Citation: ZHU Yan-tao, LÜ Gang, SONG Chong-lin, LI Bo, CHEN Ke. Catalytic oxidation of soot over monovalent copper modified ZSM-5[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(1): 106-112. shu

Catalytic oxidation of soot over monovalent copper modified ZSM-5

Tianjin University State Key Laboratory of Engines, Tianjin 300072, China

Corresponding author: LÜ Gang, lvg@tju.edu.cn
Received Date: 24 June 2016
Revised Date: 14 November 2016

Fund Project: the Major State Basic Research Development Program of China 2013CB228506the Major State Basic Research Development Program of China 973 programNational Natural Science Foundation of China 51476115the Tianjin Research Program of Application Foundation and Advanced Technology 13JCZDJC35800

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ZSM-5 zeolites were modified with different contents of monovalent copper by solid-state ion exchange method and used as the catalysts in soot oxidation; the effect of monovalent copper content on the catalytic performance was investigated through extensive characterization. The results indicate that high content of monovalent copper can be loaded on ZSM-5 zeolite by the solid-state ion exchange method, whereas has little detriment to the original micro-structure of ZSM-5. With the increase of copper content in catalyst, the reduction peaks at low temperature and high temperature both shift to lower temperature, while the area of low temperature reduction peak is increased. The catalytic activity of Cu-modified zeolite in soot oxidation decreases after an initial increase with the increase of Cu content. When the Cu loading exceeds 11%, the dispersion of copper species deteriorates, accompanying with a decrease in the catalytic activity for soot oxidation. Meanwhile, the addition of NO to the feed (O₂/He) can enhance the soot oxidation.
- soot oxidation,
- catalytic activity,
- solid-state ion exchange,
- ZSM-5 molecular sieve,
- monovalent copper
1. [1]
  ALKEMADE U G, SCHUMANN B. Engines and exhaust after treatment systems for future automotive applications[J]. Solid State Ion, 2006,177(26/32):2291-2296.
2. [2]
  HOHL Y. Retrofit kit to reduce NO_x and PM emissions from diesel engines using a low-pressure EGR and a DPF-system with FBC and throttling for active regeneration without production of secondary emissions[J]. Int J Bilingualism, 2015,19(293):627-645.
3. [3]
  FAYAD M, HERREROS J M, MARTOS F J, TSOLAKIS A. The role of alternative fuels on pm characteristics and influence of the diesel oxidation catalyst[J]. Environ Sci Technol, 2015,49(19):11967-11973. doi: 10.1021/acs.est.5b02447
4. [4]
  XU J F, LIU J, ZHAO Z, XU C M, ZHENG J X, DUAN A J, JIANG G Y. Easy synthesis of three-dimensionally ordered microporous La_1-xK_xCoO₃ catalysts and their high activities for the catalytic combustion of soot[J]. J Catal, 2011,282(1):1-12. doi: 10.1016/j.jcat.2011.03.024
5. [5]
  SEO P W, CHO S P, HONG S H, HONG S C. The influence of lattice oxygen in titania on selective catalytic reduction in the low temperature region[J]. Appl Catal A:Gen, 2010,380(1):21-27.
6. [6]
  OLSSON L, WIJAYANTI K, LEISTNER K, KUMAR A, JOSHI S Y, KAMASAMUDRAM K, NEAL W C, ALEKSEY Y. A kinetic model for sulfur poisoning and regeneration of Cu/SSZ-13 used for NH₃-SCR[J]. Appl Catal B:Environ, 2015,183:394-406.
7. [7]
  MA A J, WANG S Z, CHENG L, XIAN H, DING Q, GUO L, MENG M, TAN Y S, TSUBAKI N, ZHANG J, ZHENG L D, LI X G. Effects of Fe dopants and residual carbonates on the catalytic activities of the perovskite-type La _0.7 Sr_0.3 Co_1-xFe_xO₃, NO_x, storage catalyst[J]. Appl Catal B:Environ, 2014,146(5):24-34.
8. [8]
  IWASAKI S, MIZUTANI T, MIYAIRI Y, YUUKI K, MAKINO M. New design concept for diesel particulate filter[J]. SAE Int J Engines, 2011,4(1):527-536. doi: 10.4271/2011-01-0603
9. [9]
  YOSHIDA K, MAKINO S, SUMIYA S. Simultaneous reduction of NO_x and particulate emissions from diesel engine exhaust[J]. SAE Paper, 198919892046.
