Citation: Chen Xin CAI, Huang-Xian JU, Hong Yuan CHEN. ELECTROCATALYSIS OF NICKEL HEXACYANOFERRATE MODIFIED MICROBAND GOLD ELECTRODE FOR OXIDATION OF REDUCED NICOTINAMIDE ADENINE DINUCLEOTIDE[J]. Chinese Chemical Letters, ;1995, 6(6): 501-504. shu

ELECTROCATALYSIS OF NICKEL HEXACYANOFERRATE MODIFIED MICROBAND GOLD ELECTRODE FOR OXIDATION OF REDUCED NICOTINAMIDE ADENINE DINUCLEOTIDE

Department of Chemistry, Nanjing University, Naming 210093

Received Date: 18 October 1994

Fund Project: The project was supported by the National Natural Science Foundation of China.

A nickel hexacyanoferrate modifled microband gold electrode, which can be prepared by cyclic voltammetry, exhibits excellent electrocatalytic activity for NADH oxidation with an overpotential ca.340mV lower than that at the bare electrode.Quantitative analysis of the electrocatalytic reaction based on rotating disk voltammetry gives a rate constantk of the order of 10³ L·mol^-1·s^-1.
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