Citation: SONG Hua, DAI Xue-ya, GONG Jing, SONG Hua-lin, LIU Yan-xiu, LI Feng. Preparation of supported nickel phosphide catalyst by surface modification method and its performance in hydrodeoxygenation[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(9): 1105-1111. shu

Preparation of supported nickel phosphide catalyst by surface modification method and its performance in hydrodeoxygenation

SONG Hua ^1,*,, ,
DAI Xue-ya ¹ ,
GONG Jing ¹ ,
SONG Hua-lin ² ,
LIU Yan-xiu ¹ ,
LI Feng ¹

1.
College of Chemistry & Chemical Engineering, Northeast Petroleum University, Daqing 163318, China
2.
Provincial Key Laboratory of Oil & Gas Chemical Technology, Northeast Petroleum University, Daqing 163318, China

Corresponding author: SONG Hua, songhua2004@sina.com
Received Date: 24 March 2016
Revised Date: 7 May 2016

Fund Project: the National Natural Science Foundation of China 21276048the Natural Science Foundation of Heilongjiang Province of China ZD201201the Project of Education Department of Heilongjiang Province 12541060

Figures(5)

With MCM-41 as support, the supported Ni₂P/MCM-41 catalyst is prepared by first reducing the Ni₂P precursors at low temperature (673 K) and then modifying the surface with air; the as-prepared Ni₂P/MCM-41 catalyst was characterized by X-ray diffraction (XRD), N₂-sorption, scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray photoelectron spectroscopy (XPS) and CO uptake. The catalytic performance of Ni₂P/MCM-41 in hydrodeoxygenation (HDO) of benzofuran (BF) was investigated to elucidate the effect of surface modification with air on the catalyst structure and HDO activity. The results show that pure Ni₂P acts as the active phase on the surface of modified Ni₂P/MCM-41 catalyst; the surface modification can decrease the aggregation of P species and promote the formation of small and highly dispersed Ni₂P active phase. Under 573 K, 3.0 MPa, a weight hourly space velocity of 4.0 h^-1 and a H₂/oil volume ratio of 500, the yield of O-free products reaches 88% for HDO of BF over the modified Ni₂P/MCM-41 catalyst, which is about 50% higher than that over the catalyst prepared by conventional temperature-programmed reduction method.
- surface modification,
- Ni₂P,
- MCM-41,
- benzofuran (BF),
- hydrodeoxygenation (HDO)
1. [1]
  SERRANO RUIZ J C, DUMESIC J A. Catalytic routes for the convention of biomass into liquid hudrocarbon transportation fuels[J]. Energy Environ Sci, 2011,4(1):83-99. doi: 10.1039/C0EE00436G
2. [2]
  HUBER G W, IBORRA S, CORMA A. Synthesis of transportation fuels from biomass: Chemistry, catalysts, and engineering[J]. Chem Rev, 2006,106(9):4044-4098. doi: 10.1021/cr068360d
3. [3]
  WANG H M, JONATHAN MALE, WANG Y. Recent advances in hydrotreating of pyrolysis bio-oil and its oxygen-containing model compounds[J]. ACS Catal, 2013,3(5):1047-1070. doi: 10.1021/cs400069z
4. [4]
  HUANG Y B, WEI L, ZHAO X H, CHENG S Y, JAMES J, CAO Y H, GU Z G. Upgrading pine sawdust pyrolysis oil to green biofuels by HDO over zinc-assisted Pd/C catalyst[J]. Energy Convers Manage, 2016,115:8-16. doi: 10.1016/j.enconman.2016.02.049
5. [5]
  MORTAZA G, RICHARD G, HUA X, FERRAN D M M, ROEL W, WEERAWUT C, MD M H, DANIEL M, LI C Z. Effects of temperature on the hydrotreatment behaviour of pyrolysis bio-oil and coke formation in a continuous hydrotreatment reactor[J]. Fuel Process Technol, 2016,148:175-183. doi: 10.1016/j.fuproc.2016.03.002
6. [6]
  PETER M M, HUDSON W P D C, JAN-DIERK G, PETER A J, ANKER D J. Activity and stability of Mo₂C/ZrO₂ as catalyst for hydrodeoxygenation of mixtures of phenol and 1-octanol[J]. J Catal, 2015,328:208-215. doi: 10.1016/j.jcat.2015.02.002
