Citation: LIANG Sheng-rong, LIU Feng, WANG Qian, WU Rui-rui, ZHANG Jun-tao, SHEN Zhi-bing. Effect of modification to Hβ with F on the performance of Mo-Ni/F-Hβ catalyst in the sulfur transfer reactions of FCC gasoline[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(4): 405-413. shu

Effect of modification to Hβ with F on the performance of Mo-Ni/F-Hβ catalyst in the sulfur transfer reactions of FCC gasoline

School of Chemistry and Chemical Engineering, Xi'an Shiyou University, Xi'an 710065, China

Corresponding author: SHEN Zhi-bing, szb@xsyu.edu.cn
Received Date: 22 November 2019
Revised Date: 31 January 2020

Fund Project: China Petroleum Science and Technology Innovation Fund Project 2017D-5007-0401The project was supported by the China Petroleum Science and Technology Innovation Fund Project (2017D-5007-0401), Open Fund Project of National Key Laboratory of Heavy Oil and Postgraduate Innovation and Practical Ability Training Project of Xi'an University of Petroleum (YCS19113074)Practical Ability Training Project of Xi'an University of Petroleum YCS19113074

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Hβ zeolite was modified with different contents of F to prepare the Mo-Ni/F-Hβ catalysts. The Mo-Ni/F-Hβ catalysts were characterized by nitrogen physisorption, NH₃-TPD, XRD, Py-FTIR and SEM; the effect of modification to Hβ with F on the catalytic performance of Mo-Ni/F-Hβ in the sulfur transfer reactions such as etherification of mercaptan and alkylation of thiophene in FCC gasoline was then investigated. The results indicate that the Mo-Ni/F-Hβ catalyst prepared with 0.5% F-modified Hβ zeolite can promote the thioetherification and thiophene alkylation reactions and improve the selectivity of dienes hydrogenation. The introduction of F can enhance the medium strong acid content of Hβ zeolite, reduce the strong acid content, and increase the ratio of L/B acid sites, all these may contribute to improving the catalytic performance of Mo-Ni/F-Hβ in the sulfur transfer reactions of FCC gasoline.
- fluorine modification,
- catalyst,
- FCC gasoline,
- sulfur transfer reaction
1. [1]
  YU F, WANG Q, YUAN B, XIE C X, YU S T. Alkylation desulfurization of FCC gasoline over organic-inorganic heteropoly acid catalyst[J]. J Chem Eng, 2017,309:298-304. doi: 10.1016/j.cej.2016.10.003
2. [2]
  SHEN Z, ZHANG J, REN T, LIANG S. The performance of benzenesulfonic acid catalyst on the alkylation of thiophenic sulfur[J]. Appl Petrochem Res, 2016,6(1):35-40. doi: 10.1007/s13203-015-0116-z
3. [3]
  FU W, ZHANG L, WU D, YU Q, TANG T, TANG T. Mesoporous molecular sieve ZSM-5 supported Ni₂P catalysts with high activity in the hydrogenation of phenanthrene and 4, 6-dimethyldibenzothiophene[J]. Ind Eng Chem Res, 2016,55(26):7085-7095. doi: 10.1021/acs.iecr.6b01583
4. [4]
  GUO B, LI Y. Analysis and simulation of reactive distillation for gasoline alkylation desulfurization[J]. Chem Eng Sci, 2012,72:115-125.
5. [5]
  YU Y, LI R, LI Q. Alkylation of thiophenic compounds with 1-hexene over sulfonated solid acid catalysts[J]. Prog React Kinet Mech, 2013,38(4):425-430.
6. [6]
  SAAD A, AL-BOGAMI , HUGO I. Catalytic conversion of benzothiophene over a H-ZSM5 based catalyst[J]. Fuel, 2013,108:490-501. doi: 10.1016/j.fuel.2012.11.008
7. [7]
  RISTIĆ A, FISCHER F, HAUER A, LOGAR N Z. Improved performance of binder-free zeolite Y for low-temperature sorption heat storage[J]. J Mater Chem A, 2018,6(24):11521-11530. doi: 10.1039/C8TA00827B
8. [8]
  GUO B, WANG R, LI Y. The performance of solid phosphoric acid catalysts and macroporous sulfonic resins on gasoline alkylation desulfurization[J]. Fuel Process Technol, 2010,91(11):1731-1735. doi: 10.1016/j.fuproc.2010.07.012
