Citation: ZHANG Qiang, YU Peng-qiu, LI Lin, LE Zhi-ping. Preparation of 5-HMF from cellulose catalyzed by SnCl₄ under microwave in ZnCl₂ solution[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(3): 317-322. shu

Preparation of 5-HMF from cellulose catalyzed by SnCl₄ under microwave in ZnCl₂ solution

College of Chemistry, Nanchang University, Nanchang 330031, China

Corresponding author: LE Zhi-ping, zple@ncu.edu.cn
Received Date: 23 August 2016
Revised Date: 4 January 2017

Fund Project: the National Natural Science Foundation of China 21466021

Figures(7)

Conversion of cellulose into 5-hydroxymethylfurfural (5-HMF) catalyzed by SnCl₄ in ZnCl₂ solution with microwave was studied. The effects of microwave power, cellulose content, concentration of ZnCl₂, reaction time and the molar ratio of SnCl₄ to cellulose on the yields of 5-HMF were investigated. The results showed that under the optimum reaction condition of 1.0 g cellulose dissolved in 100 mL 70% ZnCl₂ solution, the molar ratio of SnCl₄ to cellulose of 2:1, the microwave power of 420 W, and the reaction time of 9 min, the yield of 5-HMF reaches 39.4%.
- microwave,
- cellulose,
- ZnCl₂ solution,
- SnCl₄,
- 5-HMF
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Preparation of 5-HMF from cellulose catalyzed by SnCl₄ under microwave in ZnCl₂ solution