Citation: MA Long, ZHANG Yu-xi, GAO Xin-hua, MA Qing-xiang, ZHANG Jian-li, ZHAO Tian-sheng. Preparation of Fe₃O₄@PI and its catalytic performances in Fischer-Tropsch synthesis[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(7): 813-820. shu

Preparation of Fe₃O₄@PI and its catalytic performances in Fischer-Tropsch synthesis

State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering, Ningxia University, Yinchuan 750021, China

Corresponding author: GAO Xin-hua, gxh@nxu.edu.cn ZHANG Jian-li, zhangjl@nxu.edu.cn
Received Date: 3 April 2020
Revised Date: 4 June 2020

Fund Project: the National Natural Science Foundation of China 21965029the National Natural Science Foundation of China 21968025The project was supported by the Key R & D Project of Ningxia (2018BEE03010) and the National Natural Science Foundation of China (21968025, 21965029)the Key R & D Project of Ningxia 2018BEE03010

Figures(11)

Polyimide (PI) modified Fe₃O₄@PI and Fe₃O₄-PI catalyst samples were prepared by hydrothermal-coating and ball milling methods, respectively. The effect of PI modification on the product distribution of the Fe-based catalysts for Fischer-Tropsch synthesis was investigated. The catalysts were characterized by XRD, SEM, TEM, H₂-TPR, CO-TPD, FT-IR, XPS, TG and contact angle measurements. The results showed that Fe₃O₄, Fe₃O₄@PI and Fe₃O₄-PI were spherical with uniform particle size, and the Fe₃O₄@PI particle size was smaller. PI modification promoted the reduction and the hydrophilicity of Fe₃O₄. For Fe₃O₄@PI sample, PI was uniformly coated on Fe₃O₄ surface, which led to good thermal stability. Compared with Fe₃O₄ and Fe₃O₄-PI samples, CO adsorption was promoted on Fe₃O₄@PI. Compared with Fe₃O₄, the catalytic activity of Fe₃O₄@PI and Fe₃O₄-PI decreased, and the secondary hydrogenation ability was inhibited, resulting in increase of olefin selectivity. For Fe₃O₄@PI, the olefin selectivity was enhanced significantly with olefin to alkane ratio in C_2-4 fraction increased from 0.50 to 2.15. PI modification with suitable content favored the formation of C₅₊ hydrocarbons.
- Fe₃O₄@PI catalyst,
- Fischer-Tropsch synthesis,
- light olefins,
- product distribution
1. [1]
  LU Y W, YAN Q G, HAN J, CAO B B, STREET J, YU F. Fischer-Tropsch synthesis of olefin-rich liquid hydrocarbons from biomass-derived syngas over carbon-encapsulated iron carbide/iron nanoparticles catalyst[J]. Fuel, 2017,193:369-384. doi: 10.1016/j.fuel.2016.12.061
2. [2]
  TORRES GALVIS H M, DE JONG K P. Catalysts for production of lower olefins from synthesis gas:A review[J]. ACS Catal, 2013,3(9):2130-2149. doi: 10.1021/cs4003436
3. [3]
  YANG J, MA W, CHENG D, HOLMEN A, DAVIS B H. Fischer-Tropsch synthesis:A review of the effect of CO conversion on methane selectivity[J]. Appl Catal A:Gen, 2014,470:250-260. doi: 10.1016/j.apcata.2013.10.061
4. [4]
  LI Z H, LIU R J, XU Y, MA X B. Enhanced Fischer-Tropsch synthesis performance of iron-based catalysts supported on nitric acid treated N-doped CNTs[J]. Appl Surf Sci, 2015,347:643-650. doi: 10.1016/j.apsusc.2015.04.169
5. [5]
  YAN B, MA L, GAO X H, ZHANG J L, MA Q X, ZHAO T S. Amphiphobic surface fabrication of iron catalyst and effect on product distribution of Fischer-Tropsch synthesis[J]. Appl Catal A:Gen, 2019,585117184. doi: 10.1016/j.apcata.2019.117184
6. [6]
