Citation: XU Hao, ZHANG Cheng, YUAN Chang-le, YU Sheng-hui, LI Quan, FANG Qing-yan, CHEN Gang. Study on arsenic adsorption characteristics by mineral elements in simulated flue gas atmosphere[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(7): 876-883. shu

Study on arsenic adsorption characteristics by mineral elements in simulated flue gas atmosphere

State Key Laboratory of Coal Combustion, Huazhong University of Science and Technology, Wuhan 430074, China

Corresponding author: ZHANG Cheng, chengzhang@mail.hust.edu.cn
Received Date: 27 March 2019
Revised Date: 14 May 2019

Fund Project: The project was supported by the National Key Research and Development Program of China (2018YFB0605105)the National Key Research and Development Program of China 2018YFB0605105

Figures(9)

The adsorption characteristics of As₂O₃(g) by CaO, Fe₂O₃, MgO, Al₂O₃, K₂SO₄ and Ca/Fe mixed adsorbents under the simulated flue gas atmosphere were studied by using a gas phase arsenic adsorption reaction experimental device at temperatures between 300 and 900℃. The results indicate that the adsorption ability of CaO is the strongest among the five single element adsorbents, while K₂SO₄ is the weakest. With the increase of temperature, the adsorption amount of CaO increases first, decreases slightly at 700℃, and then increases, while the adsorption amount of Fe₂O₃ increases first, and then decreases. However, the adsorption amount of MgO, Al₂O₃ and K₂SO₄ increases all the way. Compared with the calculated values of adsorption amounts of Ca/Fe mixed adsorbents in three proportions, the experimental values increase by 92% at least. The adsorption effect is the best when the ratio of CaO to Fe₂O₃ is 3:1. And the change of surface structure caused by sintering reaction after mixing is an important reason for the improvement of the adsorption effect.
- As₂O₃(g),
- adsorbents,
- flue gas atmosphere,
- mixed adsorbents
1. [1]
  WANG C, LIU H, ZHANG Y, ZOU C, ANTHONY E J. Review of arsenic behavior during coal combustion:Volatilization, transformation, emission and removal technologiesJ][J]. Prog Energy Combust, 2018,68:1-28. doi: 10.1016/j.pecs.2018.04.001
2. [2]
  KANG Yu. Environmental biogeochemistry of arsenic in coal mining area[D]. Hefei: University of Science and Technology of China, 2014.
3. [3]
  WANG C, ZHANG Y, SHI Y, LIU H, ZOU C, WU H, KANG X. Research on collaborative control of Hg, As, Pb and Cr by electrostatic-fabric-integrated precipitator and wet flue gas desulphurization in coal-fired power plants[J]. Fuel, 2017,210:527-534. doi: 10.1016/j.fuel.2017.08.108
4. [4]
  TIAN H Z, ZHU C Y, GAO J J, CHENG K, HAO J M, WANG K, HUA S B, WANG Y, ZHOU J R. Quantitative assessment of atmospheric emissions of toxic heavy metals from anthropogenic sources in China:Historical trend, spatial distribution, uncertainties, and control policies[J]. Atmos Chem Phys, 2015,15(17):10127-10147. doi: 10.5194/acp-15-10127-2015
5. [5]
