Citation: Yang Haotian, Zhou Xian, Yang Ke, Liu Jiamei, Zou Yangyang, Chen Jiaqing, Wang Jingyun, Zhou Mingdong. Hydrolysis of Microcrystalline Cellulose to Glucose Catalyzed by Molybdenum Polyoxometalates[J]. Chemistry, ;2019, 82(9): 855-859. shu

Hydrolysis of Microcrystalline Cellulose to Glucose Catalyzed by Molybdenum Polyoxometalates

College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun 113001

Corresponding author: Wang Jingyun, jingyun.wang@lnpu.edu.cn
Received Date: 10 March 2019
Accepted Date: 6 July 2019

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Eight kinds of Mo₈O₂₆ based compounds were synthesized and the structure of these compounds were characterized by NMR and FT-IR. Microcrystalline cellulose (MCC) was hydrolyzed to produce the total reducing sugar (TRS) in ionic liquid[Amim]Cl using molybdenum polyoxometalate as catalyst under microwave irradiation conditions. The effects of the kind and dosage of catalyst, reaction temperature and reaction time on the hydrolysis reaction were investigated. The results indicated that the molybdenum polyoxometalates exhibit good catalytic activity for the hydrolysis reaction of MCC. The cellulose can be completely converted with the addition of 10(wt)% of catalyst[(CH₃)₄N]₄Mo₈O₂₆ under the microwave-assisted heating condition in the ionic liquid[Amim]Cl at 170℃ for 20 min. The highest TRS and glucose yields of MCC were 84.5% and 41.5% respectively.
- Molybdenum polyoxometalates,
- Cellulose,
- Hydrolysis,
- Glucose
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