Citation: CHEN Guang-hui, LI Yu, ZHANG Chang-sen, ZHANG Rui-qin. Influence of CeO₂ on the carbonaceous deposition behavior of Ni-Cu/HZSM-5 catalyst in the hydrodeoxygenation of bio-oil[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(4): 449-457. shu

Influence of CeO₂ on the carbonaceous deposition behavior of Ni-Cu/HZSM-5 catalyst in the hydrodeoxygenation of bio-oil

College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China

Corresponding author: ZHANG Rui-qin, rqzhang@zzu.edu.cn
Received Date: 30 December 2016
Revised Date: 4 February 2017

Fund Project: the Henan Science and Technology Cooperation and Open Project 142106000046

Figures(7)

The influence of CeO₂ as an additive on the carbonaceous deposition behavior of Ni-Cu/H-ZSM-5 catalyst in the hydrodeoxygenation (HDO) of bio-oil was investigated. Various techniques such as thermogravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS), and Raman spectroscopy were used to elucidate the content and microstructure of carbon deposited on the catalyst surface, the transformation of various forms of carbon (soft carbon, hard carbon and graphite) in HDO, and the kinetics of carbon deposition. The results indicate that the content of CeO₂ added in the Ni-Cu based catalyst and the reaction temperature both have a significant influence on the carbon deposition behavior and the resistance against coking for HDO of bio-oil; for HDO over the Ni-Cu/HZSM-5 catalyst at 270℃, adding 15% CeO₂ gives the Ni-Cu catalyst highest resistance against the carbon deposition.
- bio-oil,
- hydrodeoxygenation,
- Ni-Cu/HZSM-5,
- coke deposition,
- CeO₂
1. [1]
  LI Y, ZHANG C, LIU Y, ZHAI Y, ZHANG R. Coke deposition on Ni/HZSM-5 in bio-oil hydrodeoxygenation processing[J]. Energy Fuels, 2015,28(1):52-57.
2. [2]
  RAMZI F, MAX G M, MAIK E, MAIKE H, WIEBKE F, JASMIN A, FRANK G, LAÁSZLOÓ S, NUÚRIA L, DETRE T. Promoted ceria:A structural, catalytic, and computational study[J]. ACS Catal, 2013,3:2256-68. doi: 10.1021/cs4005002
3. [3]
  SONG Yi-bing, YU Lin, SUN Chang-yong, YE Fei, FANG Yi-wen, LIN Wei-ming. Effect of Ce promoteron activity and stability of Ce-Ni/Al₂O₃ in partial oxidation of methane and CO₂ reforming of methane to synga[J]. Chin J Catal, 2002,23(3):267-270.
4. [4]
  SRISIRIWAT N, THERDTHIANWONG S, THERDTHIANWONG A. Oxidative steam reforming of ethanol over Ni/Al₂O₃ catalysts promoted by CeO₂, ZrO₂ and CeO₂-ZrO₂[J]. Int J Hydrogen Energy, 2009,34(5):2224-2234. doi: 10.1016/j.ijhydene.2008.12.058
5. [5]
  MAGNOUX P, MACHADO F, GUISNET M. Mechanism of coke formation during the transformation of propene, toluene and propene-toluene mixture on HZSM-5[J]. Stud Surf Sci Catal, 1993,75:435-447. doi: 10.1016/S0167-2991(08)64029-X
6. [6]
  XU X, ZHANG C, LIU Y, ZHAI Y, ZHANG R. Two-step catalytic hydrodeoxygenation of fast pyrolysis oil to hydrocarbon liquid fuels[J]. Chemosphere, 2013,93(4):652-660. doi: 10.1016/j.chemosphere.2013.06.060
7. [7]
  ZHANG X, WANG T, MA L, ZHANG Q, JIANG T. Hydrotreatment of bio-oil over Ni-based catalyst[J]. Bioresour Technol, 2013,127:306-311. doi: 10.1016/j.biortech.2012.07.119