  LI S, GUO S, HUANG X, HUANG T, BIBI I, MUHAMMAD F, XU G, ZHAO Z, YU L, YAN Y, JIAO B, NIAZI N K, LI D. Research on characteristics of heavy metals (As, Cd, Zn) in coal from southwest China and prevention method by using modified calcium-based materials[J]. Fuel, 2016,186:714-725. doi: 10.1016/j.fuel.2016.09.008
6. [6]
  LI J, PENG Y, CHANG H, LI X, CRITTENDEN J C, HAO J. Chemical poison and regeneration of SCR catalysts for NO_x removal from stationary sources[J]. Front Environ Sci Eng, 2016,10(3):413-427. doi: 10.1007/s11783-016-0832-3
7. [7]
  PRATIM B, WU C Y. Control of toxic metal emissions from combustors using sorbents:A review[J]. J Air Waste Manage, 1998,48(2):113-127. doi: 10.1080/10473289.1998.10463657
8. [8]
  WANG J, ZHANG Y, LIU Z, NORRIS P, ROMERO C E, XU H, PAN W P. Effect of coordinated air pollution control devices in coal-fired power plants on arsenic emissions[J]. Energy Fuels, 2017,31(7):7309-7316. doi: 10.1021/acs.energyfuels.7b00711
9. [9]
  ZHAO Y C, ZHANG J Y, HUANG W C, WANG Z H, LI Y, SONG D Y, ZH AO, F H, ZHENG C G. Arsenic emission during combustion of high arsenic coals from southwestern Guizhou, China[J]. Energy Convers Manage, 2008,49(4):615-624. doi: 10.1016/j.enconman.2007.07.044
10. [10]
  YANG Y, HU H, XIE K, HUANG Y, LIU H, LI X, YAO H, NARUSE I. Insight of arsenic transformation behavior during high-arsenic coal combustion[J]. Proc Combust Inst, 2019,37(4):4443-4450. doi: 10.1016/j.proci.2018.07.064
11. [11]
  ZHANG K, ZHANG D, ZHANG K, CAO Y. Capture of gas-phase arsenic by ferrospheres separated from fly ashes[J]. Energy Fuels, 2016,30(10):8746-8752. doi: 10.1021/acs.energyfuels.6b01637
12. [12]
  ZHANG Yue, WANG Chun-bo, LIU Hui-min, SUN Zhe, LI Wen-han, ZHANG Yong-sheng, PAN Wei-ping. Removal of gas-phase As₂O₃ in dry process by metal oxide adsorbents[J]. J Fuel Chem Technol, 2015,43(4):476-482. doi: 10.3969/j.issn.0253-2409.2015.04.016
13. [13]
  MAHULI S, AGNIHOTRI R, CHAUK S, GHOSHDASTIDAR A, FAN L S. Mechanism of arsenic sorption by hydrated lime[J]. Environ Sci Technol, 1997,31(11):3226-3231. doi: 10.1021/es9702125
14. [14]
  STERLING R O, HELBLE J J. Reaction of arsenic vapor species with fly ash compounds:Kinetics and speciation of the reaction with calcium silicates[J]. Chemosphere, 2003,51(10):1111-1119. doi: 10.1016/S0045-6535(02)00722-1
15. [15]
  ZHANG Yue, LI Wen-han, WANG Chun-bo, LIU Hui-min, ZHANG Yong-sheng, PAN Wei-ping. Experimental study on As₂O₃ capture from gas phase using ultrasound-assisted prepared Fe₂O₃/γ-Al₂O₃ sorbent[J]. J Fuel Chem Technol, 2015,43(9):1134-1141. doi: 10.3969/j.issn.0253-2409.2015.09.017
16. [16]
  HUANG Y, YANG Y, HU H, XU M, LIU H, LI X, WANG X, YAO H. A deep insight into arsenic adsorption over γ-Al₂O₃ in the presence of SO₂/NO[J]. Proc Combust Inst, 2019,37(4):4443-4450. doi: 10.1016/j.proci.2018.07.064
17. [17]
  CHEN D, HU H, XU Z, LIU H, CAO J, SHEN J, YAO H. Findings of proper temperatures for arsenic capture by CaO in the simulated flue gas with and without SO₂[J]. Chem Eng J, 2015,267:201-206. doi: 10.1016/j.cej.2015.01.035
18. [18]
