Citation: LIU You-chang, WANG Liang. Preparation of p-n heterojunction g-C3N4/BiOBr and its photocatalytic performance under visible light[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(9): 1146-1152. shu

Preparation of p-n heterojunction g-C3N4/BiOBr and its photocatalytic performance under visible light

  • Corresponding author: WANG Liang, wangliang_good@163.com
  • Received Date: 2 April 2018
    Revised Date: 12 July 2018

Figures(7)

  • g-C3N4 nanosheet was obtained from the precursors melamine and BiOBr nanosheets was synthesized from the raw materials Bi(NO3)3·5H2O and KBr. The two-dimensional g-C3N4/BiOBr heterojunction was synthesized by hydrothermal method. The intimated interface and suitable crystal facets of g-C3N4 and BiOBr were favorable the combination of this two photocatalysts, resulting in enhancing the visible-light photocatalytic activity. The phase structure, optical absorption property as well as composition and structure of as-prepared materials were characterized by X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, ultraviolet-visible diffuse reflection spectroscopy (DRS) and photoluminescence emission spectroscopy. The potential mechanisms of constructing two-dimensional g-C3N4/BiOBr heterojunction were revealed. The photocatalytic activity of as-synthesized photocatalysts was evaluated by photocatalytic degradation of RhB under visible light (λ>420 nm) irradiation. Results show that the as-synthesized heterojunctions can significantly enhance photocatalytic activity in comparison with pure g-C3N4 and BiOBr. The mechanisms of enhanced photocatalytic performance were explained.
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