  TORRES GALVIS H M, KOEKEN A C J, BITTER J H, DAVIDIAN T, RUITENBEEK M, IULIAN DUGULAN A, DE JONG K P. Effect of precursor on the catalytic performance of supported iron catalysts for the Fischer-Tropsch synthesis of lower olefins[J]. Catal Today, 2013,215:95-102. doi: 10.1016/j.cattod.2013.03.018
7. [7]
  WANG H Y, HUANG S Y, WANG J, ZHAO Q, WANG Y F, WANG Y, MA X B. Effect of Ca promoter on the structure and catalytic behavior of FeK/Al₂O₃ catalyst in Fischer-Tropsch synthesis[J]. ChemCatChem, 2019,11(14):3220-3226. doi: 10.1002/cctc.201900501
8. [8]
  CHEN X Q, DENG D H, PAN X L, HU Y F, BAO X H. N-doped graphene as an electron donor of iron catalysts for CO hydrogenation to light olefins[J]. Chem Commun, 2015,51(1):217-220. doi: 10.1039/C4CC06600F
9. [9]
  AN B, CHENG K, WANG C, WANG Y, LIN W B. Pyrolysis of metal-organic frameworks to Fe₃O₄@Fe₅C₂ core-shell nanoparticles for Fischer-Tropsch synthesis[J]. ACS Catal, 2016,6(6):3610-3618. doi: 10.1021/acscatal.6b00464
10. [10]
  TIAN Z P, WANG C G, SI Z, MA L L, CHEN L G, LIU Q Y, ZHANG Q, HUANG H Y. Fischer-Tropsch synthesis to light olefins over iron-based catalysts supported on KMnO₄ modified activated carbon by a facile method[J]. Appl Catal A:Gen, 2017,541:50-59. doi: 10.1016/j.apcata.2017.05.001
11. [11]
  YUAN Y, HUANG S Y, WANG H Y, WANG Y F, WANG J, LV J, LI Z H, MA X B. Monodisperse nano-Fe₃O₄ on α-Al₂O₃ catalysts for Fischer-Tropsch synthesis to lower olefins:Promoter and size effects[J]. ChemCatChem, 2017,9(16):3144-3152. doi: 10.1002/cctc.201700792
12. [12]
  LIU Y, CHEN J F, BAO J, ZHANG Y. Manganese-modified Fe₃O₄ microsphere catalyst with effective active phase of forming light olefins from syngas[J]. ACS Catal, 2015,5(6):3905-3909. doi: 10.1021/acscatal.5b00492
13. [13]
  MARTÍNEZ DEL MONTE D, VIZCAÍNO A J, DUFOUR J, C , MARTOS C. Effect of K, Co and Mo addition in Fe-based catalysts for aviation biofuels production by Fischer-Tropsch synthesis[J]. Fuel Process Technol, 2019,194106102. doi: 10.1016/j.fuproc.2019.05.025
14. [14]
  GU B, HE S, ZHOU W, KANG J C, CHENG K, ZHANG Q H, WANG Y. Polyaniline-supported iron catalyst for selective synthesis of lower olefins from syngas[J]. J Energy Chem, 2017,26:608-615. doi: 10.1016/j.jechem.2017.04.009
15. [15]
  YU X F, ZHANG J L, WANG X, MA Q X, GAO X H, XIA H Q, LAI X Y, FAN S B, ZHAO T S. Fischer-Tropsch synthesis over methyl modified Fe₂O₃@SiO₂ catalysts with low CO₂ selectivity[J]. Appl Catal B:Environ, 2018,232:420-428. doi: 10.1016/j.apcatb.2018.03.048
16. [16]
  SHI L H, CHEN J G, FANG K G, SUN Y H. CH₃-modified Co/Ru/SiO₂ catalysts and the performances for Fischer-Tropsch synthesis[J]. Fuel, 2008,87(4/5):521-526.
17. [17]
  ZHANG Juan, CHEN Jian-gang, CHEN Cong-biao, WANG Zhan-xiu, WANG Jun-gang, SUN Yu-han. Secondary reaction of olefin over Co-based catalyst for Fischer-Tropsch synthesis[J]. Petrochem Technol, 2010,39(8):855-860.
18. [18]
  GAO Jun-hu, WU Bao-shan, ZHOU Li-ping, YANG Yong, HAO Xu, XU Yuan-yuan, LI Yong-wang. Product distribution of Fischer-Tropsch synthesis in polar liquids[J]. Chin J Catal, 2011,32(12):1790-1802.
19. [19]
  WANG Lu-kai, FENG Jun-zong, LI Liang-jun, JIANG Yong-gang, FENG Jian. Research progress on hydrophobic modification of polyimide[J]. Mater Rep, 2018,32(S2):264-269.
20. [20]
  WANG L, LU J J, LIU M Q, LIN L, LI J J. Preparation of porous polyimide microspheres by thermal degradation of block copolymers[J]. Particuology, 2014,14(3):63-70.
21. [21]
  QU C Y, LIU C W, ZHOU H R, YU W M, WANG D Z, WANG D X. One-step synthesis of PI@Fe₃O₄ composite microspheres and practical application in Cu(Ⅱ) ion adsorption[J]. RSC Adv, 2015,5(108):88943-88949. doi: 10.1039/C5RA18756G
