Citation: MI Xing, HE Guang-xiang, GUO Xiao-yan, YANG Suo-he, LUO Guo-hua, XU Xin, JIN Hai-bo. Effect of reaction conditions on the hydrogenation of naphthalene to decalin over Ni/Al₂O₃ catalyst[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(7): 879-885. shu

Effect of reaction conditions on the hydrogenation of naphthalene to decalin over Ni/Al₂O₃ catalyst

Beijing Key Laboratory of Fuels Cleaning and Advanced Catalytic Emission Reduction Technology, School of Chemical Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China

Corresponding author: JIN Hai-bo, jinhaobo@bipt.edu.cn
Received Date: 27 November 2017
Revised Date: 3 May 2018

Fund Project: Construction of Innovative Teams and Teacher Career Development for Universities and Colleges under Beijing Municipality IDHT20180508the National Natural Science Foundation of China 91634101The project was supported by the National Natural Science Foundation of China (91634101) and Construction of Innovative Teams and Teacher Career Development for Universities and Colleges under Beijing Municipality (IDHT20180508)

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The effect of reaction conditions, including temperature, pressure, space velocity and hydrogen to oil ratio, on the hydrogenation of naphthalene to decalin over Ni/Al₂O₃ catalyst was investigated in a high pressure fixed bed reactor. The results indicate that the conversion of naphthalene and the selectivity to tran-decalin and cis-decalin are closely related to the reaction conditions. The ratio of tran-decalin to cis-decalin increases with an increase in the hydrogen to oil ratio and reaction temperature, but decreases with an increase in the liquid hourly space velocity (LHSV) and reaction pressure. Under a temperature 260-290℃, 5-7 MPa, a LHSV 1-1.5 h^-1, and a hydrogen to oil ratio higher than 250, the conversion of naphthalene is 100% and the selectivity to decalin is close to 100%, with a tran-decalin to cis-decalin ratio of about 4.0. Meanwhile, it was found that the sintering and/or loss of active component are the main factors that cause the deactivation of Ni/Al₂O₃ catalyst in naphthalene hydrogenation and influence the ratio of tran-decalin to cis-decalin in the products.
- reaction conditions,
- naphthalene hydrogenation,
- Ni/Al₂O₃,
- decalin
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Effect of reaction conditions on the hydrogenation of naphthalene to decalin over Ni/Al2O3 catalyst

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通讯作者: 陈斌, bchen63@163.com

Effect of reaction conditions on the hydrogenation of naphthalene to decalin over Ni/Al₂O₃ catalyst