Citation: LIANG Sheng-rong, LIU Feng, WANG Qian, WU Rui-rui, ZHANG Jun-tao, SHEN Zhi-bing. Effect of modification to Hβ with F on the performance of Mo-Ni/F-Hβ catalyst in the sulfur transfer reactions of FCC gasoline[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(4): 405-413. shu

Effect of modification to Hβ with F on the performance of Mo-Ni/F-Hβ catalyst in the sulfur transfer reactions of FCC gasoline

School of Chemistry and Chemical Engineering, Xi'an Shiyou University, Xi'an 710065, China

Corresponding author: SHEN Zhi-bing, szb@xsyu.edu.cn
Received Date: 22 November 2019
Revised Date: 31 January 2020

Fund Project: China Petroleum Science and Technology Innovation Fund Project 2017D-5007-0401The project was supported by the China Petroleum Science and Technology Innovation Fund Project (2017D-5007-0401), Open Fund Project of National Key Laboratory of Heavy Oil and Postgraduate Innovation and Practical Ability Training Project of Xi'an University of Petroleum (YCS19113074)Practical Ability Training Project of Xi'an University of Petroleum YCS19113074

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Hβ zeolite was modified with different contents of F to prepare the Mo-Ni/F-Hβ catalysts. The Mo-Ni/F-Hβ catalysts were characterized by nitrogen physisorption, NH₃-TPD, XRD, Py-FTIR and SEM; the effect of modification to Hβ with F on the catalytic performance of Mo-Ni/F-Hβ in the sulfur transfer reactions such as etherification of mercaptan and alkylation of thiophene in FCC gasoline was then investigated. The results indicate that the Mo-Ni/F-Hβ catalyst prepared with 0.5% F-modified Hβ zeolite can promote the thioetherification and thiophene alkylation reactions and improve the selectivity of dienes hydrogenation. The introduction of F can enhance the medium strong acid content of Hβ zeolite, reduce the strong acid content, and increase the ratio of L/B acid sites, all these may contribute to improving the catalytic performance of Mo-Ni/F-Hβ in the sulfur transfer reactions of FCC gasoline.
- fluorine modification,
- catalyst,
- FCC gasoline,
- sulfur transfer reaction
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