Citation: . SYNTHESIS OF STYRENIC TONER PARTICLES BY SPG EMULSIFICATION TECHNIQUE[J]. Chinese Journal of Polymer Science, ;2000, 18(4): 309-322. shu

SYNTHESIS OF STYRENIC TONER PARTICLES BY SPG EMULSIFICATION TECHNIQUE

Received Date: 10 January 1999

This research studied the initiator efficiency for producing polymeric particles of poly(styrene-co-methylmethacrylate) copolymers by a Shirasu porous glass membrane (SPG) emulsification technique followed by suspensioncopolymerization. BPO, ADVN, and AIBN were used as initiators and we found that BPO is the most suitable initiator.Copolymers for various feed ratios of styrene/methyl methacrylate were thus synthesized by benzoyl peroxide, and theircopolymer particle size, molecular weight distribution and particle size distribution were characterized.Then n-BMA or 2-EHMA was added as the third monomer to decrease the terpolymer glass transition temperature.This article describes the preparation technique,recipes and polymerization conditions for producing both copolymer and terpolymer particles,particle size changes,the corresponding particle morphologies and glass transition temperatures.
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