Citation: LIU Jie, ZHOU Zhao-qian, LI Wen-shen, SONG Shi-ye, MA Bo. Removal of basic nitrogen compounds from fuel oil with[Amim]Cl/ZnCl₂ ionic liquid[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(10): 1233-1239. shu

Removal of basic nitrogen compounds from fuel oil with[Amim]Cl/ZnCl₂ ionic liquid

LIU Jie ^1,2,*,, ,
ZHOU Zhao-qian ¹ ,
LI Wen-shen ¹ ,
SONG Shi-ye ¹ ,
MA Bo ^1,2

1.
College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun 113001, China
2.
College of Chemical Engineering, China University of Petroleum(East China), Qingdao 266580, China

Corresponding author: LIU Jie, lj13898309829@163.com
Received Date: 20 April 2016
Revised Date: 29 June 2016

Figures(10)

Metal-based ionic liquid [Amim]Cl/ZnCl₂ was synthesized and its structure and acidity were characterized with FT-IR spectroscopy. The denitrogenation performance of the ionic liquid was investigated using Fushun shale diesel oil containing 0.52% basic nitrogen as feedstock. Experimental results showed that the ionic liquid exhibited good denitrogenation performance and 83.78% basic N-extraction efficiency was achieved under the optimized operation conditions, i.e., temperature of 30℃, 1:7 (mass ratio) IL:oil, reaction time of 20 min and settling time of 2 h. In addition, the basic N-removal efficiency of the ionic liquid can still remain 52% after four recycles.
- [Amim]Cl/ZnCl₂ ionic liquid,
- shale diesel oil,
- denitrogenation,
- basic nitrogen
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Removal of basic nitrogen compounds from fuel oil with[Amim]Cl/ZnCl2 ionic liquid

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通讯作者: 陈斌, bchen63@163.com

Removal of basic nitrogen compounds from fuel oil with[Amim]Cl/ZnCl₂ ionic liquid