Citation: Zhao Yan, Xu Qing, Fu Yao, Liu Yin. Preliminary study on Preparation of High-Quality Transportation Fuels from Lignin[J]. Chemistry, ;2017, 80(3): 278-282. shu

Preliminary study on Preparation of High-Quality Transportation Fuels from Lignin

Zhao Yan ^1, ,
Xu Qing ² ,
Fu Yao ² ,
Liu Yin ¹

1.
School of Materials Science and Engineering, Anhui University of Science and Technology, Huainan 232001
2.
Anhui Province Key Laboratory of Biomass Clean Energy, Department of Chemistry, University of Science and Technology of China, Hefei 230026

Received Date: 30 August 2016
Accepted Date: 13 November 2016

Figures(5)

Lignin as an abundant natural renewable resource is the ideal feedstock for the production of liquid transportation fuels. In this work a method for the production of liquid transportation fuels from lignin was studied. First, lignin monomer model was oxidized to obtain aromatic aldehyde under the catalysis of K-OMS-2. The lignin dimer model (α-O-4 structure lignin dimer) was oxidized and depolymerized to obtain the aromatic aldehyde in 65% yield. Meanwhile, by oxidizing alkali lignin, vanillin, p-hydroxybenzaldehyde and other aromatic aldehyde compounds can be detected from the product. Then, the length of the carbon chain was increased by Claisen-Schmidt condensation reaction of aromatic aldehydes and acetone. Finally, high-grade saturated alkane fuel was obtained by hydrogenation of aromatic hydrocarbons.
- Lignin,
- Oxidation,
- Condensation,
- Hydrogenation
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