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Citation: Hong Chen, Yue Wang, Wenting Zhang, Yu Zhu, Jianrong Li. Determination of Ciprofloxacin by Electrochemical Sensor Based on Metal Organic Framework Material[J]. Chemistry, ;2021, 84(2): 167-171. shu

Determination of Ciprofloxacin by Electrochemical Sensor Based on Metal Organic Framework Material

Hong Chen ^{1, 2,,} ,
Yue Wang ¹ ,
Wenting Zhang ¹ ,
Yu Zhu ¹ ,
Jianrong Li ^2,,

1.
College of Chemistry and Materials Engineering
2.
Food Science Research Institute, Bohai University, Jinzhou, 121013

Corresponding author: Hong Chen, redastar@163.com Jianrong Li, lijr6491@163.com
Received Date: 24 May 2020
Accepted Date: 20 September 2020

Figures(7)

Cobalt-terephthalic acid metal organic framework material (Co(BDC)) was synthesized through a hydrothermal method and characterized by scanning electron microscope and infrared spectrum. The hybrid material of Co(BDC) and sodium polyacrylate (PAAS) was cast on a glassy carbon electrode (GCE) to get a modified electrode Co(BDC)-PAAS/GCE for the electrochemical detection of CIP. The electrochemical study showed that Co(BDC) exhibited high catalytic effect on the reduction of CIP. The results showed that the peak current increased with the CIP concentration in the range of 3.0×10^-9~1.5×10^-8 mol/L with a calibration equation of I (μA)=99.8C_CIP+5.74(R²=0.989), and in the range of 1.5×10^-8~1.5×10^-7 mol/L with a calibration equation of I (μA)=11.09C_CIP+7.09 (R²=0.992). The detection limit is 1.0×10^-9 mol/L (S/N=3). The Co(BDC)-PAAS/GCE exhibited excellent reproducibility, good stability and good selectivity and was successfully applied to the determination of CIP in aquatic samples. Recoveries obtained for the determination of CIP in spiked samples were between 95.0% and 101.9%.
- Electrochemical sensor,
- Metal organic framework material,
- Ciprofloxacin,
- Aquatic product
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