Citation: WANG Lei, XU Tian-xiao, HAN Yan-xu, QING Shao-jun, MA Yu-bo. Study on the catalytic hydrogenation of methyl levulinate over Ru/organic modified vermiculite[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(1): 100-107. shu

Study on the catalytic hydrogenation of methyl levulinate over Ru/organic modified vermiculite

WANG Lei ¹ ,
XU Tian-xiao ² ,
HAN Yan-xu ² ,
QING Shao-jun ^3,, ,
MA Yu-bo ⁴

1.
School of Chemistry and Chemical Engineering, Lingnan Normal University, Zhanjiang 524048, China
2.
School of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China
3.
Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
4.
School of Chemical Engineering, Chongqing Chemical Industry Vocational College, Chongqing 401220, China

Corresponding author: QING Shao-jun, qingshaojun@sxicc.ac.cn
Received Date: 25 September 2019
Revised Date: 28 November 2019

Fund Project: the National Nature Science Foundation of China 21808192Foundation of Xinjiang Education Department XJEDU2017S002the National Nature Science Foundation of China U1703128The project was supported by the National Nature Science Foundation of China (21808192, U1703128), the Doctoral Scientific Research Staring Foundation of Lingnan Normal University(ZL2017), Natural Science Foundation of Xinjiang Uygur Autonomous Region (2016D01C077), Foundation of Xinjiang Education Department(XJEDU2017S002)the Doctoral Scientific Research Staring Foundation of Lingnan Normal University ZL2017Natural Science Foundation of Xinjiang Uygur Autonomous Region 2016D01C077

Figures(8)

Organic-pillared vermiculite supported Ru (Ru/OV) was prepared via adsorption-precipitation method, using RuCl₃·xH₂O as precursor and applied to catalytic hydrogenation of methyl levulinate (ML). The physicochemical properties of the catalysts were investigated by XRD, N₂-adsorption-desorption, TEM and XPS. Effects of reaction temperature, pressure, reaction time on the catalytic performance were studied by orthogonal and single factor experiments. Under the optimum conditions, the conversion of ML and the selectivity of γ-valerolactone (GVL) were 84% and 100%, separately. After being recycled for 20 times, the conversion of ML was above 80% and the 100% selectivity of GVL could be obtained.
- Ru,
- organic-pillared vermiculite,
- catalytic hydrogenation,
- methyl levulinate,
- γ-valerolactone
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