Citation: Fang Xin FU, Xiu Juan LI, Hua De PAN, Yan XING, Yong Hua LIN. CRYSTAL AND MOLECULAR STRUCTURE OF THE COMPLEX OF METHOXYCARBONYLETHYLTIN TRICHLORIDE WITH SALICYLIDENE－M－TOLUIDINE[J]. Chinese Chemical Letters, ;1995, 6(1): 87-90. shu

CRYSTAL AND MOLECULAR STRUCTURE OF THE COMPLEX OF METHOXYCARBONYLETHYLTIN TRICHLORIDE WITH SALICYLIDENE－M－TOLUIDINE

a Department of Chemistry, Northeast Normal University, Changchun 130024;
b Changchun Applied Chemistry Institute Academy Sinica, Changchun 130022

Received Date: 23 August 1994

The synthesis and properties of the title complex CH₃OCOCH₂CH₂SnCl₃·2-HOC₆H₄CH=NC₆H₄-3'-CH₃ are described.It crystallizes from benzene in the monoclinic space group P2_1/n with unit cell dimensions a=10.326(3),b=6.815(8),c=12.931(6) Å,β=111.52(3)°,V=2088.7(1)Å ³,Z=4,F(000)=1040,μ=16.31 cm^-1,Dc=l.67g/cm³ final R factor is 0.037 for 3177 observed reflections,I≥3σ( I_o).The tin atom in the structure of the complex exists in a distored octahedral geometry defined by three Cl atoms,the C and O atoms of a chelating methoxycarbonylethyl group as well as an O atom derived from the Schiff base ligand.
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