Citation: Xu Chuanhui, Zou Changjun. Study on Preparation, Characterization, and Encapsulation/Release Propeties of β-CD Modified Carboxymethyl Cellulose Hydrogel[J]. Chemistry, ;2018, 81(7): 630-635. shu

Study on Preparation, Characterization, and Encapsulation/Release Propeties of β-CD Modified Carboxymethyl Cellulose Hydrogel

Xu Chuanhui ,
Zou Changjun ^,

College of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 610500

Corresponding author: Zou Changjun, changjunzou@126.com
Received Date: 16 March 2018
Accepted Date: 2 April 2018

Figures(8)

A series of β-CD modified carboxymethyl cellulose hydrogel particles (gel CMC-β-CD) were prepared through inverse suspension polymerization under alkaline condition, and their adsorption and encapsulation abilities were investigated. The results showed that the hydrogel had excellent adsorption and release properties. When the environmental pH was 11.0, the highest equilibrium swelling ratio was 1765.1%. The equilibrium swelling ratio would decrease when feed ratio of β-CD to CMC increase. The modified hydrogel has excellent vanillin encapsulation ability, the maximum encapsulation efficiency is 95.8% at low vanillin initial concentration, and the maximum release efficiency is 93.9% under neutral condition, indicating that it has excellent reusability. The results of this paper can provide guidance for the industrial application of substances which are sensitive to light, air or other external conditions.
- Carboxymethyl cellulose,
- β-Cyclodextrin,
- Vanillin,
- Adsorbents
1. [1]
  A K A Silva, C Richard, M Bessodes et al. Biomacromolecules, 2008, 10(1):9-18.
2. [2]
  H Kamata, Y Akagi, Y Kayasugakariya et al. Science, 2014, 343:873-875.
3. [3]
  B Xiao, S Lü, C Zhen et al. Chem. Eng. J., 2016, 288:546-556.
4. [4]
  Y T Chen, S Goudar, R G Wu et al. RSC Adv., 2016, 4:44425-44434.
5. [5]
  X Wang, Z Zhou, X Guo et al. RSC Adv., 2016, 6:35550-35558.
6. [6]
  Z Huang, Q Wu, S Liu et al. Carbohyd. Polym., 2013, 97:496-501.
7. [7]
8. [8]
  J Xiao, C Shi, Y Li et al. Food Hydrocolloid., 2017, 62:35-42.
9. [9]
  G M Durán, A M Contento, Á Ríos. Talanta, 2015, 131:286-291.
10. [10]
  Z Dong, F Gu, F Xu et al. Food Chem., 2014, 149:54-61.
11. [11]
  A Celebioglu, F S ⅰ Kayacisenirmak, E Durgun et al. Food Funct., 2016, 7:3141.
12. [12]
13. [13]
  Z Huang, Q Wu, S Liu et al. Carbohyd. Polym., 2013, 97:496-501.
14. [14]
  L R Varghese, N Das. Ecol. Eng., 2015, 85:201-202.
15. [15]
  T S Anirudhan, P L Divya, J Nima. Chem. Eng. J., 2016, 284:1259-1269.
16. [16]
  J Hu, M Zhang, J He et al. RSC Adv., 2016, 6:40858-40868.
17. [17]
  D Wang, W Ma, M Jia et al. RSC Adv., 2016, 6:27301-27312.
18. [18]
  R Serragómez, C A Dreiss, J Gonzálezbenito et al. Langmuir, 2016, 32(25):6398-6408.
19. [19]
20. [20]
  G Antlsperger, G Schmid. Toxicological comparison of cyclodextrins//Proceedings of the Eighth International Symposium on Cyclodextrins. Springer, Dordrecht, 1996:149-155.
21. [21]
  Z Aytac, Z I Yildiz, F Kayacisenirmak et al. J. Agr. Food Chem., 2016, 64(39):7325-7334.
22. [22]
  S Y Hundre, P Karthik, C Anandharamakrishnan. Food Chem., 2015, 174:16-24.
23. [23]
  H Kono, K Onishi, T Nakamura. Carbohyd. Polym., 2013, 98:784-792.
24. [24]
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沈阳化工大学材料科学与工程学院沈阳 110142