Citation: Fu An WANG, Chang Sheng YANG, Wen Chang WANG, Yuan Li JIANG. INTERSECTION POINT RULE OF THE RETENTION VALUE AND NORMAL BOILING POINT OF THE HOMOLOGUES IN REVERSED-PHASE HIGH-PERFORMANCE LIQUID CHROMATOGRAPHY[J]. Chinese Chemical Letters, ;1991, 3(8): 637-640. shu

INTERSECTION POINT RULE OF THE RETENTION VALUE AND NORMAL BOILING POINT OF THE HOMOLOGUES IN REVERSED-PHASE HIGH-PERFORMANCE LIQUID CHROMATOGRAPHY

Department of Chemical Engineering Zhengzhon Institute of Technology Zhengzhou 450002

Received Date: 6 May 1991

In this paper, a linear relationship between the logarithm of capacity factor k' and normal boiling point to of the homologues has been derived, based on the basic retention equation of liquid chromatography according to statistical thermodyoamics proposed by professor Ln Peizhang and others, This equation has been verified by a large number of experimental data, all the strsight lines of lnk'--t_b of bumologues for different mobile phass coaiposltion cross each other at the same point, So the intereection point equation was proposed, wbich was used to prodict the retention value, the result was satisfactory.
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