Citation: Wang Binbin, Liu Lei, Zhang Yuanyuan, Shen Liangjun, Wang Lejia, Chen Aibinga, Feng Haobin, Xiao Xunwen. Novel Diaryquioxaline Derivatives with Aggregation-Induced Emission Characteristics for Turn-On Detection of Hg²⁺[J]. Chemistry, ;2018, 81(6): 525-530. shu

Novel Diaryquioxaline Derivatives with Aggregation-Induced Emission Characteristics for Turn-On Detection of Hg²⁺

1.
College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018
2.
College of Material Science and Chemical Engineering, Ningbo University of Technology, Ningbo 315211
3.
Hebei Provincial Institute of Food Inspection, Shijiazhuang 050000

Corresponding author: Liu Lei, liulei@hebust.edu.cn Xiao Xunwen, xunwenxiao@nbut.edu.cn
Received Date: 13 March 2018
Accepted Date: 6 April 2018

Figures(8)

Fluorescence sensing is a powerful tool for detection of chemical species due to its high sensitivity and selectivity. New aggregation-induced emission (AIE)-active fluorophores, diarylquinoxaline derivatives (1~4), are synthesized and characterized. By the combination of diarylquinoxaline core and a 1, 3-dithiole-2-thione unit, compounds 3, 4 are used as "turn on" chemosensors for Hg²⁺ by taking use of the AIE feature of diarylquinoxaline core and the specific reaction of 1, 3-dithiole-2-thione with Hg²⁺. Compound 3 especially displays a good selectivity towards Hg²⁺ over other common heavy metal ions.
- 1,
- 3-Dithiole-2-thione,
- AIE,
- Fluorescent probe,
- Sensor,
- Hg²⁺
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沈阳化工大学材料科学与工程学院沈阳 110142

Novel Diaryquioxaline Derivatives with Aggregation-Induced Emission Characteristics for Turn-On Detection of Hg2+

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通讯作者: 陈斌, bchen63@163.com

Novel Diaryquioxaline Derivatives with Aggregation-Induced Emission Characteristics for Turn-On Detection of Hg²⁺