Citation: SONG Hua, DAI Xue-ya, GONG Jing, SONG Hua-lin, LIU Yan-xiu, LI Feng. Preparation of supported nickel phosphide catalyst by surface modification method and its performance in hydrodeoxygenation[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(9): 1105-1111. shu

Preparation of supported nickel phosphide catalyst by surface modification method and its performance in hydrodeoxygenation

SONG Hua ^1,*,, ,
DAI Xue-ya ¹ ,
GONG Jing ¹ ,
SONG Hua-lin ² ,
LIU Yan-xiu ¹ ,
LI Feng ¹

1.
College of Chemistry & Chemical Engineering, Northeast Petroleum University, Daqing 163318, China
2.
Provincial Key Laboratory of Oil & Gas Chemical Technology, Northeast Petroleum University, Daqing 163318, China

Corresponding author: SONG Hua, songhua2004@sina.com
Received Date: 24 March 2016
Revised Date: 7 May 2016

Fund Project: the National Natural Science Foundation of China 21276048the Natural Science Foundation of Heilongjiang Province of China ZD201201the Project of Education Department of Heilongjiang Province 12541060

Figures(5)

With MCM-41 as support, the supported Ni₂P/MCM-41 catalyst is prepared by first reducing the Ni₂P precursors at low temperature (673 K) and then modifying the surface with air; the as-prepared Ni₂P/MCM-41 catalyst was characterized by X-ray diffraction (XRD), N₂-sorption, scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray photoelectron spectroscopy (XPS) and CO uptake. The catalytic performance of Ni₂P/MCM-41 in hydrodeoxygenation (HDO) of benzofuran (BF) was investigated to elucidate the effect of surface modification with air on the catalyst structure and HDO activity. The results show that pure Ni₂P acts as the active phase on the surface of modified Ni₂P/MCM-41 catalyst; the surface modification can decrease the aggregation of P species and promote the formation of small and highly dispersed Ni₂P active phase. Under 573 K, 3.0 MPa, a weight hourly space velocity of 4.0 h^-1 and a H₂/oil volume ratio of 500, the yield of O-free products reaches 88% for HDO of BF over the modified Ni₂P/MCM-41 catalyst, which is about 50% higher than that over the catalyst prepared by conventional temperature-programmed reduction method.
- surface modification,
- Ni₂P,
- MCM-41,
- benzofuran (BF),
- hydrodeoxygenation (HDO)
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