9. [9]
  FAVARETTO L, AN J, SAMBO M, DE NISI A, BETTINI C, MELUCCI M, KOVTUN A, LISCIO A, PALERMO V, BOTTONI A, ZERBETTO F, CALVARESI M, ZERBETTO F. Graphene oxide promotes site-selective allylic alkylation of thiophenes with alcohols[J]. Org Lett, 2018,20(12):3705-3709. doi: 10.1021/acs.orglett.8b01531
10. [10]
  SRIVASTAVA V C. An evaluation of desulfurization technologies for sulfur removal from liquid fuels[J]. Rsc Adv, 2012,2(3):759-783. doi: 10.1039/C1RA00309G
11. [11]
  XU Ya-rong, SHEN Ben-xian, XU Xin-liang, ZHAO Ji-gang, LIU Gang. Transfer performance of solid mixed acid catalytic alkylation of sulfur in FCC gasoline[J]. J East China Univ Technol:Nat Sci Ed, 2010,36(5):633-638. doi: 10.3969/j.issn.1006-3080.2010.05.006
12. [12]
  NOCCA J L, COSYNS J, DEBUISSCHERT Q, DIDILLON B. The domino interaction of refinery processes for gasoline quality attainment. San Antonio, TX: Proceedings of the NPRA Annual Meeting, March 2000, AM-00-61.
13. [13]
  Zhou Zhi-yuan. Study on acid catalysts for diene thioetherification[C]//Catalysis Committee of the Chinese Chemical Society. Proceedings of the 11th National Youth catalysis Academic Conference (2). Catalysis Committee of the Chinese Chemical Society: School of chemistry and chemistry, China University of Petroleum (East China), 2007: 2.
14. [14]
  PATMAN H M. Method of mercaptan removal: CN, 00812936.3[P]. 2000-07-03.
15. [15]
  HEARN D, HICKEY T P. Gasoline desulfurization method: CN, 96196515.0[P]. 1998-09-06.
16. [16]
  ZHANG Z, GUO X, LIU S, ZHU X, XU L. Modification of Hβ molecular sieve by fluorine and its influence on olefin alkylation thiophenic sulfur in gasoline[J]. Fuel Process Technol, 2008,89(1):103-110. doi: 10.1016/j.fuproc.2007.08.003
17. [17]
  WANG R, WAN J, LI Y, SUN H. An improvement of MCM-41 supported phosphoric acid catalyst for alkylation desulfurization of fluid catalytic cracking gasoline[J]. Fuel, 2015,143:504-511. doi: 10.1016/j.fuel.2014.11.093
18. [18]
  SHI R, LI Y, WANG R, GUO B. Alkylation of thiophenic compounds with olefins and its kinetics over MCM-41 supported phosphoric acid in fcc gasoline[J]. Catal Lett, 2010,139(3/4):114-122.
19. [19]
  PAN Hong-yan, TIAN Min, LIN Qian. Effect of silicon aluminum ratio on the performance of ZSM-5 zeolite catalyst for methanol to olefin[J]. Nat Gas Ind, 2015,40(1):9-12.
20. [20]
  BRZOZOWSKI R, SKUPIŃSKI W. Molecular sieve pore entrance effect on shape selectivity in naphthalene isopropylation[J]. J Catal, 2002,210(2):313-318.
21. [21]
  COLON G, FERINO I, ROMBI E. Liquid-phase alkylation of naphthalene by isopropanol over molecular sieves. Part 1:HY molecular sieves[J]. Appl Catal A:Gen, 1998,168(1):81-92. doi: 10.1016/S0926-860X(97)00346-3
22. [22]
  SMIRNIOTIS P G, RUCKENSTEIN E J. Comparison between zeolite β and γ-Al₂O₃ supported Pt for reforming reactions[J]. J Catal, 1993,140(2):526-542.
23. [23]
  RUCKENSTEIN E, SMIRNIOTIS P G. Two sources of synergism in the reforming ofn-hexane, methylcyclopentane, methylcyclohexane mixtures over composites of basic and acidic zeolites[J]. Catal Lett, 1994,24(1/2):123-132.
24. [24]
  SMIRNIOTIS P G, RUCKENSTEIN E. Increased aromatization in the reforming of mixtures of n-hexane, methylcyclopentane and methylcyclohexane over composites of Pt/BaKL zeolite with Pt/β or Pt/USY zeolites[J]. Appl Catal A:Gen, 1995,123(1):59-88. doi: 10.1016/0926-860X(94)00241-X
25. [25]
  BLACKMOND D G, GOODWIN J G, LESTER J E. In situ Fourier transform infrared spectroscopy study of HY cracking catalysts:Coke formation and the nature of the active sites[J]. J Catal, 1982,78(1):34-43.
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