Citation: Li Fangji, Bian Yanjiang, Chen Zhixin, Tang Lijun, Zhong Keli, Hou Shuhua. A Isophthalic Dihydrazide-Based Fluorescent Probe for Relay Recognition of Al³⁺ and Pyrophosphate[J]. Chemistry, ;2019, 82(8): 743-748. shu

A Isophthalic Dihydrazide-Based Fluorescent Probe for Relay Recognition of Al³⁺ and Pyrophosphate

College of Chemistry and Chemical Engineering, Bohai University, Jinzhou 121013

Received Date: 24 February 2019
Revised Date: 8 March 2019

A simple and efficient fluorescent probe L was synthesized by using 2-hydroxy-1-naphthaldehyde and isophthalic dihydrazide as raw materials. Its structure were characterized by ¹H NMR,¹³C NMR and HRMS. Probe L displays an highly selective recognition and a lower detection limit (5.924×10^-6mol/L) for Al³⁺ over other tested metal ions, which has a significant fluorescence enhancement in the mixed ETOH and water (1:1) system. This probe L has a binding ratio of 1:2. In addition, the L-2Al³⁺ showed highly selective sequential recognition of pyrophosphate ions (PPi) with good sensitivity. The detection limit of L-2Al³⁺ to PPi could reach 4.756×10^-5mol/L. The fluorescent probe has potential application value.
- 2-Hydroxy-1-naphthaldehyde,
- Isophthalic dihydrazide,
- Al³⁺,
- Pyrophosphate
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沈阳化工大学材料科学与工程学院沈阳 110142

A Isophthalic Dihydrazide-Based Fluorescent Probe for Relay Recognition of Al3+ and Pyrophosphate

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通讯作者: 陈斌, bchen63@163.com

A Isophthalic Dihydrazide-Based Fluorescent Probe for Relay Recognition of Al³⁺ and Pyrophosphate