8. [8]
  ZHANG H, SHAO S, XIAO R, SHEN D, ZENG J. Characterization of coke deposition in the catalytic fast pyrolysis of biomass derivates[J]. Energy Fuels, 2014,28(1):52-57. doi: 10.1021/ef401458y
9. [9]
  MOLJORD K, MAGNOUX P, GUISNET M. Coking, aging and regeneration of zeolites XV. Influence of the composition of HY zeolites on the mode of formation of coke from propene at 450℃[J]. Appl Catal A:Gen, 1995,122(1):21-32. doi: 10.1016/0926-860X(94)00210-X
10. [10]
  YANG X, XU S, CHEN Z, LIU J. Improved nickel-olivine catalysts with high coking resistance and regeneration ability for the steam reforming of benzene[J]. React Kinet Mech Catal, 2012,108(2):459-472.
11. [11]
  PARK J W, SEO G. IR study on methanol-to-olefin reaction over zeolites with different pore structures and acidities[J]. Appl Catal A:Gen, 2009,356(2):180-188. doi: 10.1016/j.apcata.2009.01.001
12. [12]
  GUICHARD B, ROY-AUBERGER M, DEVERS E, REBOURS B, QUOINEAUD A A, DIGNE M. Characterization of aged hydrotreating catalysts. Part Ⅰ:Coke depositions, study on the chemical nature and environment[J]. Appl Catal A:Gen, 2009,367(1/2):1-8.
13. [13]
  CASTAÑO P, ELORDI G, OLAZAR M, ANDRES T, AGUAYO B P. Insights into the coke deposited on HZSM-5, Hβ and HY zeolites during the cracking of polyethylene[J]. Appl Catal B:Environ, 2011,104(1/2):91-100.
14. [14]
  VOGELAAR B M, VAN LANGEVELD A D, EIJSBOUTS S, MOULIJN J A. Analysis of coke deposition profiles in commercial spent hydroprocessing catalysts using Raman spectroscopy[J]. Fuel, 2007,86(7/8):1122-1129.
15. [15]
  ROBERTSON J. Diamond-like amorphous carbon[J]. Mater Sci Eng, R, 2002,37(4):129-281.
16. [16]
  WRAGG D S, JOHNSEN R E, BALASUNDARAM M, NORBY P, FUGLERUD T. SAPO-34 methanol-to-olefin catalysts under working conditions:A combined in situ powder X-ray diffraction, mass spectrometry and Raman study[J]. J Catal, 2009,268(2):290-296.
17. [17]
  TUINSTRA F. Raman spectrum of graphite[J]. J Chem Phys, 1970,53(3)1126. doi: 10.1063/1.1674108
18. [18]
  TAO G. The XPS analysis of surface texture of different-density-level coking coal of fenxi county[J]. Int J Oil, Gas Coal Eng, 2014,2(4):59-65. doi: 10.11648/j.ogce.20140204.12
19. [19]
  MORENO-CASTILLA C, LOPEZ-RAMON M, CARRASCO-MARIN F. Changes in surface chemistry of activated carbons by wet oxidation[J]. Carbon, 2000,38(14):1995-2001. doi: 10.1016/S0008-6223(00)00048-8
20. [20]
  YAO Su-ling, YANG Cai-hong, TAN Yi-sheng, HAN Yi-zhuo. Deactivation of activated carbon supported nickel-palladium catalyst for vapor phase carbonylation of methanol[J]. J Fuel Chem Technol, 2006,34(6):706-711. doi: 10.1016/S1872-5813(07)60006-1
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Influence of CeO2 on the carbonaceous deposition behavior of Ni-Cu/HZSM-5 catalyst in the hydrodeoxygenation of bio-oil

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通讯作者: 陈斌, bchen63@163.com

Influence of CeO₂ on the carbonaceous deposition behavior of Ni-Cu/HZSM-5 catalyst in the hydrodeoxygenation of bio-oil