  ZHANG Jun-ying, REN De-yi, ZHONG Qin, XU Fu-ming, ZHANG Yan-guo. Restraining of arsenic volatility using lime in coal combustion[J]. J Fuel Chem Technol, 2000,28(3):198-200. doi: 10.3969/j.issn.0253-2409.2000.03.002
19. [19]
  JADHAV R A, FAN L S. Capture of gas-phase arsenic oxide by Lime:Kinetic and mechanistic studies[J]. Environ Sci Technol, 2001,35(4):794-799. doi: 10.1021/es001405m
20. [20]
  LI Y, TONG H, ZHUO Y, LI Y, XU X. Simultaneous removal of SO₂ and trace As₂O₃ from flue gas:Mechanism, kinetics study, and effect of main gases on arsenic capture[J]. Environ Sci Technol, 2007,41(8):2894-2900. doi: 10.1021/es0618494
21. [21]
  ZHANG Y, LIU J. Density functional theory study of arsenic adsorption on the Fe₂O₃ (001) Surface[J]. Energy Fuels, 2019,33(2):1414-1421. doi: 10.1021/acs.energyfuels.8b04155
22. [22]
  MCLENNAN A R, BRYANT G W, STANMORE B R, WALL T F. Ash formation mechanisms during pf combustion in reducing conditions[J]. Energy Fuels, 2000,14(1):150-159.
23. [23]
  ZHOU C, LIU G, XU Z, SUN H, LAM P K S. Effect of ash composition on the partitioning of arsenic during fluidized bed combustion[J]. Fuel, 2017,204:91-97. doi: 10.1016/j.fuel.2017.05.048
24. [24]
  HU H, CHEN D, LIU H, YANG Y, CAI H, SHEN J, YAO H. Adsorption and reaction mechanism of arsenic vapors over γ-Al₂O₃ in the simulated flue gas containing acid gases[J]. Chemosphere, 2017,180:186-191. doi: 10.1016/j.chemosphere.2017.03.114
25. [25]
  CONTRERAS M L, AROSTEGUI J M, ARMESTO L. Arsenic interactions during co-combustion processes based on thermodynamic equilibrium calculations[J]. Fuel, 2009,88(3):539-546. doi: 10.1016/j.fuel.2008.09.028
26. [26]
  SEAMES W S, WENDT J O L. Regimes of association of arsenic and selenium during pulverized coal combustion[J]. Proc Combust Inst, 2007,31(2):2839-2846. doi: 10.1016/j.proci.2006.08.066
27. [27]
  LIU G, LIAO Y, WU Y, MA X. Synthesis gas production from microalgae gasification in the presence of Fe₂O₃ oxygen carrier and CaO additive[J]. Appl Energy, 2018,212:955-965. doi: 10.1016/j.apenergy.2017.12.110
28. [28]
  ZHANG Guo-zhu. Study on the crystal composition and physical and chemical properties of SFCA[D]. Tangshan: North China University of Science and Technology, 2017.
29. [29]
  FAN Xiao-hui, Meng Jun, CHEN Xu-lin, ZHUANG Jian-ming, LI Ying, YUAN Li-shun. Influence factors of calcium ferrite formation in iron ore sintering[J]. J Cent South Univ, 2008,39(6):1125-1131.
30. [30]
  MENG Fan-jian. Study on the influencing factors of forming Silico-Ferrite of calcium and aluminum and the behavior of primary slag formation[D]. Anshan: University of Science and Technology Liaoning, 2018.
31. [31]
  LI Yan-xu, LI Chun-hu, GUO Han-xian, ZHONG Bing. Preparation of iron calcium oxide high temperature gas desulfurizer[J]. J Fuel Chem Technol, 1999,27(6):49-54.
32. [32]
  YANG Li-zhai, QI Hai-ying, YOU Chang-fu, XU Xu-chang. Activation of Fe₂O₃ to desulfurization with CaO AT medium temperature[J]. J Chem Ind Eng, 2003,54(1):86-90. doi: 10.3321/j.issn:0438-1157.2003.01.019
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