7. [7]
  YANG J, ZHAO L, LIU S, WANG Y Y, DAI L Y. High-quality bio-oil from one-pot catalytic hydrocracking of kraft lignin over supported noble metal catalysts in isopropanol system[J]. Bioresour Technol, 2016,212:302-310. doi: 10.1016/j.biortech.2016.04.029
8. [8]
  GAUDETTE A F, BURNS A W, HAYES J R, MICA C S, RICHARD H B, TAKELE SEDA, MARK E B. M ssbauer spectroscopy investigation and hydrodesulfurization properties of iron-nickel phosphide catalysts[J]. J Catal, 2010,272(1):18-27. doi: 10.1016/j.jcat.2010.03.016
9. [9]
  OYAMA S T. Novel catalysts for advanced hydroprocessing: Transition metal phosphides[J]. J Catal, 2003,216(1/2):343-352.
10. [10]
  LIA X, FENGA J P, GUO J Y, WANG A J, ROEL P, DUAN X P, CHEN Y Y. Preparation of Ni₂P/Al₂O₃ by temperature-programmed reduction of a phosphate precursor with a low P/Ni ratio[J]. J Catal, 2016,334(1):116-119.
11. [11]
  SONG Hua, DAI Min, SONG Hua-lin. Ni₂P catalyst for hydrodesulfurization[J]. Prog Chem, 2012,24(5):43-47.
12. [12]
  ABU I I, SMITH K J. HDN and HDS of model compounds and light gas oil derived from Athabasca bitumen using supported metal phosphide catalysts[J]. Appl Catal A: Gen, 2007,328(1):58-67. doi: 10.1016/j.apcata.2007.05.018
13. [13]
  MOON J S, KIM E G, LEE Y K. Active sites of Ni₂P/SiO₂catalyst for hydrodeoxygenation of guaiacol: A joint XAFS and DFT study[J]. J Catal, 2014,311:144-152. doi: 10.1016/j.jcat.2013.11.023
14. [14]
  LEE Y K, SHU Y Y, OYAMA S T. Active phase of a nickel phosphide (Ni₂P) catalyst supported on KUSY zeolite for the hydrodesulfurization of 4, 6-DMDBT[J]. Appl Catal A: Gen, 2007,322:191-204. doi: 10.1016/j.apcata.2007.01.007
15. [15]
  SONG Hua, WANG Zi-dong, DAI Min, SONG Hua-lin, WAN Xia, LI Feng. Preparation of Ni₂P catalysts at low reduction temperature and its HDS performance[J]. J Fuel Chem Technol, 2014,42(6):733-737.
16. [16]
  MELéNDEZ-ORTIZ H I, GARCíA-CERDA L A, OLIVARES-MALDONADO Y, CASTRUITA G, MERCADO-SILVA J A, PERERA-MERCADO Y A. Preparation of spherical MCM-41 molecular sieve at room temperature: Influence of the synthesis conditions in the structural properties[J]. Ceram Int, 2012,38(8):6353-6358. doi: 10.1016/j.ceramint.2012.05.007
17. [17]
  CECILIA J A, INFANTES-MOLINA E, RODRÍGUEZ-CASTELLÓN A, JIMÉNEZ-LÓPEZ A. A novel method for preparing an active nickel phosphide catalyst for HDS of dibenzothiophene[J]. J Catal, 2009,263(1):4-15. doi: 10.1016/j.jcat.2009.02.013
18. [18]
  BUI P, JUAN A C, OYAMA S T, TAKAGAKI A, INFANTES-MOLINA A, ZHAO H Y, LI D, RODRIGUEZ-CASTELLON E, LÓPEZ A J. Studies of the synthesis of transition metal phosphides and their activity in the hydrodeoxygenation of a biofuel model compound[J]. J Catal, 2012,294:184-198. doi: 10.1016/j.jcat.2012.07.021
19. [19]
  LAYMAN K A, BUSSELL M E. Infrared spectroscopic investigation of CO adsorption on silica-supported nickel phosphide catalysts[J]. J Phys Chem B, 2004,108:10930-10941. doi: 10.1021/jp037101e
20. [20]
  WU S K, LAI P C, LIN Y C. Atmospheric hydrodeoxygenation of guaiacol over alumina-, zirconia-, and silica-supported nickel phosphide catalysts[J]. ACS Sustain Chem Eng, 2013,1:349-358. doi: 10.1021/sc300157d
21. [21]
  LIU P, RODRIGUEZ J A. Water-gas-shift reaction on a Ni₂P (001) catalyst: Formation of oxy-phosphides and highly active reaction sites[J]. J Catal, 2009,262(2):294-303. doi: 10.1016/j.jcat.2009.01.006
22. [22]
  OKAMOTO H. Hydrodeoxygenation of benzofuran and its oxygenated derivatives (2, 3-dihydrobenzofuran and 2-ethylphenol) over NiMoP/Al₂O₃ catalyst[J]. J Catal, 2009,353(1):46-53.
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1.
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