Citation: LI Zhen-hua, LIU Chen, XIE Chun-fang, WANG Wei-han, WANG Bao-wei, MA Xin-bin. Influence of water on the methanation performance of Mo-based catalyst[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(6): 689-696. shu

Influence of water on the methanation performance of Mo-based catalyst

Key Lab for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China

Corresponding author: WANG Wei-han, wangwh@tju.edu.cn
Received Date: 3 March 2017
Revised Date: 21 April 2017

Fund Project: the National High-Technology Research and Development Program of China 863 programthe National High-Technology Research and Development Program of China 2015AA050504the National Natural Science Foundation of China 21576203

Figures(8)

The effects of H₂O on the performance of the sulfur-resistant Mo-based methanation catalysts were investigated by adding vapor into the reactant gas at the reaction conditions of 550℃, 5 500 h^-1, 1.2% of H₂S concentration. The results indicate that water caused irreversible deactivation of Mo-based catalyst supported on Al₂O₃, while additive Co and cerium-aluminum composite carrier can enhance the activity and improve the stability of the Mo-based catalyst for methanation of syngas. The promoter Co protects the active phase MoS₂ of Mo-based catalyst, inhibits the irreversible deactivation caused by the addition of water. When the water content in reactant gas is increased, the water gas shift reaction increases and becomes the main reaction on catalysts, and the increase of water leads to further decrease of the catalyst activity and stability.
- sulfur-resistant methanation,
- Mo-based catalyst,
- water,
- water-gas shift,
- deactivation
1. [1]
  MIAO Xing-wang, WU Feng, ZHANG Shu-yi. Development status of coal-to-natural gas technology[J]. Danfei Jishu, 2010,31(1):6-8.
2. [2]
  LIU Zhi-guang, GONG Hua-jun, YU Li-ming. SNG development in China[J]. Coal Chem Ind, 2009,37(2):5-9+17.
3. [3]
  SAITO M, ANDERSON R B. The activity of several molybdenum compounds for the methanation of CO[J]. J Catal, 1980,11(36):296-302.
4. [4]
  KOPYSCINSKI J, SCHILDHAUER T J, BIOLLAZ S M A. Production of synthetic natural gas (SNG) from coal and dry biomass-a technology review from 1950 to 2009[J]. Fuel, 2010,89(8):1763-1783. doi: 10.1016/j.fuel.2010.01.027
5. [5]
  WANG Wei-han, LI Zhen-hua, WANG Bao-wei, XU Yan, MA Xin-bin. Recent advances in sulfur-resistant methanation[J]. CIESC J, 2015,66(9):3357-3366.
6. [6]
  GAO J, LIU Q, GU F, LIU B, ZHONG Z, SU F. Recent advances in methanation catalysts for the production of synthetic natural gas[J]. RSC Adv, 2015,5(29):22759-22776. doi: 10.1039/C4RA16114A
7. [7]
  GAO Y L, FANG X C, CHENG Z M. Development and application of ex-situ presulfurization technology for hydrotreating catalysts in China[J]. Front Chem Sci Eng, 2011,5(3):287-296. doi: 10.1007/s11705-010-0529-2
8. [8]
  WANG H Y, LI Z H, WANG E D, LIN C, SHANG Y G, DING G Z, MA X B, QIN S D, SUN Q. Effect of composite supports on the methanation activity of Co-Mo-based sulfur-resistant catalyst[J]. J Nat Gas Chem, 2012,21(6):767-773. doi: 10.1016/S1003-9953(11)60430-1
9. [9]
  BADAWI M, PAUL J F, CRISTOL S, PAYEN E, ROMERO Y, RICHARD F, BRUNET S, LAMBERT D, PORTIER X, POPOV A, KONDRATIEVA E, GOUPIL J M, FALLAH J EL, GILSON J P, MARIEY L, TRAVERT A, MAUGÉ F. Effect of water on the stability of Mo and CoMo hydrodeoxygenation catalysts: A combined experimental and DFT study[J]. J Catal, 2011,282(1):155-164. doi: 10.1016/j.jcat.2011.06.006
10. [10]
  WANG B W, DING G Z, SHANG Y G, LV J, WANG H Y, WANG E D, LI Z H, MA X B, QIN S D, SUN Q. Effects of MoO₃ loading and calcination temperature on the activity of the sulphur-resistant methanation catalyst MoO₃/ γ -Al₂O₃[J]. Appl Catal A: Gen, 2012,431-432(1):144-150.
11. [11]
  LIN C, WANG H Y, LI Z H, WANG B W, MA X B, QIN S D, SUN Q. Effect of a promoter on the methanation activity of Mo-based sulfur-resistant catalyst[J]. Front Chem Sci Eng, 2013,7(1):88-94. doi: 10.1007/s11705-013-1301-1
12. [12]
  WANG X T, LIU G S, YU J G, RODRIGUES A E. Preparation, characterization and deactivation studies of Co-Mo/ γ -Al₂O₃ deoxidizing catalyst[J]. Appl Catal A: Gen, 2004,270(1):143-149.
13. [13]
  TOPSØE H, CLAUSEN B S, MASSOTH F E. A review of: "Hydrotreating catalysis science and technology"[J]. Fuel Sci Technol Int, 1996,14(10)1465. doi: 10.1080/08843759608947653
14. [14]
  KUHN M, RODRIGUEZ J A. Photoemission studies of S/Co/Mo(110) and S/Ni/Mo(110) surfaces: Co-and Ni-promoted sulfidation of Mo(110)[J]. Surf Sci, 1996,355(1/3):85-99.