22. [22]
  YAN H J, CHEN Y, XU S M. Synthesis of graphitic carbon nitride by directly heating sulfuric acid treated melamine for enhanced photocatalytic H₂ production from water under visible light[J]. Int J Hydrogen Energy, 2012,37(1):125-133. doi: 10.1016/j.ijhydene.2011.09.072
23. [23]
  ZENG S Z, GUO L M, CUI F M, GAO Z, ZHOU J, SHI J L. Template-free synthesis of crystalline polyimide spheres with radiate branches[J]. Mater Lett, 2010,64(5):625-627. doi: 10.1016/j.matlet.2009.12.024
24. [24]
  NI Z J, QIN H F, KANG S F, BAI J R, WANG Z L, LI Y G, ZHENG Z, LI X. Effect of graphitic carbon modification on the catalytic performance of Fe@SiO₂-GC catalysts for forming lower olefins via Fischer-Tropsch synthesis[J]. J Colloid Interf Sci, 2018,516:16-22. doi: 10.1016/j.jcis.2018.01.017
25. [25]
  ZHANG Jian-li, WANG Xu, MA Li-ping, YU Xu-fei, MA Qing-xiang, FAN Su-bing, ZHAO Tian-sheng. Preparation of layered K/Mg-Fe-Al catalysts and its catalytic performances in CO hydrogenation[J]. J Fuel Chem Technol, 2017,45(12):1489-1498. doi: 10.3969/j.issn.0253-2409.2017.12.011
26. [26]
  WU X, MA H F, ZHANG H T, QIAN W X, LIU D H, SUN Q W, YING W Y. High-temperature Fischer-Tropsch synthesis of light olefins over nano-Fe₃O₄@MnO₂ core-shell catalysts[J]. Ind Eng Chem Res, 2019,58(47):21350-21362. doi: 10.1021/acs.iecr.9b04221
27. [27]
  ROMERO-SARRIA F, BOBADILLA L F, JIMÉNEZ BARRERA E M, ODRIOZOLA J A. Experimental evidence of HCO species as intermediate in the Fischer-Tropsch reaction using operando techniques[J]. Appl Catal B:Environ, 2020,272119032. doi: 10.1016/j.apcatb.2020.119032
28. [28]
  DING M Y, YANG Y, WU B S, LI Y W, WANG T J, MA L L. Study on reduction and carburization behaviors of iron phases for iron-based Fischer-Tropsch synthesis catalyst[J]. Appl Energy, 2015,160:982-989. doi: 10.1016/j.apenergy.2014.12.042
1. [1]
  Xue Dong , Xiaofu Sun , Shuaiqiang Jia , Shitao Han , Dawei Zhou , Ting Yao , Min Wang , Minghui Fang , Haihong Wu , Buxing Han . Electrochemical CO₂ Reduction to C₂₊ Products with Ampere-Level Current on Carbon-Modified Copper Catalysts. Acta Physico-Chimica Sinica, 2025, 41(3): 2404012-0. doi: 10.3866/PKU.WHXB202404012
2. [2]
  Yajin Li , Huimin Liu , Lan Ma , Jiaxiong Liu , Dehua He . Photothermal Synthesis of Glycerol Carbonate via Glycerol Carbonylation with CO₂ over Au/Co₃O₄-ZnO Catalyst. Acta Physico-Chimica Sinica, 2024, 40(9): 2308005-0. doi: 10.3866/PKU.WHXB202308005
3. [3]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . Simultaneously Improving Inter-Plane Crystallization and Incorporating K Atoms in g-C₃N₄ Photocatalyst for Highly-Efficient H₂O₂ Photosynthesis. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-0. doi: 10.3866/PKU.WHXB202406005
4. [4]
  Haoyu Sun , Dun Li , Yuanyuan Min , Yingying Wang , Yanyun Ma , Yiqun Zheng , Hongwen Huang . Hierarchical Palladium-Copper-Silver Porous Nanoflowers as Efficient Electrocatalysts for CO₂ Reduction to C₂₊ Products. Acta Physico-Chimica Sinica, 2024, 40(6): 2307007-0. doi: 10.3866/PKU.WHXB202307007
5. [5]
  Xiaofang Li , Zhigang Wang . 调节金助催化剂的d_z²占据轨道增强光催化合成H₂O₂. Acta Physico-Chimica Sinica, 2025, 41(7): 100080-0. doi: 10.1016/j.actphy.2025.100080
6. [6]
  Xuejie Wang , Guoqing Cui , Congkai Wang , Yang Yang , Guiyuan Jiang , Chunming Xu . Research Progress on Carbon-based Catalysts for Catalytic Dehydrogenation of Liquid Organic Hydrogen Carriers. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-0. doi: 10.1016/j.actphy.2024.100044
