Citation: LU Xue-ting, PU Yan-feng, LI Lei, ZHAO Ning, WANG Feng, XIAO Fu-kui. Preparation of metal-organic frameworks Cu₃(BTC)₂ with amino-functionalization for CO₂ adsorption[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(3): 338-343. shu

Preparation of metal-organic frameworks Cu₃(BTC)₂ with amino-functionalization for CO₂ adsorption

LU Xue-ting ^1,2 ,
PU Yan-feng ¹ ,
LI Lei ¹ ,
ZHAO Ning ^1,, ,
WANG Feng ^1,, ,
XIAO Fu-kui ¹

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: ZHAO Ning, zhaoning@sxicc.ac.cn WANG Feng, wangf@sxicc.ac.cn
Received Date: 8 November 2018
Revised Date: 24 December 2018

Fund Project: The project was supported by the National Natural Science Foundation of China (21306217, 21776294), Coal-Based Science and Technology Project of Shanxi Province (MD2014-09) and Natural Science Foundation of Shanxi Province (201601D102006, 201801D121070)Natural Science Foundation of Shanxi Province 201801D121070The project was supported by the National Natural Science Foundation of China 21776294The project was supported by the National Natural Science Foundation of China 21306217Natural Science Foundation of Shanxi Province 201601D102006Coal-Based Science and Technology Project of Shanxi Province MD2014-09

Figures(9)

The metal-organic framework of Cu₃(NH₂BTC)₂ was synthesized by solvothermal method with the prepared grafted amine-based trimesic acid as organic ligand. The synthesized adsorbent was characterized by XRD, N₂ adsorption-desorption, thermogravimetry, FT-IR and in-situ FT-IR. The performance of the CO₂ adsorption was studied by the breakthrough curve based on the fixed-bed reactor. The results showed that the amine groups had been successfully grafted into the skeleton of Cu₃(BTC)₂. The CO₂ adsorption capacity of Cu₃(NH₂BTC)₂ was improved to 1.41 mmol/g at 10 kPa and 50 ℃. The improvement of CO₂ uptake might due to the effect of both the physical and chemical adsorption of CO₂.
- amino-functionalized,
- Cu₃(BTC)₂,
- CO₂ adsorption
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Preparation of metal-organic frameworks Cu3(BTC)2 with amino-functionalization for CO2 adsorption

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Preparation of metal-organic frameworks Cu₃(BTC)₂ with amino-functionalization for CO₂ adsorption