Citation: E Liu, Xiaoguang Dong, Xiaojing Liu, Aiquan Jia, Ziyu Guo, Huiling Liu, Xiaoshuang Guo, Qianfeng Zhang. Dinuclear Copper-Dipyridyl Water Cluster Complex with Host Dragonfly-Like Structure[J]. Chemistry, ;2021, 84(1): 58-62. shu

Dinuclear Copper-Dipyridyl Water Cluster Complex with Host Dragonfly-Like Structure

E Liu ^{1, 2, 3,,} ,
Xiaoguang Dong ² ,
Xiaojing Liu ² ,
Aiquan Jia ¹ ,
Ziyu Guo ² ,
Huiling Liu ² ,
Xiaoshuang Guo ² ,
Qianfeng Zhang ^1,,

1.
Institute of Molecular Engineering and Applied Chemistry, Anhui University of Technology, Ma'anshan, 243002
2.
School of Chemical Engineering and Pharmaceutics, Henan University of Science and Technology, Luoyang, 471023
3.
LuoYang Heke University Renewable Energy Co. LTD, Luoyang, 471023)

Corresponding author: E Liu, 798233143@haust.edu.cn Qianfeng Zhang, zhangqf@ahut.edu.cn
Received Date: 8 July 2020
Accepted Date: 28 August 2020

Figures(7)

This paper introduces a simple method to synthesize[Cu₂(bipy)₂(H₂P₂O₇)(OH)₂]·7H₂O binuclear copper water cluster complex. The crystal structure analysis indicated that seven crystal waters form a two-dimensional water cluster polymer[(H₂O)₇]_n, and the water cluster then forms a strong hydrogen bond with the hydroxyl group in the core structure. The structure of the whole complex resembles a dragonfly. Through the research of this kind of water cluster polymer, it is helpful for improving the modelling of some of the unexplained properties of water and better understanding the structure and behaviour of water molecules in chemical and biological process.
- Pyrophosphate,
- Water cluster,
- Dipyridyl,
- Hydrogen-bond,
- Dragonfly-like structure
1. [1]
  Shah R D T, Sharma S, Bharati L. Ecol. Indic., 2020, 108: 105735~105743.
2. [2]
  Kemmler L, Ibrahim M, Dobbek H, et al. Phys. Chem. Chem. Phys., 2019, 21: 25449~25466.
3. [3]
  Ghosh S K, Bharadwaj P K. Angew. Chem., 2004, 116(27): 3661~3664.
4. [4]
  Vaillant C L, Wales D J, Althorpe S C. J. Phys. Chem. Lett., 2019, 10(22): 7300~7304.
5. [5]
  Doedens R J, Yohannes E, Khan M I. Chem. Commun., 2002, 1: 62~63.
6. [6]
  Sun D, Xu H R, Yang C F. Cryst. Growth Des., 2010, 10(10): 4642~4649.
7. [7]
  Luo G G, Xiong H B, Dai J C. Cryst. Growth Des., 2011, 11(2): 507~515.
8. [8]
  Luo G G, Xiong H B, Sun D, et al. Cryst. Growth Des., 2011, 11(5): 1948~1956.
9. [9]
  Luo G G, Wu D L, Wu J H, et al. Cryst. Growth Des., 2012, 14: 5377~5380.
10. [10]
  Assaf K I, Ural M S, Pan F F, et al. Angew. Chem. Int. Ed., 2015, 54(23): 6942~6956.
11. [11]
  Desiraju G R. Chem. Commun., 1991, (6): 426~428.
12. [12]
  Son H S, Hong B H, Lee C W, et al. J. Am. Chem. Soc., 2001, 123(3): 514~515.
13. [13]
  Ghosh S K, Bharadwaj P K. Angew. Chem. Int. Ed., 2004, 43(34): 3577~3580.
14. [14]
  Oxtoby N S, Blake A J, Champness N R, et al. Chem. Eur. J., 2005, 11(16): 4643~4654.
15. [15]
  Infantes L, Chisholm J, Motherwell S. CrystEngComm, 2003, 5(85): 480~486.
16. [16]
  Mascal M, Infantes L, Chisholm J. Angew. Chem. Int. Ed., 2006, 45(1): 32~36.
17. [17]
  Keutsch F N, Cruzan J D, Saykally R J. Chem. Rev., 2003, 103(7): 2533~2578.
18. [18]
  Miyazaki M, Fujii A, Ebata T, et al. Science, 2004, 304(5674): 1134~1137.
19. [19]
  Eisenberg D, Kauzmann W. The Structure and Properties of Water. Oxford University Press, 1969, 20(12): 527~531.
20. [20]
  X Pu, Gordon M S. J. Phys. Chem. A, 2014, 118(35): 7548~7559.
21. [21]
  Infantes L, Motherwell S. CrystEngComm, 2002, 4(75): 454~461.
1. [1]
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2. [2]
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13. [13]
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16. [16]
  Xianghe Kong , Xiaoli Liao , Zhenkun Huang , Lei Mei , Hongqing Wang , Kongqiu Hu , Weiqun Shi . Designed assembly of heterometallic cluster organic frameworks based on Th₆ cluster. Chinese Chemical Letters, 2024, 35(11): 109642-. doi: 10.1016/j.cclet.2024.109642
17. [17]
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19. [19]
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20. [20]
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