Citation: JIN Ya-mei, DONG Mei, WANG Guo-fu, WANG Hao, LI Jun-fen, FAN Wei-bin, WANG Jian-guo, QIN Zhang-feng. Synthesis of Silicalite-1 hollow sphere catalyst and its application for Beckmann rearrangement reaction[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(8): 1001-1009. shu

Synthesis of Silicalite-1 hollow sphere catalyst and its application for Beckmann rearrangement reaction

JIN Ya-mei ^1,2 ,
DONG Mei ^1,*,, ,
WANG Guo-fu ¹ ,
WANG Hao ¹ ,
LI Jun-fen ¹ ,
FAN Wei-bin ^1,*,, ,
WANG Jian-guo ¹ ,
QIN Zhang-feng ¹

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: DONG Mei, mdong@sxicc.ac.cn FAN Wei-bin, fanwb@sxicc.ac.cn
Received Date: 31 March 2016
Revised Date: 10 May 2016

Figures(10)

Silicalite-1 zeolite hollow sphere structured material was hydrothermally synthesized via the aid of carbon microspheres as hard-template. The morphology, structure, textural and physicochemical properties of the material were characterized with XRD, SEM, FT-IR, N₂ adsorption-desorption isotherm, ²⁹Si MAS NMR, TG, and XPS techniques. It was suggested that the obtained Silicalite-1 hollow spheres were highly crystallized with developed multiple channel structure and abundant surface hydroxyl groups, which endowed the material with excellent catalytic properties in Beckmann rearrangement reaction of cyclohexanone-oxime. Compared with the Silicalite-1 catalyst prepared from conventional method, the Silicalite-1 hollow sphere catalyst showed much higher activity to the conversion of cyclohexanone-oxime (99%) and selectivity of caprolactam (94%), with excellent stability at the same time. The abundant nest silanols and terminal silanols in Silicalite-1 hollow sphere were main active sites for Beckmann rearrangement reaction, and could be easily recovered from the deactivated catalysts by calcination.
- Silicalite-1,
- hollow sphere,
- carbon microspheres,
- hard-template,
- Beckmann rearrangement
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