Citation: SONG Yang-bo, XU Shao-ping, LI Ling-li, XIAO Ya-hui. Chemical looping gasification of coal char with Cu-olivine oxygen carriers[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(8): 916-923. shu

Chemical looping gasification of coal char with Cu-olivine oxygen carriers

State Key Laboratory of Fine Chemicals, Chemical Engineering Institute, Dalian University of Technology, Dalian 116024, China

Corresponding author: XU Shao-ping, spxu@dlut.edu.cn
Received Date: 29 March 2017
Revised Date: 26 May 2017

Figures(10)

A Cu-olivine oxygen carrier was prepared using impregnation method and used for steam gasification of coal char in a fixed bed reactor. It is shown that higher gasification temperature and steam/C molar ratio conduce to an increase in carbon conversion and syngas yield. The increase of CuO loading on the oxygen carrier and the oxygen carrier/char weight ratio leads to a higher carbon conversion but a lower syngas yield. The reaction activity of oxygen carrier has not been reduced after multiple regenerations at 950 ℃, which indicates that the olivine could inhibit the sintering of the supported Cu/CuO. The gasification at 800 ℃ in the presence of the oxygen carrier after 8th regeneration has a carbon conversion of 42.3%, a water conversion of 57.3% and a syngas yield of 2.12 L/(g·h).
- chemical looping gasification,
- coal char,
- Cu-olivine oxygen carrier,
- fixed bed reactor
1. [1]
  FAN L S. Chemical Looping Systems for Fossil Energy Conversions[M]. John Wiley & Sons, 2011.
2. [2]
  LYNGFELT A, LECKNER B, MATTISSON T. A fluidized-bed combustion process with inherent CO₂ separation; Application of chemical-looping combustion[J]. Chem Eng Sci, 2001,56(10):3101-3113. doi: 10.1016/S0009-2509(01)00007-0
3. [3]
  MATTISSON T, LYNGFELT A, LEION H. Chemical-looping with oxygen uncoupling for combustion of solid fuels[J]. Int J Green Gas Con, 2009,3(1):11-19. doi: 10.1016/j.ijggc.2008.06.002
4. [4]
  ADANEZ J, ABAD A, GARCIA-LABIANO F, GAYAN P, LUIS F. Progress in chemical-looping combustion and reforming technologies[J]. Prog Energy Combust Sci, 2012,38(2):215-282. doi: 10.1016/j.pecs.2011.09.001
5. [5]
  SIRIWARDANE R, RILEY J, TIAN H, RICHARDS G. Chemical looping coal gasification with calcium ferrite and barium ferrite via solid-solid reactions[J]. Appl Energ, 2016,165:952-966. doi: 10.1016/j.apenergy.2015.12.085
6. [6]
  YONGZHUO L I U, QINGJIE G U O. Investigation into syngas generation from solid fuel using CaSO₄-based chemical looping gasification process[J]. Chin J Chem Eng, 2013,21(2):127-134. doi: 10.1016/S1004-9541(13)60450-4
7. [7]
  HUANG Zhen-yao, HE Yao-fang, LI Hai-bin, ZHAO Zeng-li. Synthesis gas generation by chemical-looping gasification of biomass using natural hematite as oxygen carrier[J]. J Fuel Chem Technol, 2012,40(3):300-308.
8. [8]
  RAN Jing-yu, ZHANG Song, QIN Chang-lei, YU Jian-gong, FU Fan-xuan, YANG Lin. Gasification reactivity of biomass char with oxygen carrier CuO[J]. J Fuel Chem Technol, 2014,42(11):1316-1323. doi: 10.3969/j.issn.0253-2409.2014.11.007
9. [9]
  CORBELLA B, PALACIOS J M. Titania-supported iron oxide as oxygen carrier for chemical-looping combustion of methane[J]. Fuel, 2007,86(2):113-122.
10. [10]
  GAYÁN P, FORERO C R, ABAD A, DIEGO L F, GARCIA-LABIANO F, ADANEZ J. Effect of support on the behavior of Cu-based oxygen carriers during long-term CLC operation at temperatures above 1073 K[J]. Energy Fuels, 2011,25(3):1316-1326. doi: 10.1021/ef101583w
11. [11]
  ISHIDA M, JIN H. A novel combustor based on chemical-looping reactions and its reaction kinetics[J]. J Chem Eng Jpn, 1994,27(3):296-301. doi: 10.1252/jcej.27.296
12. [12]
