Citation: WAN Xiao-rui, CHU Chun-yu, BAI Guo-qiang, GAO Shi-liang, MENG Xiu-hong, DUAN Lin-hai. Adsorption and mass transfer behavior of benzene on hierarchically structured Y by acid-base treatment[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(5): 634-640. shu

Adsorption and mass transfer behavior of benzene on hierarchically structured Y by acid-base treatment

Key Laboratory of Petrochemical Catalytic Science and Technology of Liaoning Province, Liaoning Shihua University, Fushun 113001, China

Corresponding author: DUAN Lin-hai, lhduan@126.com
Received Date: 16 December 2015
Revised Date: 28 February 2016

Fund Project: the National Natural Science Foundation of China 21476101

Figures(9)

A series of hierarchical NaY zeolites with different pore size distribution were synthesized by sequential treatment with ethylenediaminetetraacetic acid and NaOH. The structural properties of the as-synthesized hierarchical NaY zeolites were characterized by X-ray diffraction, N₂ sorption, SEM and TEM. The adsorption and diffusion performances of benzene on NaY and hierarchical NaY zeolites were studied by frequency response (FR) and intelligent gravimetric analyser (IGA). It was found that the structure of NaY zeolite was remained by suitable acid and base treatment, but the connectivity in the pores was finely tailored. Mesoporous was introduced to reduce the molecular diffusion resistance in the pores, while the larger pore size and connectivity in the mesoporous was more beneficial to diffusion and accessibility of activity site. The adsorption of benzene on NaY was found to be the rate-controlling step. While, the limiting steps for the overall mass transfer processes in the hierarchical zeolites are the diffusion process in the length scale of micropore/mesopore and the mass transfer at the micropore-mesopore molecular exchange rather than the intracrystalline diffusion one in the micropores of the zeolite crystals.
- hierarchical porous Y,
- benzene,
- frequency response,
- adsorption and diffusion
1. [1]
  PARK D H, KIM S S, WANG H, PINAVAIA T J, PAPAPETROU M C, LAPPAS A A, TRIANTAFYLLIDIS K S. Selective petroleum refining over a zeolite catalyst with small intracrystal mesopores[J]. Angew Chem Int Ed Eng, 2009,48(41):7645-7648. doi: 10.1002/anie.v48:41
2. [2]
  FLEISCH T H, MEYERS B L, RAY G J, HALL J B, MARSHALL C L. Hydrothermal dealumination of faujasites[J]. J Catal, 1986,99(86):117-125.
3. [3]
  WANG Q L, GIANNETTO G, TORREALBA M, PEROT G, KAPPENSTEIN C, GUISNET M. Dealumination of zeolites Ⅱ. Kinetic study of the dealumination by hydrothermal treatment of a NH₄NaY zeolite[J]. J Catal, 1991,130(2):459-470. doi: 10.1016/0021-9517(91)90128-Q
4. [4]
  LIU Xing-yun, ZHANG Xu-zheng, LI Xuan-wen. NaY zeolite acid dealumination[J]. Chem Res Chin Univ, 1997,18(3):342-347.
5. [5]
  PU X, SHI L, LIU N W. Acid properties and catalysis of USY zeolite with different extra-framework aluminum concentration[J]. Microporous Mesoporous Mater, 2015,201:17-23. doi: 10.1016/j.micromeso.2014.08.056
6. [6]
  QIN Z X, SHEN B J, YU Z W, DENG F, ZHAO L, ZHOU S G, YUAN D L, GAO X H, WANG B J, ZHAO H J, LIU H H. A defect-based strategy for the preparation of mesoporous zeolite Y for high-performance catalytic cracking[J]. J Catal, 2013,298:102-111. doi: 10.1016/j.jcat.2012.11.023
7. [7]
