Citation: Wu Yu, Liu Jiacheng. Self-Assembled Dye-Sensitized Solar Cell Containing Dihydrothiazole Porphyrin Coordination Polymers[J]. Chemistry, ;2020, 83(8): 718-723. shu

Self-Assembled Dye-Sensitized Solar Cell Containing Dihydrothiazole Porphyrin Coordination Polymers

Wu Yu ^1, ,
Liu Jiacheng ²

1.
School of Chemistry and Chemical Engineering, Qiannan Normal University for Nationalities, Duyun, 558000
2.
College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, 730070

Received Date: 17 February 2020
Accepted Date: 12 May 2020

Figures(5)

Two new dihydrothiazole zinc porphyrin(2+2 type and A4 type) based Mn (Ⅱ) ion coordination polymers (CPsx, x=1, 2) have been synthesized and well-characterized. Two as-synthesized coordination polymers and anchored porphyrins (ZnPA) self-assembled into dye-sensitized solar cells through axial coordination of metal-ligands. The assemby modes of the assemblies immobilized on TiO₂ electrode surfaces were also verified by TEM. The photovoltaic performance tests showed that the self-assembly polymer has better photoelectric conversion efficiency than the monomer, especially the A4 type CPs2 based solar cell showed higher short circuit current and conversion efficiency. Their optical performance and EIS were also investigated to further understand the photoelectrochemical results.
- Dihydrothiazole,
- Porphyrin polymer,
- Self-assembly,
- Dye sensitized solar cells
1. [1]
  Yella A, Lee H W, Tsao H N, et al. Science, 2011, 334(6056):629-634.
2. [2]
  O'Regan B, Grätzel M. Nature, 1991, 353(6346):737-740.
3. [3]
  Kay A, Grätzel M. J. Phys. Chem. A, 1993, 97(23):6272-6277.
4. [4]
  Kato F, Kikuchi A, Okuyama T, et al. Angew. Chem. Int. Ed., 2012, 51(40):10177-10180.
5. [5]
  Meng X D, Yin M, Shu T, et al. J. Inorg. Mater., 2018, 33(5):483-493.
6. [6]
7. [7]
  Mandal S, Nayak S K, Mallampalli S, et al. ACS Appl. Mater. Interf., 2014, 6(1):130-136.
8. [8]
  Fuhrhop J H. Langmuir, 2014, 30(1):1-12.
9. [9]
  Dawsey A C, Li V, Hamilton K C, et al. Dalton Transac., 2012, 41(26):7994-8002.
10. [10]
  Mofford D M, Reddy G R, Miller S C. J. Am. Chem. Soc., 2014, 136(38):13277-13282.
11. [11]
  Brockmeyer F, Morosow V, Martens J. Org. Biomol. Chem., 2015, 13(11):3341-3346.
12. [12]
  Velusamy M, Justin Thomas K R, Lin J T, et al. Org. Lett., 2005, 7(10):1899-1902.
13. [13]
  Wang Y, Zhou E J, Liu Y Q, et al. Chem. Mater., 2007, 19(14):3361-3363.
14. [14]
  Luo J, Xu M F, Li R Z, et al. J. Am. Chem. Soc., 2014, 136(1):265-272.
15. [15]
  Kurotobi K, Toude Y, Kawamoto K, et al. Chem. Eur. J. 2013, 19(50):17075-17081.
16. [16]
  Imahori H, Umeyama T, Kurotobi K, et al. Chem. Commun., 2012, 48(34):4032-4045.
17. [17]
  Ichiki T, Matsuo Y, Nakamura E. Chem. Commun., 2013, 49(3):279-281.
18. [18]
  D'Souza F, Amin A N, El-Khouly M E, et al. J. Am. Chem. Soc., 2012, 134(1):654-664.
19. [19]
  Cao J, Liu J C, Deng W T, et al. Electrochim. Acta, 2013, 112:515-521.
20. [20]
  Wu Y, Zhang Q, Liu J C, et al. Org. Electron., 2017, 41:301-306.
21. [21]
  Han F M, Yang J Y, Zhe Y, et al. Dalton Transac., 2016, 45(21):8862-8868.
22. [22]
  Palomares E, Martínez-díaz M V, Haque S A, et al. Chem. Commun., 2004, (18):2112-2113.
23. [23]
  Kira A, Umeyama T, Matano Y, et al. J. Am. Chem. Soc., 2009, 131(9):3198-3200.
24. [24]
  Wang P, Zakeeruddin S M, Comte P, et al. J. Phys. Chem. B, 2003, 107(51):14336-14341.
25. [25]
  Cai N, Wang P, Zhang M, et al. Adv. Funct. Mater., 2013, 23(14):1846-1854.
26. [26]
  Trachsel D. Helv. Chim. Acta, 2002, 85(9):3019-3026.
27. [27]
28. [28]
29. [29]
  He C, Lin Z H, He Z, et al. Angew. Chem. Int. Ed., 2008, 47(5):877-881.
30. [30]
  Ray A, Banerjee S, Sen S, et al. Struct. Chem., 2008, 19(2):209-217.
31. [31]
  Mangalam N A, Sheeja S R, Kurup M R P. Polyhedron, 2010, 29(18):3318-3323.
32. [32]
  Leondiadis L, Momenteau M. J. Org. Chem., 1989, 54(26):6135-6138.
33. [33]
  Seo K D, Lee M J, Song H M, et al. Dyes Pigments, 2012, 94(1):143-149.
34. [34]
35. [35]
  Subbaiyan N K, Wijesinghe C A, F D'Souza. J. Am. Chem. Soc., 2009, 131(41):14646-14647.
36. [36]
  Mathew S, Yella A, Gao P, et al. Nat. Chem., 2014, 6(3):242-247.
37. [37]
38. [38]
  Wang Q, Moser J E, Grätzel M. J. Phys. Chem. B, 2005, 109(31):14945-14953.
39. [39]
  Barea E M, Gónzalea-Pedro V, Ripollés-Sanchis T, et al. J. Phys. Chem. C, 2011, 115(21):10898-10902.
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Self-Assembled Dye-Sensitized Solar Cell Containing Dihydrothiazole Porphyrin Coordination Polymers

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com