Citation: Yi Xianmei, Deng Yaxin, Huang Chao, Zhu Bixue. Syntheses and Structures of Macrocycles Containing 2, 6-Diamidopyridine Unit and their Complex Properties for Tetrahedral Anions[J]. Chemistry, ;2020, 83(9): 821-827. shu

Syntheses and Structures of Macrocycles Containing 2, 6-Diamidopyridine Unit and their Complex Properties for Tetrahedral Anions

Key Laboratory of Macrocyclic and Supramolecular Chemistry, Guizhou University, Guiyang, 550025

Corresponding author: Zhu Bixue, bxzhu@gzu.edu.cn
Received Date: 1 March 2020
Accepted Date: 27 May 2020

Figures(6)

[1+1] Schiff base macrocycle L¹ was synthesized from the reaction of precursors N, N'-bis(3-aminophenyl)-pyridine-2, 6-dicarboxamide (1) with 5, 5'-methylene-bis-salicylaldehyde (2), and furthermore the macrocycle L¹ was reduced to the corresponding saturated macrocycle L². The two macrocycles were characterized by¹H NMR, FABMS spectroscopies and elemental analysis, and their crystal structures were determined by X-ray diffraction analysis. The two macrocycles exhibited non-planar structures, and L² showed a more flexible twisted conformation. The complexation of macrocycles with a series of anions was investigated by UV-Vis spectrometric titration technology. The results showed that L¹ had obvious selective recognition ability for tetrahedral anions H₂PO₄^-, HP₂O₇^3-, and H₂P₂O₇^2-, respectively. Properties of the [1+1] Schiff base macrocycle L¹ hydrogen-bonding interactions with these tetrahedral anions were investigated using UV-Vis and¹H NMR titration, respectively. The stoichiometric ratio and binding constant (K) of the interaction were obtained. The results demonstrated that L¹ binded the three anions with a 1:1 binding stoichiometry, and the bonding constants (K_a) increased in the order of H₂PO₄^-, HP₂O₇^3-, H₂P₂O₇^2-.
- Schiff base macrocycle,
- Crystal structures,
- Tetrahedral anion,
- Recognition
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