  ADDNEZ J, DE DIEGO L F, GARCIA-LABIANO F, GAYAN P, ABAD A. Selection of oxygen carriers for chemical-looping combustion[J]. Energy Fuels, 2004,18(2):371-377. doi: 10.1021/ef0301452
13. [13]
  RYU H J, SEO Y, JIN G T. Development of chemical-looping combustion technology: long-term operation of a 50 kW/h chemical-looping combustor with Ni-and CO-based oxygen carrier particles[C]. In: Proc of the Regional Symp on Chem Eng Hanoi, Vietnam, 2005.
14. [14]
  SONG Q, XIAO R, DENG Z, SHEN L, XIAO J, ZHANG M. Effect of temperature on reduction of CaSO₄ oxygen carrier in chemical-looping combustion of simulated coal gas in a fluidized bed reactor[J]. Ind Eng Chem Res, 2008,47(21):8148-8159. doi: 10.1021/ie8007264
15. [15]
  RYDÉN M, LYNGFELT A, MATTISSON T, CHEN D, HOLMEN A, BJØRGUM E. Novel oxygen-carrier materials for chemical-looping combustion and chemical-looping reforming; La_xSr_1xFeyCo_1-yO_3-δ perovskites and mixed-metal oxides of NiO, Fe₂O₃ and Mn₃O₄[J]. Int J Green Gas Con, 2008,2(1):21-36. doi: 10.1016/S1750-5836(07)00107-7
16. [16]
  GUO Q, CHENG Y, LIU Y, JIA W, RYU H J. Coal chemical looping gasification for syngas generation using an iron-based oxygen carrier[J]. Ind Eng Chem Res, 2013,53(1):78-86.
17. [17]
  GE Hui-jun, GUO Wan-jun, SHEN Lai-hong, SONG Tao, Gu Hai-ming, JIANG Shou-xi. Experiments on chemical looping gasification of biomass with natural hematite as oxygen carrier[J]. J Eng Thermophys, 2015,36(6):1371-1375.
18. [18]
  LIU Yong-qiang, WANG Zhi-qi, WU Jin-hu, WU Jing-li, XU Mei. Investigation on Cu-based oxygen carrier for chemical looping combustion of combustible solid waste[J]. J Fuel Chem Technol, 2013,41(9):1056-1063.
19. [19]
  YANG W, ZHAO H, MA J, MEI D, ZHENG C. Copper-decorated hematite as an oxygen carrier for in situ gasification chemical looping combustion of coal[J]. Energy Fuels, 2014,28(6):3970-3981. doi: 10.1021/ef5001584
20. [20]
  NIU X, SHEN L, JIANG S, GU H, XIAO J. Combustion performance of sewage sludge in chemical looping combustion with bimetallic Cu-Fe oxygen carrier[J]. Chem Eng J, 2016,294:185-192. doi: 10.1016/j.cej.2016.02.115
21. [21]
  LI F, LUO S, SUN Z, BAO X, FAN L S. Role of metal oxide support in redox reactions of iron oxide for chemical looping applications: experiments and density functional theory calculations[J]. Energ Environ Sci, 2011,4(9):3661-3667. doi: 10.1039/c1ee01325d
22. [22]
  WEI Li-gang, XU Shao-ping, LIU Chang-hou, LIU Shu-qin. Effects of pre-calcination on catalytic activity of olivine in biomass gasification[J]. J Fuel Chem Technol, 2008,36(4):426-430.
23. [23]
  ŚWIERCZYŃSKI D, COURSON C, BEDEL L, KIENNEMANN A, VILMINOT S. Oxidation reduction behavior of iron-bearing olivines (Fe_xMg_1-x)₂SiO₄ used as catalysts for biomass gasification[J]. Chem Mater, 2006,18(4):897-905. doi: 10.1021/cm051433+
1. [1]
  Guowen Xing , Guangjian Liu , Le Chang . Five Types of Reactions of Carbonyl Oxonium Intermediates in University Organic Chemistry Teaching. University Chemistry, 2025, 40(4): 282-290. doi: 10.12461/PKU.DXHX202407058
2. [2]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
3. [3]
  Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu₂O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
4. [4]
  Hanmei Lü , Xin Chen , Qifu Sun , Ning Zhao , Xiangxin Guo . Uniform Garnet Nanoparticle Dispersion in Composite Polymer Electrolytes. Acta Physico-Chimica Sinica, 2024, 40(3): 2305016-0. doi: 10.3866/PKU.WHXB202305016
5. [5]
  Zhengyu Zhou , Huiqin Yao , Youlin Wu , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(10): 2312010-0. doi: 10.3866/PKU.WHXB202312010
6. [6]
  Xiaomei Ning , Liang Zhan , Xiaosong Zhou , Jin Luo , Xunfu Zhou , Cuifen Luo . Preparation and Electro-Oxidation Performance of PtBi Supported on Carbon Cloth: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 217-224. doi: 10.3866/PKU.DXHX202401085