  VERBOEKEND D, KELLER T C, MITCHELL S, PEREZ-RAMIREZ J. Hierarchical FAU-and LTA-type zeolites by post-synthetic design: A new generation of highly efficient base catalysts[J]. Adv Funct Mater, 2013,23(15):1923-1934. doi: 10.1002/adfm.v23.15
8. [8]
  VERBOEKEND D, VILE G, PEREZ-RAMIREZ J. Hierarchical Y and USY zeolites designed by post-synthetic strategies[J]. Adv Funct Mater, 2012,22(5):916-928. doi: 10.1002/adfm.v22.5
9. [9]
  TIAN F P, SHEN Q C, FU Z K, WU Y H, JIA C Y. Enhanced adsorption desulfurization performance over hierarchically structured zeolite Y[J]. Fuel Process Technol, 2014,128:176-182. doi: 10.1016/j.fuproc.2014.07.018
10. [10]
  SUN H Y, SUN L P, LI F, ZHANG L. Adsorption of benzothiophene from fuels on modified NaY zeolites[J]. Fuel Process Technol, 2015,134:284-289. doi: 10.1016/j.fuproc.2015.02.010
11. [11]
  ZHAO J, YIN Y C, LI Y, CHEN W Y, LIU B J. Synthesis and characterization of mesoporous zeolite Y by using block copolymers as templates[J]. Chem Eng J, 2016,284:405-411. doi: 10.1016/j.cej.2015.08.143
12. [12]
  KORTUNOV P, VASENKOV S, KARGER J, VALIULLIN R, GOTTSCHALK P, ELIA MF, PEREZ M, STOCKER M, DRESCHER B, MCELHINEY G, BERGER C, GLASER R, WEITKAMP J. The role of mesopores in intracrystalline transport in USY zeolite: PFG NMR diffusion study on various length scales[J]. J Am Chem Soc, 2005,127(37):13055-13059. doi: 10.1021/ja053134r
13. [13]
  QIN Z X, SHEN B J, GAO X H, LIN F, WANG B J, XU C M. Mesoporous Y zeolite with homogeneous aluminum distribution obtained by sequential desilication-dealumination and its performance in the catalytic cracking of cumene and 1, 3, 5-triisopropylbenzene[J]. J Catal, 2011,278(2):266-275. doi: 10.1016/j.jcat.2010.12.013
14. [14]
  BOURDIN V, GRAY P G, GRENIER P, TERRIER M F. An apparatus for adsorption dynamics studies using infrared measurement of the adsorbent temperature[J]. Rev Sci Instrum, 1998,69(5):2130-2136. doi: 10.1063/1.1148911
15. [15]
  SONG L J, SUN Z L, REES L V C. Studies of adsorption, diffusion and molecular simulation of cyclic hydrocarbons in MFI zeolites[J]. Stud Surf Sci Catal, 2001,135:3064-3072.
1. [1]
  Xuefei Zhao , Xuhong Hu , Zhenhua Jia . 理论与计算化学在傅-克烷基化反应教学中的应用. University Chemistry, 2025, 40(8): 360-367. doi: 10.12461/PKU.DXHX202410008
2. [2]
  Ling Liu , Haibin Wang , Genrong Qiang . Curriculum Ideological and Political Design for the Comprehensive Preparation Experiment of Ethyl Benzoate Synthesized from Benzyl Alcohol. University Chemistry, 2024, 39(2): 94-98. doi: 10.3866/PKU.DXHX202304080
3. [3]
  Feng Sha , Xinyan Wu , Ping Hu , Wenqing Zhang , Xiaoyang Luan , Yunfei Ma . Design of Course Ideology and Politics for the Comprehensive Organic Synthesis Experiment of Benzocaine. University Chemistry, 2024, 39(2): 110-115. doi: 10.3866/PKU.DXHX202307082
4. [4]
  Wanmin Cheng , Juan Du , Peiwen Liu , Yiyun Jiang , Hong Jiang . Photoinitiated Grignard Reagent Synthesis and Experimental Improvement in Triphenylmethanol Preparation. University Chemistry, 2024, 39(5): 238-242. doi: 10.3866/PKU.DXHX202311066
5. [5]
  Liangzhen Hu , Li Ni , Ziyi Liu , Xiaohui Zhang , Bo Qin , Yan Xiong . A Green Chemistry Experiment on Electrochemical Synthesis of Benzophenone. University Chemistry, 2024, 39(6): 350-356. doi: 10.3866/PKU.DXHX202312001
6. [6]
  Shahua Huang , Xiaoming Guo , Lin Lin , Guangping Chang , Sheng Han , Zuxin Zhou . Application of “Integration of Industry and Education” in Engineering Chemistry: Improvement of the Pesticide Fipronil Production. University Chemistry, 2024, 39(3): 199-204. doi: 10.3866/PKU.DXHX202309064
