Citation: Wang Peng, Li Lihua, Wu Xian, Ma Cheng. Research Progress of Polyoxometalate-Based Photocatalysts in the Dyes Photodegradation[J]. Chemistry, ;2019, 82(5): 415-423. shu

Research Progress of Polyoxometalate-Based Photocatalysts in the Dyes Photodegradation

Liaoning Shihua University, Fushun 113001

Corresponding author: Li Lihua, llh72@163.com
Received Date: 5 December 2018
Accepted Date: 25 December 2018

Figures(9)

How to effectively remove the dyes from the waste water has been the popular direction of materials and environmental science. Compared with traditional adsorption and concentration filtration methods, the photocatalytic degradation has attracted more attention due to its unique environmental-friendly, conveniency, safety and without secondary pollution. In numerous catalysts, heteropoly acid (HPA) has great potential in photocatalytic applications due to its special 'cage' structure, tunable electronic properties, non-toxicity, oxygen-rich surface, cheapness and excellent redox properties, etc. In this paper, the research progress of polyoxometalate-based photocatalysts in recent years was introduced, and they can be classified into two major categories:modification and loading method, which were further subdivided into substitution HPAs, altered counterion HPA, organic and inorganic modification method, silicate loading method, titanium dioxide loading method and graphene loading method. The main improvement direction is to resolve their water solubility problem, broaden the light response range, increase their specific surface area and improve the recyclability. The synthesis conditions and catalytic mechanism of different catalyst systems were summarized and analyzed in detail, at the end, the future development trend is forecasted.
- Dyes,
- Polyoxometalate-based catalysts,
- Photodegradation
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