7. [7]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371
8. [8]
  Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . Designing thermodynamically stable noble metal single-atom photocatalysts for highly efficient non-oxidative conversion of ethanol into high-purity hydrogen and value-added acetaldehyde. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-0. doi: 10.1016/j.actphy.2025.100067
9. [9]
  Dong Xiang , Kunzhen Li , Kanghua Miao , Ran Long , Yujie Xiong , Xiongwu Kang . Amine-Functionalized Copper Catalysts: Hydrogen Bonding Mediated Electrochemical CO₂ Reduction to C₂ Products and Superior Rechargeable Zn-CO₂ Battery Performance. Acta Physico-Chimica Sinica, 2024, 40(8): 2308027-0. doi: 10.3866/PKU.WHXB202308027
10. [10]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
11. [11]
  Jia Wang , Qing Qin , Zhe Wang , Xuhao Zhao , Yunfei Chen , Liqiang Hou , Shangguo Liu , Xien Liu . P-Doped Carbon-Supported Zn_xP_yO_z for Efficient Ammonia Electrosynthesis under Ambient Conditions. Acta Physico-Chimica Sinica, 2024, 40(3): 2304044-0. doi: 10.3866/PKU.WHXB202304044
12. [12]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
13. [13]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . Molten Intermediate Transportation-Oriented Synthesis of Amino-Rich g-C₃N₄ Nanosheets for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-0. doi: 10.3866/PKU.WHXB202406021
14. [14]
  Lutian Zhao , Yangge Guo , Liuxuan Luo , Xiaohui Yan , Shuiyun Shen , Junliang Zhang . Electrochemical Synthesis for Metallic Nanocrystal Electrocatalysts: Principle, Application and Challenge. Acta Physico-Chimica Sinica, 2024, 40(7): 2306029-0. doi: 10.3866/PKU.WHXB202306029
15. [15]
  Wenke ZHENG , Ce LIU , Wei CHEN , Hongshan KE , Fanlong ZENG , Yibo LEI , Anyang LI , Wenyuan WANG . Synthesis and bonding analysis of low-coordinate Fe and Cr complexes with ultra-bulky silylamino groups. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1285-1293. doi: 10.11862/CJIC.20250095
16. [16]
  Yixuan Wang , Canhui Zhang , Xingkun Wang , Jiarui Duan , Kecheng Tong , Shuixing Dai , Lei Chu , Minghua Huang . Engineering Carbon-Chainmail-Shell Coated Co₉Se₈ Nanoparticles as Efficient and Durable Catalysts in Seawater-Based Zn-Air Batteries. Acta Physico-Chimica Sinica, 2024, 40(6): 2305004-0. doi: 10.3866/PKU.WHXB202305004
17. [17]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
18. [18]
  Yuwei Liu , Yihui Zhu , Weijian Duan , Yizhuo Yang , Haorui Tuo , Chunhua Feng . Electrocatalytic nitrate reduction on Fe, Fe₃O₄, and Fe@Fe₃O₄ cathodes: Elucidating structure-sensitive mechanisms of direct electron versus hydrogen atom transfer. Chinese Chemical Letters, 2025, 36(6): 110347-. doi: 10.1016/j.cclet.2024.110347
19. [19]
  Qi Wu , Changhua Wang , Yingying Li , Xintong Zhang . Enhanced photocatalytic synthesis of H₂O₂ by triplet electron transfer at g-C₃N₄@BN van der Waals heterojunction interface. Acta Physico-Chimica Sinica, 2025, 41(9): 100107-0. doi: 10.1016/j.actphy.2025.100107
20. [20]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(890)
HTML views(111)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of Fe3O4@PI and its catalytic performances in Fischer-Tropsch synthesis

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation of Fe₃O₄@PI and its catalytic performances in Fischer-Tropsch synthesis