7. [7]
  Jingyu Cai , Xiaoyu Miao , Yulai Zhao , Longqiang Xiao . Exploratory Teaching Experiment Design of FeOOH-RGO Aerogel for Photocatalytic Benzene to Phenol. University Chemistry, 2024, 39(4): 169-177. doi: 10.3866/PKU.DXHX202311028
8. [8]
  Tianqi Bai , Kun Huang , Fachen Liu , Ruochen Shi , Wencai Ren , Songfeng Pei , Peng Gao , Zhongfan Liu . Nanoscale Mechanism of Microstructure-Dependent Thermal Diffusivity in Thick Graphene Sheets. Acta Physico-Chimica Sinica, 2025, 41(3): 2404024-0. doi: 10.3866/PKU.WHXB202404024
9. [9]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
10. [10]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
11. [11]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
12. [12]
  Jian Jin , Jing Cheng , Xueping Yang . Integration Practice of Organic Chemistry Experiment and Safety Education: Taking the Synthesis of Triphenylmethanol as an Example. University Chemistry, 2024, 39(3): 345-350. doi: 10.3866/PKU.DXHX202309010
13. [13]
  Tao Cao , Fang Fang , Nianguang Li , Yinan Zhang , Qichen Zhan . Green Synthesis of p-Hydroxybenzonitrile Catalyzed by Spinach Extracts under Red-Light Irradiation: Research and Exploration of Innovative Experiments for Pharmacy Undergraduates. University Chemistry, 2024, 39(5): 63-69. doi: 10.3866/PKU.DXHX202309098
14. [14]
  Guodong Xu , Chengcai Sheng , Xiaomeng Zhao , Tuojiang Zhang , Zongtang Liu , Jun Dong . Reform of Comprehensive Organic Chemistry Experiments in the Context of Emerging Engineering Education: A Case Study on the Improved Preparation of Benzocaine. University Chemistry, 2024, 39(11): 286-295. doi: 10.12461/PKU.DXHX202403094
15. [15]
  Feng Han , Fuxian Wan , Ying Li , Congcong Zhang , Yuanhong Zhang , Chengxia Miao . Comprehensive Organic Chemistry Experiment: Phosphotungstic Acid-Catalyzed Direct Conversion of Triphenylmethanol for the Synthesis of Oxime Ethers. University Chemistry, 2025, 40(3): 342-348. doi: 10.12461/PKU.DXHX202405181
16. [16]
  Jichao XU , Ming HU , Xichang CHEN , Chunhui WANG , Leichen WANG , Lingyi ZHOU , Xing HE , Xiamin CHENG , Su JING . Construction and hydrogen peroxide-activated chemodynamic activity of ferrocene?benzoselenadiazole conjugate. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1495-1504. doi: 10.11862/CJIC.20250144
17. [17]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
18. [18]
  Qianping Li , Hua Guan , Changfeng Wan , Yonghai Song , Jianwen Jiang . 大学有机化学复习课项目式教学——以“液晶化合物4-正戊基苯甲酸-4′-正戊基苯酯的合成路线设计与产品制备”为例. University Chemistry, 2025, 40(8): 100-116. doi: 10.12461/PKU.DXHX202410070
19. [19]
  Yanglin Jiang , Mingqing Chen , Min Liang , Yige Yao , Yan Zhang , Peng Wang , Jianping Zhang . Experimental and Theoretical Investigations of Solvent Polarity Effect on ESIPT Mechanism in 4′-N,N-diethylamino-3-hydroxybenzoflavone. Acta Physico-Chimica Sinica, 2025, 41(2): 2309027-0. doi: 10.3866/PKU.WHXB202309027
20. [20]
  Yuting Bai , Cenqi Yan , Zhen Li , Jiaqiang Qin , Pei Cheng . Preparation of High-Strength Polyimide Porous Films with Thermally Closed Pore Property by In Situ Pore Formation Method. Acta Physico-Chimica Sinica, 2024, 40(9): 2306010-0. doi: 10.3866/PKU.WHXB202306010

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(1463)
HTML views(196)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142