15. [15]
  KOOYMAN P J, VAN VEEN J A R V. The detrimental effect of exposure to air on supported MoS₂[J]. Catal Today, 2008,130(1):135-138. doi: 10.1016/j.cattod.2007.07.019
16. [16]
  TOPSØE H. The role of Co-Mo-S type structures in hydrotreating catalysts[J]. Appl Catal A: Gen, 2007,322:3-8. doi: 10.1016/j.apcata.2007.01.002
17. [17]
  WANG B W, SHANG Y G, DING G Z, LV J, WANG H Y, WANG E D, LI Z H, MA X B, QIN S D, SUN Q. Effect of ceria-alumina composite support on the Mo-based catalyst sulfur-resistant activity for synthetic natural gas process[J]. React Kinet Mech Catal, 2012,106(2):495-506. doi: 10.1007/s11144-012-0452-2
18. [18]
  JIANG M H, WANG B W, YAO Y Q, WANG H Y, LI Z H, MA X B, QIN S D, SUN Q. The role of the distribution of Ce species on MoO₃/CeO₂-Al₂O₃ catalysts in sulfur-resistant methanation[J]. Catal Commun, 2013,35:32-35. doi: 10.1016/j.catcom.2013.02.008
19. [19]
  FERREIRA A P, ZANCHET D, ARAUJO J C S, LIBERATORI J W C, SOUZA-AGUIAR E F, NORONHA F B, BUENO J M C. The effects of CeO₂ on the activity and stability of Pt supported catalysts for methane reforming, as addressed by in situ temperature resolved XAFS and TEM analysis[J]. J Catal, 2009,263(2):335-344. doi: 10.1016/j.jcat.2009.02.026
20. [20]
  MYOUNG Y K, SEUNG B H, DONG J K, CHANGDAE B, EUN D P. CO methanation over supported Mo catalysts in the presence of H₂S[J]. Catal Commun, 2013,35(17):68-71.
1. [1]
  Shule Liu . Application of SPC/E Water Model in Molecular Dynamics Teaching Experiments. University Chemistry, 2024, 39(4): 338-342. doi: 10.3866/PKU.DXHX202310029
2. [2]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
3. [3]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
4. [4]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
5. [5]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371
6. [6]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
7. [7]
  Tengjiao Wang , Tian Cheng , Rongjun Liu , Zeyi Wang , Yuxuan Qiao , An Wang , Peng Li . Conductive Hydrogel-based Flexible Electronic System: Innovative Experimental Design in Flexible Electronics. University Chemistry, 2024, 39(4): 286-295. doi: 10.3866/PKU.DXHX202309094
8. [8]
  Jinyao Du , Xingchao Zang , Ningning Xu , Yongjun Liu , Weisi Guo . Electrochemical Thiocyanation of 4-Bromoethylbenzene. University Chemistry, 2024, 39(6): 312-317. doi: 10.3866/PKU.DXHX202310039
9. [9]
  Xuejie Wang , Guoqing Cui , Congkai Wang , Yang Yang , Guiyuan Jiang , Chunming Xu . 碳基催化剂催化有机液体氢载体脱氢研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-. doi: 10.1016/j.actphy.2024.100044
10. [10]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
11. [11]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
12. [12]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046
13. [13]
  Yuena Yang , Xufang Hu , Yushan Liu , Yaya Kuang , Jian Ling , Qiue Cao , Chuanhua Zhou . The Realm of Smart Hydrogels. University Chemistry, 2024, 39(5): 172-183. doi: 10.3866/PKU.DXHX202310125
14. [14]
  Zhaoxuan ZHU , Lixin WANG , Xiaoning TANG , Long LI , Yan SHI , Jiaojing SHAO . Application of poly(vinyl alcohol) conductive hydrogel electrolytes in zinc ion batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 893-902. doi: 10.11862/CJIC.20240368
15. [15]
  Xue Liu , Lipeng Wang , Luling Li , Kai Wang , Wenju Liu , Biao Hu , Daofan Cao , Fenghao Jiang , Junguo Li , Ke Liu . Cu基和Pt基甲醇水蒸气重整制氢催化剂研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100049-. doi: 10.1016/j.actphy.2025.100049
16. [16]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
17. [17]
  Fangxuan Liu , Ziyan Liu , Guowei Zhou , Tingting Gao , Wenyu Liu , Bin Sun . Hollow structured photocatalysts. Acta Physico-Chimica Sinica, 2025, 41(7): 100071-. doi: 10.1016/j.actphy.2025.100071
18. [18]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
19. [19]
  Lijuan Liu , Xionglei Wang . Preparation of Hydrogels from Waste Thermosetting Unsaturated Polyester Resin by Controllable Catalytic Degradation: A Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 313-318. doi: 10.12461/PKU.DXHX202403060
20. [20]
  Yaping Li , Sai An , Aiqing Cao , Shilong Li , Ming Lei . The Application of Molecular Simulation Software in Structural Chemistry Education: First-Principles Calculation of NiFe Layered Double Hydroxide. University Chemistry, 2025, 40(3): 160-170. doi: 10.12461/PKU.DXHX202405185

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(996)
HTML views(153)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142