10. [10]
  YIN F, JI S, WU P, ZHAO F, LI C. , Deactivation behavior of Pd-based SBA-15 mesoporous silica catalysts for the catalytic combustion of methane[J]. J Catal, 2008,257(1):108-116. doi: 10.1016/j.jcat.2008.04.010
11. [11]
  FIERRO G, MORETTI G, FERRARIS G, ANDREOZZI G B. A Mössbauer and structural investigation of Fe-ZSM-5 catalysts:Influence of Fe oxide nanoparticles size on the catalyticbehaviour for the NO-SCR by C₃H₈[J]. Appl Catal B:Environ, 2011,102(1):215-223.
12. [12]
  BIN F, SONG C L, LV G, SONG J O, WANG K P, LI X D. Soot low-temperature combustion on Cu-Zr/ZSM-5 catalysts in O₂/He and NO/O₂/He atmospheres[J]. Proc Combust Inst, 2013,34(2):2303-2311. doi: 10.1016/j.proci.2012.07.075
13. [13]
  SCHWIDDER M, SANTHOSH K M, BRVCKNER A, GRVERT W. Active sites for NO reduction over Fe-ZSM-5 catalysts[J]. Chem Commun, 2005,6(6):805-807.
14. [14]
  SONG Z X, ZHANG Q L, NING P, LIU X, ZHANG J H, WANG Y C, XU L S, HUANG Z Z. Effect of copper precursors on the catalytic activity of Cu/ZSM-5 catalysts for selective catalytic reduction of NO by NH₃[J]. Res Chem Intermed, 2016,42(10):7429-7445. doi: 10.1007/s11164-016-2545-4
15. [15]
  YUAN E, ZHANG K, LU G, MO Z, TANG Z. Synthesis and application of metal-containing ZSM-5 for the selective catalytic reduction of NO_x, with NH₃[J]. J Ind Eng Chem, 2016,42:142-148. doi: 10.1016/j.jiec.2016.07.030
16. [16]
  KANG W, CHOI B, KIM H. Characteristics of the simultaneous removal of PM and NO_x, using CuNb-ZSM-5 coated on diesel particulate filter[J]. J Ind Eng Chem, 2013,19(4):1406-1412. doi: 10.1016/j.jiec.2013.01.004
17. [17]
  TRONCONI E, NOVA I, MARCHITTI F, KOLTSAKIS G, KARAMITROS D, MALETIC B, MARKERT N, CHATTERJEE D, HEHLE M. Interaction of NO_x, reduction and soot oxidation in a DPF with Cu-zeolite SCR coating[J]. Emis Control Sci Technol, 2015,1(2):134-151. doi: 10.1007/s40825-015-0014-y
18. [18]
  SHAKYA B M, HAROLD M P, BALAKOTAIAH V. Simulations and optimization of combined Fe-and Cu-zeolite SCR monolith catalysts[J]. Chem Eng J, 2015,278:374-384. doi: 10.1016/j.cej.2014.11.029
19. [19]
  HUANG L H, ZHANG F B, WANG N, CHEN R H, ANDREW T H. Nickel-based perovskite catalysts with iron-doping via self-combustion for hydrogen production in auto-thermal reforming of ethanol[J]. Int J Hydrogen Energy, 2012,37(2):1272-1279. doi: 10.1016/j.ijhydene.2011.10.005
20. [20]
  URQUIETAGONZÁLEZ , MARTINS E A, PEGUIN L, BATISTA RPS S M. Identification of extra-framework species on Fe/ZSM-5 and Cu/ZSM-5 catalysts typical microporous molecular sieves with zeolitic structure[J]. Mater Res, 2002,5(3):321-327. doi: 10.1590/S1516-14392002000300017
21. [21]
  SCHWIDDER M, SANTHOSH K M, BRVCKNER A, GRVNERT W. Active sites for NO reduction over Fe-ZSM-5 catalysts[J]. Chem Commun, 2015,6:805-807.
22. [22]
  PANG L, FAN C, SHAO L N, SONG K P, YI J X, CAI X, WANG J, KANG M, LI T. The Ce doping Cu/ZSM-5 as a new superior catalyst to remove NO from diesel engine exhaust[J]. Chem Eng J, 2014,25(7):394-401.
23. [23]
  DEKA U, LEZCANOGONZALEZ I, WECKHUYSEN B M, BEALE A M. Local environment and nature of Cu active sites in zeolite-based catalysts for the selective catalytic reduction of NO_x[J]. ACS Catal, 2013,3(3):413-427. doi: 10.1021/cs300794s
24. [24]
  ABOUL-GHEIT A K, ABOUL-FOTOUH S M, ABDEL-HAMID S M, ABOUL-GHEIT N A K. Hydroconversion of cyclohexene using H-ZSM-5 zeolite catalysts promoted via hydrochlorination and/or platinum incorporation[J]. J Mol Catal A:Chem, 2006,245(1):167-177.
25. [25]
  GUILLÉN-HURTADO N, BUENO-LÓPEZ A, GARCÍA-GARCÍA A. Catalytic performances of ceria and ceria-zirconia materials for the combustion of diesel soot under NO_x/O₂, and O₂. Importance of the cerium precursor salt[J]. Appl Catal A:Gen, 2012,437-438:166-172. doi: 10.1016/j.apcata.2012.06.028
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