Citation: ZI Zhong-yue, LI Bing-shuang, GE Yuan-zheng, LIU Guang-bo, LI Jian-qing, WU Jin-hu. Research on propene oligomerization reaction over the Fenton's reagent modified ZSM-5[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(8): 986-992. shu

Research on propene oligomerization reaction over the Fenton's reagent modified ZSM-5

ZI Zhong-yue ^1,2 ,
LI Bing-shuang ^1,2 ,
GE Yuan-zheng ^1,2 ,
LIU Guang-bo ¹ ,
LI Jian-qing ^1,, ,
WU Jin-hu ^1,,

1.
Key Laboratory of Biofuels, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: LI Jian-qing, WU Jin-hu, wujh@qibebt.ac.cn
Received Date: 7 April 2020
Revised Date: 7 July 2020

Fund Project: The project was supported by the National Key R&D Program of China (2018YFB1501403), Strategic Priority Research Program of Chinese Academy of Sciences (XDA21060800), the National Natural Science Foundation of China (U1610254) and the Key Laboratory of Biofuels, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences (Y372081100)the Key Laboratory of Biofuels, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences Y372081100the National Key R&D Program of China 2018YFB1501403Strategic Priority Research Program of Chinese Academy of Sciences XDA21060800the National Natural Science Foundation of China U1610254

Figures(5)

ZSM-5 zeolite was modified by Fenton's reagent, FeSO₄ and H₂O₂ aqueous solutions using impregnation method, respectively. All these catalysts were characterized by XRD, ICP-OES, N₂ adsorption-desorption, NH₃-TPD, Py-FTIR and evaluated in propene oligomerization process. The results demonstrated that the framework of the parent ZSM-5 was well preserved after modification with Fenton's reagent, FeSO₄ or H₂O₂ solutions. However, the SiO₂/Al₂O₃ ratios for all the modified ZSM-5 samples increased due to the dealumination. Furthermore, Fe was detected in Fenton-ZSM-5 while no Fe was observed for FeSO₄-ZSM-5 catalyst. The BET surface areas and total pore volumes of three modified catalysts significantly increased compared with the original ZSM-5 sample. Among them, the BET surface area of the Fenton-ZSM-5 increased by 17.86%.The increase of mesopores was probably caused by the removal of the residual organic template in the catalysts due to the generation of·OH radicals by Fenton's reagent and H₂O₂. The Fenton-ZSM-5 catalyst formed new acid sites of Brønsted (B) and Lewis (L) with little change in the total calculated amount, which significantly changed the B/L ratio. Compared with the parent ZSM-5, the Fenton-ZSM-5 catalyst exhibited the best activity and stability for propene oligomerization reaction. The initial propene conversion and diesel selectivity were as high as 98.3% and 92.4%, respectively, and kept at >80% and >82% for about 24 h, respectively.
- Fenton's reagent,
- ZSM-5,
- FeSO₄,
- H₂O₂,
- propene oligomerization
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