 5 V-class LiNi_0.5Mn_1.5O₄ cathode material. The LiNi_0.5Mn_1.5O₄ half-cells based on TMS/LiTFSI concentrated electrolyte showed excellent rate capability and cycle performance. The half-cell returned to its original specific capacity at 0.1 C after high power charge and discharge, meanwhile the coulombic efficiency of the half-cell was above 92% at 0.2 C after the first 25 cycles.
- Lithium-ion battery,
- Concentrated electrolyte,
- Tetramethylene sulfone,
- High-voltage
1. [1]
  F Wu, Q Z Zhu, R J Chen et al. Nano Energy, 2015, 13:546~553.
2. [2]
3. [3]
  J B Goodenough, Y Kim. J. Power Sources, 2011, 196(16):6688~6694.
4. [4]
  Y Bai, Y Tang, Z H Wang et al. Solid State Ionics, 2015, 272:24~29.
5. [5]
  E Quartarone, P Mustarelli. Chem. Soc. Rev., 2011, 40(5):2525~2540.
6. [6]
  S Tan, Y J Ji, Z R Zhang et al. ChemPhysChem, 2014, 15(10):1956~1969.
7. [7]
  A Manthiram, X W Yu, S F Wang. Nat. Rev. Mater., 2017, 2(4):16103.
8. [8]
  Y Yamada, K Furukawa, K Sodeyama et al. J. Am. Chem. Soc., 2014, 136(13):5039~5046.
9. [9]
  J H Wang, Y Yamada, K Sodeyama et al. Nat. Commun., 2016, 7:12032.
10. [10]
  V Nilsson, R Younesi, D Brandell et al. J. Power Sources. 2018, 384:334~341.
11. [11]
  S K Jeong, M Inaba, Y Iriyama et al. Electrochem. Solid-State Lett., 2003, 6(1):A13-A15.
12. [12]
  Y Yamada, Y Takazawa, K Miyazaki et al. J. Phys. Chem. C, 2010, 114(26):11680~11685.
13. [13]
  S K Jeong, H Y Seo, D H Kim et al. Electrochem. Commun., 2008, 10(4):635~638.
14. [14]
  J H Wang, Y Yamada, K Sodeyama et al. Nat. Energy, 2018, 3(1):22~29.
15. [15]
  Y Yamada, M Yaegashi, T Abe et al. Chem. Commun., 2013, 49(95):11194~11196.
16. [16]
  S M Ahn, J Suk, D Y Kim et al. Adv. Sci., 2017, 4(10):1700235.
17. [17]
  F Wu, H Zhou, Y Bai et al. ACS Appl. Mater. Interf., 2015, 7(27):15098~15107.
18. [18]
  K Xu. Chem. Rev., 2004, 104(10):4303~4417.
19. [19]
  K Matsumoto, K Inoue, K Nakahara et al. J. Power Sources, 2013, 231:234~238.
20. [20]
  D W McOwen, D M Seo, O Borodin et al. Energy Environ. Sci., 2014, 7(1):416~426.
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