7. [7]
  Jiarong Feng , Yejie Duan , Chu Chu , Dezhen Xie , Qiu'e Cao , Peng Liu . Preparation and Application of a Streptomycin Molecularly Imprinted Electrochemical Sensor: A Suggested Comprehensive Analytical Chemical Experiment. University Chemistry, 2024, 39(8): 295-305. doi: 10.3866/PKU.DXHX202401016
8. [8]
  Pengzi Wang , Wenjing Xiao , Jiarong Chen . Copper-Catalyzed C―O Bond Formation by Kharasch-Sosnovsky-Type Reaction. University Chemistry, 2025, 40(4): 239-244. doi: 10.12461/PKU.DXHX202406090
9. [9]
  Weicheng Feng , Jingcheng Yu , Yilan Yang , Yige Guo , Geng Zou , Xiaoju Liu , Zhou Chen , Kun Dong , Yuefeng Song , Guoxiong Wang , Xinhe Bao . Regulating the High Entropy Component of Double Perovskite for High-Temperature Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2024, 40(6): 2306013-0. doi: 10.3866/PKU.WHXB202306013
10. [10]
  Gonglan Ye , Xia Yin , Feng Xu , Peng Yang , Yingpeng Wu , Huilong Fei . Innovations in “Four-in-One” Inorganic Chemistry Education. University Chemistry, 2024, 39(8): 136-141. doi: 10.3866/PKU.DXHX202401071
11. [11]
  Zhexue Lu , Ping Wu , Huihui Li , Libai Wen . 四“味”一体的无机及分析化学课程思政. University Chemistry, 2025, 40(6): 333-340. doi: 10.12461/PKU.DXHX202405196
12. [12]
  Yang Meiqing , Lu Wang , Haozi Lu , Yaocheng Yang , Song Liu . Recent Advances of Functional Nanomaterials for Screen-Printed Photoelectrochemical Biosensors. Acta Physico-Chimica Sinica, 2025, 41(2): 2310046-0. doi: 10.3866/PKU.WHXB202310046
13. [13]
  Jingyi Xie , Qianxi Lü , Weizhen Qiao , Chenyu Bu , Yusheng Zhang , Xuejun Zhai , Renqing Lü , Yongming Chai , Bin Dong . Enhancing Cobalt―Oxygen Bond to Stabilize Defective Co₂MnO₄ in Acidic Oxygen Evolution. Acta Physico-Chimica Sinica, 2024, 40(3): 2305021-0. doi: 10.3866/PKU.WHXB202305021
14. [14]
  Jiabo Huang , Quanxin Li , Zhongyan Cao , Li Dang , Shaofei Ni . Elucidating the Mechanism of Beckmann Rearrangement Reaction Using Quantum Chemical Calculations. University Chemistry, 2025, 40(3): 153-159. doi: 10.12461/PKU.DXHX202405172
15. [15]
  Renqing Lü , Shutao Wang , Fang Wang , Guoping Shen . Computational Chemistry Aided Organic Chemistry Teaching: A Case of Comparison of Basicity and Stability of Diazine Isomers. University Chemistry, 2025, 40(3): 76-82. doi: 10.12461/PKU.DXHX202404119
16. [16]
  Chengbin Gong , Guona Zhang , Qian Tang , Hong Lei , Ling Kong , Wenshan Ren . Development of a Practical Teaching System for the Applied Chemistry Major Emphasizing “Industry-Education Integration, University-Enterprise Cooperation, and Multi-Dimensional Combination”. University Chemistry, 2024, 39(6): 220-225. doi: 10.3866/PKU.DXHX202309104
17. [17]
  Zhixin Zhou , Ran Chen , Yuanjian Zhang , Songqin Liu , Yanfei Shen . 分析化学课程本硕一体化的全英文教学改革. University Chemistry, 2025, 40(6): 64-70. doi: 10.12461/PKU.DXHX202407093
18. [18]
  Jinfeng Chu , Yicheng Wang , Ji Qi , Yulin Liu , Yan Li , Lan Jin , Lei He , Yufei Song . Comprehensive Chemical Experiment Design: Convenient Preparation and Characterization of an Oxygen-Bridged Trinuclear Iron(III) Complex. University Chemistry, 2024, 39(7): 299-306. doi: 10.3866/PKU.DXHX202310105
19. [19]
  Zhaoyu Wen , Na Han , Yanguang Li . Recent Progress towards the Production of H₂O₂ by Electrochemical Two-Electron Oxygen Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(2): 2304001-0. doi: 10.3866/PKU.WHXB202304001
20. [20]
  Houjin Li , Wenjian Lan . Name Reactions in University Organic Chemistry Laboratory. University Chemistry, 2024, 39(4): 268-279. doi: 10.3866/PKU.DXHX202310016

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(1796)
HTML views(349)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142